无机纳米材料的光化学合成

doi:10.7517/j.issn.1674-0475.2017.04.024

影像科学与光化学 ›› 2017, Vol. 35 ›› Issue (5): 642-648.DOI: 10.7517/j.issn.1674-0475.2017.04.024

无机纳米材料的光化学合成

曹溢涛^1,2, 吴骊珠¹, 佟振合¹, 张铁锐¹

1. 中国科学院理化技术研究所光化学转换与功能材料重点实验室, 北京 100190;
2. 中国科学院大学, 北京 100049

收稿日期:2017-05-19 修回日期:2017-06-07 出版日期:2017-09-15 发布日期:2017-09-15
通讯作者: 张铁锐
基金资助:
国家重点基础研究发展计划（2014CB239402，2013CB834505）、国家重点基础研究专项基金（2016YFB0600900）、国家自然科学基金项目（51572270，U1662118，21401207）、北京市自然科学基金项目（2152033）、中国科学院先导B项目（XDB17030300）资助

Photochemical Synthesis of Inorganic Nanomaterials

CAO Yitao^1,2, WU Lizhu¹, TONG Zhenhe(TUNG Chenho)¹, ZHANG Tierui¹

1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received:2017-05-19 Revised:2017-06-07 Online:2017-09-15 Published:2017-09-15

摘要/Abstract

摘要：

无机纳米材料的合成是纳米科学发展的前提和基础之一。区别于传统的高温湿化学合成法，光化学方法在无机纳米材料的合成中表现出许多优点，并在近年来受到了广泛关注。本文分三个部分综述了近年来光化学方法在无机纳米材料合成中的应用，具体包括贵金属纳米材料的光化学合成与负载，半导体纳米材料的光化学合成以及表面等离子体共振诱导的各向异性金属纳米晶合成。最后，在总结光化学方法在无机纳米材料合成中体现出的优势及目前研究仍存在不足的基础上，我们对其未来可能的发展方向进行了展望。

关键词: 无机纳米材料, 光化学合成, 贵金属纳米材料, 半导体纳米材料

Abstract:

The synthesis of inorganic nanomaterials is one of the prerequisites and bases for the development of nanoscience. Different from the wet-chemical method at elevated temperature, the photochemical method reveals some unique characteristics in the synthesis of inorganic nanomaterials, and has attracted extensive attention in recent years. This paper reviews the applications of photochemical method in the synthesis of inorganic nanomaterials in recent years in three parts, including photochemical synthesis and loading of noble metal nanomaterials, photochemical synthesis of semiconductor nanomaterials, and plasmon-mediated photochemical synthesis of anisotropic metal nanocrystals. At last, on the basis of summarizing the advantages of photochemical method in the synthesis of inorganic nanomaterials and the shortcomings in the present studies, we prospect the possible direction of its development in the future.

Key words: inorganic nanomaterials, photochemical synthesis, noble metal nanomaterials, semiconductor nanomaterials

曹溢涛, 吴骊珠, 佟振合, 张铁锐. 无机纳米材料的光化学合成[J]. 影像科学与光化学, 2017, 35(5): 642-648.

CAO Yitao, WU Lizhu, TONG Zhenhe(TUNG Chenho), ZHANG Tierui. Photochemical Synthesis of Inorganic Nanomaterials[J]. Imaging Science and Photochemistry, 2017, 35(5): 642-648.

参考文献

[1] LaMer V K, Dinegar R H. Theory, production and mechanism of formation of monodispersed hydrosols[J]. Journal of the American Chemical Society, 1950, 72(11):4847-4854.
[2] Jun Y, Choi J, Cheon J. Shape control of semiconductor and metal oxide nanocrystals through nonhydrolytic colloidal routes[J]. Angewandte Chemie International Edition, 2006, 45(21):3414-3439.
[3] Xia Y N, Xiong Y J, Lim B,Skrabalak S E. Shape-controlled synthesis of metal nanocrystals:simple chemistry meets complex physics[J]. Angewandte Chemie International Edition, 2009, 48(1):60-103.
[4] Jin R C, Cao Y W, Mirkin C A, Kelly K L, Schatz G C, Zheng J. Photoinduced conversion of silver nanospheres to nanoprisms[J]. Science, 2001, 294(5548):1901-1903.
[5] Langille M R, Personick M L, Mirkin C A. Plasmon-mediated syntheses of metallic nanostructures[J]. Angewandte Chemie International Edition, 2013, 52(52):13910-13940.
[6] Tan D, Liu X, Qiu J. Photochemical synthesis of doped graphene quantum dots and their photoluminescence in aqueous and solid states[J]. RSC Advances, 2015, 5(102):84276-84279.
[7] Eustis S, Hsu H Y, El-Sayed M A. Gold nanoparticle formation from photochemical reduction of Au³⁺ by continuous excitation in colloidal solutions. A proposed molecular mechanism[J]. The Journal of Physical Chemistry B, 2005, 109(11):4811-4815.
[8] Zhang H, Huang X, Li L, Zhang G W, Hussain I, Li Z, Tan B. Photoreductive synthesis of water-soluble fluorescent metal nanoclusters[J]. Chemical Communications, 2012, 48(4):567-569.
[9] Marin M L, McGilvray K L, Scaiano J C. Photochemical strategies for the synthesis of gold nanoparticles from Au (Ⅲ) and Au (Ⅰ) using photoinduced free radical generation[J]. Journal of the American Chemical Society, 2008, 130(49):16572-16584.
[10] Maretti L, Billone P S, Liu Y, Scaiano J C. Facile photochemical synthesis and characterization of highly fluorescent silver nanoparticles[J]. Journal of the American Chemical Society, 2009, 131(39):13972-13980.
[11] Kim F, Song J H, Yang P. Photochemical synthesis of gold nanorods[J]. Journal of the American Chemical Society, 2002, 124(48):14316-14317.
[12] Quaresma P, Soares L, Contar L, Miranda A, Osorio I, Carvalho P A, Franco R, Pereira E. Green photocatalytic synthesis of stable Au and Ag nanoparticles[J]. Green Chemistry, 2009, 11(11):1889-1893.
[13] Kumar V, Gundampati R K, Singh D K, Bano D, Jagannadham M V, Hasan S H. Photoinduced green synthesis of silver nanoparticles with highly effective antibacterial and hydrogen peroxide sensing properties[J]. Journal of Photochemistry and Photobiology B:Biology, 2016, 162:374-385.
[14] Kshirsagar P, Sangaru S S, Brunetti V, Malvindi M A, Pompa P P. Synthesis of fluorescent metal nanoparticles in aqueous solution by photochemical reduction[J]. Nanotechnology, 2014, 25(4):045601.
[15] Huang X, Zhou X Z, Wu S X, Wei Y Y, Qi X Y, Zhang J, Boey F, Zhang H. Reduced graphene oxide-templated photochemical synthesis and in situ assembly of Au nanodots to orderly patterned Au nanodotchains[J]. Small, 2010, 6(4):513-516.
[16] Cheng N Y, Tian J Q, Liu Q, Ge C J, Qusti A H, Asiri A M, Al-Youbi A O, Sun X P. Au-nanoparticle-loaded graphitic carbon nitride nanosheets:green photocatalytic synthesis and application toward the degradation of organic pollutants[J]. ACS Applied Materials & Interfaces, 2013, 5(15):6815-6819.
[17] Fageria P, Uppala S, Nazir R, Gangopadhyay S, Chang C H, Basu M, Pande S. Synthesis of monometallic (Au and Pd) and bimetallic (AuPd) nanoparticles using carbon nitride (C₃N₄) quantum dots via the photochemical route for nitrophenol reduction[J]. Langmuir, 2016, 32(39):10054-10064.
[18] Ge J, Li Y, Wang J, Pu Y, Xue W D, Liu X G. Green synthesis of graphene quantum dots and silver nanoparticles compounds with excellent surface enhanced Raman scatte-ring performance[J]. Journal of Alloys and Compounds, 2016, 663:166-171.
[19] Jiang D L, Zhang Y, Chu H Y, Liu J, Wan J, Chen M. N-doped graphene quantum dots as an effective photocatalyst for the photochemical synthesis of silver deposited porous graphitic C₃N₄ nanocomposites for nonenzymatic electrochemical H₂O₂ sensing[J]. RSC Advances, 2014, 4(31):16163-16171.
[20] Peng D L, Wang H H, Yu K, Chang Y, Ma X G, Dong S J. Photochemical preparation of the ternary composite CdS/Au/gC₃N₄ with enhanced visible light photocatalytic performance and its microstructure[J]. RSC Advances, 2016, 6(81):77760-77767.
[21] Qin X Y, Lu W B, Chang G H, Luo Y L, Asiri A M, Al-Youbi A O, Sun X P. Novel synthesis of Au nanoparticles using fluorescent carbon nitride dots as photocatalyst[J]. Gold Bulletin, 2012, 45(2):61-67.
[22] Stroyuk A L, Shvalagin V V, Kuchmii S Y. Photochemical synthesis and optical properties of binary and ternary metal-semiconductor composites based on zinc oxide nanoparticles[J]. Journal of Photochemistry and Photobiology A:Chemistry, 2005, 173(2):185-194.
[23] Liu P X, Zhao Y, Qin R X, Mo S G, Chen G X, Gu L, Chevrier D M, Zhang P, Guo Q, Zang D D, Wu B H, Fu G, Zheng N F. Photochemical route for synthesizing ato-mically dispersed palladium catalysts[J]. Science, 2016, 352(6287):797-800.
[24] Egorov N B, Eremin L P, Usov V F, Larionov A M. Preparation of lead sulfide nanoparticles in the photolysis of aqueous solutions of lead thiosulfate complex[J]. High Energy Chemistry, 2007, 41(4):251-254.
[25] Gao X, Wu J, Wei X, He C, Wang X, Guo G, Pu Q. Fa-cile one-step photochemical synthesis of water soluble CdTe (S) nanocrystals with high quantum yields[J]. Journal of Materials Chemistry, 2012, 22(13):6367-6373.
[26] Gonzalez C M, Wu W C, Tracy J B, Martin B. Photochemical synthesis of size-tailored hexagonal ZnS quantum dots[J]. Chemical Communications, 2015, 51(15):3087-3090.
[27] Kundu S, Liang H. Photochemical synthesis of electrically conductive CdS nanowires on DNA scaffolds[J]. Advanced Materials, 2008, 20(4):826-831.
[28] Taghavinia N, Iraji-zad A, Mahdavi S M, Reza-esmaili M. Photo-induced CdS nanoparticles growth[J]. Physica E:Low-dimensional Systems and Nanostructures, 2005, 30(1):114-119.
[29] Cao Y T, Geng W, Shi R, Shang L, Waterhouse G I N, Liu L M, Wu L Z, Tung C H, Yin Y D, Zhang T R. Thiolate-mediated photoinduced synthesis of ultrafine Ag₂S quantum dots from silver nanoparticles[J]. Angewandte Chemie International Edition, 2016, 55(48):14952-14957.
[30] Linic S, Aslam U, Boerigter C, Morabito M. Photochemical transformations on plasmonic metal nanoparticles[J]. Nature Materials, 2015, 14(6):567-576.
[31] Ahmadi T S, Wang Z L, Green T C, Henglein A, El-Sayed M A. Shape-controlled synthesis of colloidal platinum nanoparticles[J]. Science, 1996, 272(5270):1924.
[32] Jana N R, Gearheart L, Murphy C J. Wet chemical synthesis of high aspect ratio cylindrical gold nanorods[J]. The Journal of Physical Chemistry B, 2001, 105(19):4065-4067.
[33] Jin R C, Cao Y C, Hao E C, Metraux G S, Schatz G C, Mirkin C A. Controlling anisotropic nanoparticle growth through plasmon excitation[J]. Nature, 2003, 425(6957):487-490.
[34] Xue C, Millstone J E, Li S Y, Mirkin C A. Plasmon-driven synthesis of triangular core-shell nanoprisms from gold seeds[J]. Angewandte Chemie International Edition, 2007, 119(44):8588-8591.
[35] Xue C, Millstone J E, Li S Y, Mirkin C A. Mechanistic study of photomediated triangular silver nanoprism growth[J]. Journal of the American Chemical Society, 2008, 130(26):8337-8344.
[36] Langille M R, Zhang J, Personick M L, Li S Y, Mirkin C A. Stepwise evolution of spherical seeds into 20-fold twinned icosahedra[J]. Science, 2012, 337(6097):954-957.
[37] Zhai Y M, DuChene J S, Wang Y C, Qiu J J, Johnston-Peck A C, You B, Guo W X, DiCiaccio B, Qian K, Zhao E W, Ooi F, Hu D H, Su D, Stach E A, Zhu Z H, Wei W D. Polyvinylpyrrolidone-induced anisotropic growth of gold nanoprisms in plasmon-driven synthesis[J]. Nature Materials, 2016, 15(8):889-895.

无机纳米材料的光化学合成

Photochemical Synthesis of Inorganic Nanomaterials

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 2

编辑推荐

Metrics

本文评价

[1]	王华. 噻吩螺烯的化学与光化学合成[J]. 影像科学与光化学, 2017, 35(5): 603-613.
[2]	江致勤, 曾代迅. 光氧化反应的研究 Ⅵ.敏化光氧化反应合成胆甾烯烃衍生物[J]. 影像科学与光化学, 1989, 7(1): 53-59.