影像科学与光化学 ›› 2014, Vol. 32 ›› Issue (6): 514-522.DOI: 10.7517/j.issn.1674-0475.2014.06.514

• 论文 • 上一篇    下一篇

电沉积法制备固态染料敏化太阳能电池

李海洋1,2, 张敬波3, 魏刚1, 孙丽娜1, 林原2, 付国柱1   

  1. 1. 北京化工大学 材料科学与工程学院, 化工资源有效利用国家重点实验室, 材料电化学过程与技术北京市重点实验室, 北京 100029;
    2. 中国科学院 化学研究所 光化学重点实验室, 北京分子科学国家实验室, 北京 100190;
    3. 天津师范大学 化学学院, 天津市功能分子结构与性能重点实验室, 无机-有机杂化材料化学省部共建教育部重点实验室, 天津 300387
  • 收稿日期:2014-03-19 修回日期:2014-05-08 出版日期:2014-11-15 发布日期:2014-11-15
  • 通讯作者: 张敬波, 付国柱
  • 基金资助:

    Supported by the National Natural Science Foundation of China (21273160, 51102011), the Program for Innovative Research Team in University of Tianjin (TD12-5038) and the Program for Excellent Introduced Talents of Tianjin Normal University in China (5RL116)

Solid-state Dye-sensitized Solar Cell Prepared by Electrochemical Deposition

LI Haiyang1,2, ZHANG Jingbo3, WEI Gang1, SUN Lina1, LIN Yuan2, FU Guozhu1   

  1. 1. National Key Laboratory of Chemical Effective Utilization of Resources, Beijing Key Laboratory of Materials for Electrochemical Process and Technology, College of Material Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P.R.China;
    2. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R.China;
    3. Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, College of Chemistry, Tianjin Normal University, Tianjin 300387, P.R.China
  • Received:2014-03-19 Revised:2014-05-08 Online:2014-11-15 Published:2014-11-15
  • Supported by:

    Supported by the National Natural Science Foundation of China (21273160, 51102011), the Program for Innovative Research Team in University of Tianjin (TD12-5038) and the Program for Excellent Introduced Talents of Tianjin Normal University in China (5RL116)

摘要:

本文采用一步电化学沉积的方法在导电玻璃上先后沉积了ZnO/染料复合薄膜以及CuSCN薄层,实现仅以电沉积法制备结构为ZnO/染料/CuSCN的固态染料敏化太阳能电池,电池的光电转换效率达到0.1%.在电沉积CuSCN前,脱附电沉积制备的ZnO/染料复合薄膜中的染料以形成多孔ZnO薄膜,然后通过染料再吸附得到染料敏化ZnO纳晶多孔薄膜.在电沉积过程中,ZnO和CuSCN的晶体尺寸、晶体取向和膜层形貌都可以进行比较精准的控制.探讨了影响沉积薄膜形貌和光电转换效率的因素,如旋转圆盘电极的旋转速度、电沉积温度以及染料敏化剂的选择.本文报道的低温电沉积制备全固态太阳能电池的方法为制备柔性染料敏化太阳能电池提供了一种新的思路.

关键词: 电化学沉积, ZnO/染料/CuSCN, 固态染料敏化太阳能电池, 光电转换效率

Abstract:

One-step electrochemical deposition method was employed to serially deposit a ZnO/dye hybrid thin film on the conducting glass substrate and then a CuSCN thin layer. Thus a solid-state dye-sensitized solar cell with structure of ZnO/dye/CuSCN was fabricated only by the electrodeposition method, and the photoelectric conversion efficiency of the fabricated solar cell attained 0.1%. Prior to deposition of CuSCN, the dye was first extracted from the as-prepared ZnO/dye hybrid thin film to form porous ZnO thin film, and then dye-sensitized ZnO nanoporous thin film was prepared by readsorption of dye. Crystal size, growth orientation and morphology of ZnO and CuSCN can be accurately controlled by the electrochemical deposition approach, respectively. The factors such as rotating speed of the rotating disk electrode, temperature of electrodeposition, addition of different dyes, to influence the morphology of the as-deposited thin films and the photoelectric conversion efficiency of the as-prepared solar cells were also studied in this paper. The electrochemical deposition operated at low temperature opens a way to fabricate flexible dye-sensitized solar cells in future.

Key words: electrochemical deposition, ZnO/dye/CuSCN, solid-state dye-sensitized solar cell, photoelectric conversion efficiency