范德华外延生长硫化镉二维纳米片及其光致发光性能研究

doi:10.7517/j.issn.1674-0475.2016.03.273

影像科学与光化学 ›› 2016, Vol. 34 ›› Issue (3): 273-280.DOI: 10.7517/j.issn.1674-0475.2016.03.273

范德华外延生长硫化镉二维纳米片及其光致发光性能研究

朱丹丹, 夏静, 王磊, 李玄泽, 孟祥敏

中国科学院理化技术研究所光化学与光功能材料重点实验室, 北京 100190

收稿日期:2016-04-01 修回日期:2016-04-12 出版日期:2016-05-15 发布日期:2016-05-15
通讯作者: 孟祥敏
基金资助:
国家重点基础研究发展规划973项目(2012CB932401)、中国科学院战略性先导科技专项(XDA09040203)资助

Van der Waals Epitaxy and Photoluminescence of Two-Dimensional CdS Nanoplates

ZHU Dandan, XIA Jing, WANG Lei, LI Xuanze, MENG Xiangmin

Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received:2016-04-01 Revised:2016-04-12 Online:2016-05-15 Published:2016-05-15

摘要/Abstract

摘要：

二维纳米材料具有独特的结构和优异的性能,在电子学及光电子学领域有广泛的应用前景,但关于硫化镉二维纳米材料的制备及性能研究还鲜有报道。本文首次采用范德华外延生长技术,在氟金云母片衬底上制备了硫化镉二维纳米片。通过扫描电子显微镜、透射电子显微镜、原子力显微镜、X射线粉末衍射仪和拉曼光谱仪等分析手段对产物的形貌、厚度、晶体结构、成分等进行了系统的研究。结果表明,纳米片具有六方纤锌矿晶体结构,尺寸约为几个微米,厚度约为几十纳米。范德华外延生长技术在硫化镉二维单晶纳米片制备上的成功应用,为其它二维非层状材料的制备提供了新的思路,并使其在高性能电子和光电子器件上的应用成为了可能。

关键词: 范德华外延, 二维材料, 硫化镉, 非层状材料, 光致发光

Abstract:

Two-dimensional (2D) materials have been demonstrated for applications of electronic and optoelectronic devices due to their unique structures and excellent properties. Nevertheless, researches on 2D CdS materials have remained conspicuously absent. In this work, we present the first growth of 2D CdS nanoplates on mica substrates via van der Waals epitaxy. The morphology, thickness, structure and component of the products were systematically studied by scanning electron microscopy, transmission electron microscopy, atomic force microscopy, X-Ray powder diffraction and Raman spectroscopy. They all clearly indicate that the as-synthesized 2D nanoplates possess a single-crystalline hexagonal structure, and have a lateral size around several microns and height about several tens of nanometers. Our work may open up a new pathway for the synthesis of 2D nanostructures of other non-layered materials and make it possible for 2D non-layered materials to apply in high performance electronic and optoelectronic devices.

Key words: van der Waals epitaxy, two-dimensional materials, CdS, non-layerd materials, photoluminescence

朱丹丹, 夏静, 王磊, 李玄泽, 孟祥敏. 范德华外延生长硫化镉二维纳米片及其光致发光性能研究[J]. 影像科学与光化学, 2016, 34(3): 273-280.

ZHU Dandan, XIA Jing, WANG Lei, LI Xuanze, MENG Xiangmin. Van der Waals Epitaxy and Photoluminescence of Two-Dimensional CdS Nanoplates[J]. Imaging Science and Photochemistry, 2016, 34(3): 273-280.

参考文献

[1] Liao L, Lin Y C, Bao M, Cheng R, Bai J, Liu Y, Qu Y, Wang K L, Huang Y, Duan X. High-speed graphene transistors with a self-aligned nanowire gate[J]. Nature, 2010, 467(7313): 305-308.
[2] Xu M, Liang T, Shi M, Chen H. Graphene-like two-dimensional materials[J]. Chemical Reviews, 2013, 113(5): 3766-3798.
[3] Sun Z, Chang H. Graphene and graphene-like two-dimensional materials in photodetection: mechanisms and metho-dology[J]. Acs Nano, 2014, 8(5): 4133-4156.
[4] Zhao W, Ribeiro R M, Toh M, Carvalho A, Kloc C, Castro Neto A H, Eda G. Origin of indirect optical transitions in few-layer MoS₂, WS₂, and WSe2[J]. Nano Letters, 2013, 13(11): 5627-5634.
[5] Meric I, Han M Y, Young A F, Ozyilmaz B, Kim P, Shepard K L. Current saturation in zero-bandgap, topgated graphene field-effect transistors[J].Nature Nanotechnology, 2008, 3(11): 654-659.
[6] Mak K F, Lee C, Hone J, Shan J, Heinz T F. Atomically thin MoS₂: a new direct-gap semiconductor[J]. Physical Review Letters, 2010, 105:136805.
[7] Splendiani A, Sun L, Zhang Y, Li T, Kim J, Chim C Y, Galli G, Wang F. Emerging photoluminescence in monolayer MoS₂[J]. Nano Letters, 2010, 10(4): 1271-1275.
[8] Zhao W, Ghorannevis Z, Chu L, Toh M, Kloc C, Tan P H, Eda G. Evolution of electronic structure in atomically thin sheets of WS₂ and WSe₂[J]. Acs Nano, 2013, 7(1): 791-797.
[9] Wang Q, Safdar M, Xu K, Mirza M, Wang Z, He J. Van der Waals epitaxy and photoresponse of hexagonal tellurium nanoplates on flexible mica sheets[J]. ACS Nano, 2014, 8(7): 7497-7505.
[10] Utama M I B, Zhang Q, Zhang J, Yuan Y, Belarre F J, Arbiol J, Xiong Q. Recent developments and future directions in the growth of nanostructures by van der Waals epitaxy[J]. Nanoscale, 2013, 5(9): 3570-3588.
[11] Ji Q, Zhang Y, Gao T, Zhang Y, Ma D, Liu M, Chen Y, Qiao X, Tan P H, Kan M, Feng J, Sun Q, Liu Z. Epitaxial monolayer MoS₂ on mica with novel photoluminescence[J]. Nano Letters, 2013, 13(8): 3870-3877.
[12] Zhang X, Meng F, Christianson J R, Arroyo Torres C, Lukowski M A, Liang D, Schmidt J R, Jin S. Vertical heterostructures of layered metal chalcogenides by van der Waals epitaxy[J]. Nano Letters, 2014, 14(6): 3047-3054.
[13] Hong Y J, Yang J W, Lee W H, Ruoff R S, Kim K S, Fukui T. Van der Waals epitaxial double heterostructure: InAs/single-layer graphene/InAs[J]. Advanced Mate-rials, 2013, 25(47): 6847-6853.
[14] Tan C, Zhang H. Epitaxial growth of hetero-nanostructures based on ultrathin two-dimensional nanosheets[J]. Journal of the American Chemical Society, 2015, 137(38): 12162-12174.
[15] Kim J, Bayram C, Park H, Cheng C W, Dimitrakopoulos C, Ott J A, Reuter K B, Bedell S W, Sadana D K. Principle of direct van der Waals epitaxy of single-crystalline films on epitaxial graphene[J]. Nature Communications,2014, Sep.,11:4836. doi:10.1038/ncomms5836.
[16] Wang Y, Shi Y, Xin G, Lan J, Shi J. Two-dimensional van der Waals epitaxy kinetics in a three-dimensional perovskite halide[J]. Crystal Growth & Design, 2015, 15(10): 4741-4749.
[17] Tang J, Huo Z, Brittman S, Gao H, Yang P. Solution-processed core-shell nanowires for efficient photovoltaic cells[J]. Nature Nanotechnology, 2011, 6(9): 568-572.
[18] Deng K, Li L. CdS nanoscale photodetectos[J]. Advanced Materials, 2014, 26(17): 2619-2635.
[19] Pan A, Zhou W, Leong E S P, Liu R, Chin A H, Zou B, Ning C Z. Continuous alloy-composition spatial grading and superbroad wavelength-tunable nanowire lasers on a single chip[J]. Nano Letters, 2009, 9(2): 784-788.
[20] Hayden O, Greytak A B, Bell D C. Core-shell nanowire light-emitting diodes[J]. Advanced Materials, 2005, 17(6): 701-704.
[21] Li H, Wang X, Xu J, Zhang Q, Bando Y, Golberg D, Ma Y, Zhai T. One-dimensional CdS nanostructures: a promising candidate for optoelectronics[J]. Advanced Mate-rials, 2013, 25(22): 3017-3037.
[22] Ithurria S, Tessier M D, Mahler B, Lobo R P S M, Dubertret B, Efros A L. Colloidal nanoplatelets with two-dimensional electronic structure[J]. Nature Materials, 2011, 10(12): 936-941.
[23] Feng Q, Mao N, Wu J, Xu H, Wang C, Zhang J, Xie L. Growth of MoS_2(1-x)Se_2x (x=0.41-1.00) Monolayer alloys with controlled morphology by physical vapor deposition[J]. ACS Nano, 2015, 9(7): 7450-7455.
[24] Zhou H, Wang C, Shaw J C, Cheng R, Chen Y, Huang X, Liu Y, Weiss N O, Lin Z, Huang Y, Duan X. Large area growth and electrical properties of p-type WSe₂ atomic layers[J]. Nano Letters, 2015, 15(1): 709-713.
[25] Utama M I B, Peng Z, Chen R, Peng B, Xu X, Dong Y, Wong L M, Wang S, Sun H, Xiong Q. Vertically aligned cadmium chalcogenide nanowire arrays on muscovite mica: a demonstration of epitaxial growth strategy[J]. Nano Letters, 2011, 11(8): 3051-3057.

范德华外延生长硫化镉二维纳米片及其光致发光性能研究

Van der Waals Epitaxy and Photoluminescence of Two-Dimensional CdS Nanoplates

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	朱文庆, 樊盼, 李扬, 朱玉梦, 张瑾. 双配体Zn(Ⅱ)MOFs材料的构筑及光致发光性能[J]. 影像科学与光化学, 2020, 38(2): 159-166.
[2]	郜昱, 刘国罡, 石建兵, 董宇平. 芳基吡咯衍生物的合成及其发光性质[J]. 影像科学与光化学, 2019, 37(2): 93-106.
[3]	李玥, 宋育泽, 陶雁忠, 高风仙, 汤宁. CdS/TiO₂复合纳米网的制备及光催化性能研究[J]. 影像科学与光化学, 2018, 36(3): 275-282.
[4]	纪海侠, 董露露, 杜岩, 姚欣悦, 杨冬芝. 肿瘤细胞内CdS纳米量子点的仿生化合成[J]. 影像科学与光化学, 2018, 36(1): 57-63.
[5]	靳玉娟, 罗运军, 李国平, 张婉露. 聚酰胺-胺树形分子对胶带上油潜指纹的显现研究[J]. 影像科学与光化学, 2012, 30(3): 228-236.
[6]	靳玉娟, 罗运军, 李国平, 李杰. 荧光性聚酰胺-胺树形分子在潜指纹显现中的应用研究[J]. 影像科学与光化学, 2011, 29(3): 194-202.
[7]	靳玉娟, 罗运军, 李国平, 李杰, 卢文婷. 聚酰胺-胺树形分子荧光性能研究及其在指纹识别领域应用初探[J]. 影像科学与光化学, 2010, 28(2): 111-120.
[8]	曹莹, 白雪峰. 负载型纳米CdS制备及催化分解水制氢的研究进展[J]. 影像科学与光化学, 2009, 27(3): 225-232.
[9]	李国平, 罗运军. 紫外光辐照下以PAMAM树形分子为模板制备Ag纳米簇及光致发光性能研究[J]. 影像科学与光化学, 2007, 25(4): 249-256.
[10]	陈晓慧, 柳丽芬, 杨凤林, 张兴文, 余济美. CdS/TiO₂光催化去除水体中氨氮的研究[J]. 影像科学与光化学, 2007, 25(2): 89-101.
[11]	李捷, 韩莉, 薛敏钊, 张青, 刘燕刚. 紫外线对BaFCl:Eu光激励发光的增强效应[J]. 影像科学与光化学, 2003, 21(1): 39-45.
[12]	张晓宏, 姜永才, 吴世康, 高志强, 李振声, 李述汤. 具有不同取代基的吡唑啉衍生物的光致发光和电致发光[J]. 影像科学与光化学, 2000, 18(2): 160-164.
[13]	蒋峰芝, 许认, 王夺元, 董兴德, 李桂春. 气动力压敏漆发光特性研究[J]. 影像科学与光化学, 1999, 17(4): 309-315.
[14]	张晓宏, 吴世康, 高志强, W.Y. Lai, 李振声, 邝海伦, 李述汤 . 苯并噻唑衍生物用作EL器件中发光材料的研究[J]. 影像科学与光化学, 1999, 17(3): 199-202.
[15]	谢普会, 陈景荣, 张宝文, 曹怡. 吨染料与反胶束体系中CdS的光敏电子转移[J]. 影像科学与光化学, 1999, 17(1): 51-60.