基于金属钴配合物的均相光催化还原二氧化碳研究进展

doi:10.7517/j.issn.1674-0475.2017.04.025

影像科学与光化学 ›› 2017, Vol. 35 ›› Issue (5): 649-657.DOI: 10.7517/j.issn.1674-0475.2017.04.025

基于金属钴配合物的均相光催化还原二氧化碳研究进展

桂梦茜, 俞洋, 朱诚逸, 刘宏芳, 王锋

华中科技大学化学与化工学院, 能量转换与存储材料化学教育部重点实验室, 湖北武汉 430074

收稿日期:2017-06-05 修回日期:2017-06-19 出版日期:2017-09-15 发布日期:2017-09-15
通讯作者: 王锋
基金资助:
华中科技大学2016人才引进基金、国家自然科学基金（U1662114）和深圳市科技创新委员会知识创新基础研究（自由探索）项目（JCYJ20170307154314576）资助

Advances on Molecular Systems for Photocatalytic CO₂ Reduction Based on Cobalt Complexes as Catalysts

GUI Mengxi, YU Yang, ZHU Chengyi, LIU Hongfang, WANG Feng

Key Laboratory of Materials Chemistry for Energy Conversion and Storage(HUST) of Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei, P. R. China

Received:2017-06-05 Revised:2017-06-19 Online:2017-09-15 Published:2017-09-15

摘要/Abstract

摘要：

本文综述了自20世纪80年代以来基于钴配合物的均相光催化二氧化碳还原研究成果，以钴配合物催化剂的结构分类并结合时间顺序回顾了近四十年来该领域的发展轨迹，重点总结了用于光催化二氧化碳还原研究的金属钴配合物的结构、催化活性以及光催化体系的构成等特点，分析了该领域面临的挑战并展望了未来的发展方向。

关键词: 人工光合作用, 光催化二氧化碳还原, 可见光催化, 金属钴配合物, 分子催化剂

Abstract:

Photocatalytic CO₂ reduction is a major part of the study of artificial photosynthesis. The conversion of molecule CO₂ into fuels, precursor to fuels, or value-added chemicals through visible light induced photocatalysis is considered as an ideal way of fixation and resource utilization of CO₂. Metal complexes as molecular catalysts for CO₂ reduction had long been used in photocatalytic CO₂ reduction systems for its tunable structure, rich valences of contained metal, easy synthesis, and economic advantages. The study of utilization of cobalt complexes as catalysts for photocatalytic CO₂ reduction dates from 1980s. A large number of cobalt complexes of Co-macrocycles, Co-porphyrin and its analogues, Co-polypyridine complexes had been developed as catalysts to mediate CO₂-CO or CO₂-formate conversion in particular photocatalytic CO₂ reduction systems. Herein, we review the development and advances of the study on molecular systems for photocatalytic CO₂ reduction based on cobalt complexes as catalysts. The cobalt complexes used in photocatalytic CO₂ reduction systems are classified and discussed. The structures, mechanisms, and composition of systems are reviewed. In the end of the review, a summary and outlook are given.

Key words: artificial photosynthesis, photocatalytic CO₂ reduction, photocatalysis, cobalt complexes, molecular catalyst

桂梦茜, 俞洋, 朱诚逸, 刘宏芳, 王锋. 基于金属钴配合物的均相光催化还原二氧化碳研究进展[J]. 影像科学与光化学, 2017, 35(5): 649-657.

GUI Mengxi, YU Yang, ZHU Chengyi, LIU Hongfang, WANG Feng. Advances on Molecular Systems for Photocatalytic CO₂ Reduction Based on Cobalt Complexes as Catalysts[J]. Imaging Science and Photochemistry, 2017, 35(5): 649-657.

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基于金属钴配合物的均相光催化还原二氧化碳研究进展

Advances on Molecular Systems for Photocatalytic CO₂ Reduction Based on Cobalt Complexes as Catalysts

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Advances on Molecular Systems for Photocatalytic CO2 Reduction Based on Cobalt Complexes as Catalysts

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Advances on Molecular Systems for Photocatalytic CO₂ Reduction Based on Cobalt Complexes as Catalysts