银纳米微球和银纳米棒自组装膜的制备及SERS研究

doi:10.7517/j.issn.1674-0475.2016.04.329

影像科学与光化学 ›› 2016, Vol. 34 ›› Issue (4): 329-335.DOI: 10.7517/j.issn.1674-0475.2016.04.329

银纳米微球和银纳米棒自组装膜的制备及SERS研究

李莉¹, 鲁峰¹, 杨武²

1. 甘肃有色冶金职业技术学院, 甘肃金昌 737100;
2. 西北师范大学化学化工学院生态环境相关高分子材料教育部重点实验室, 甘肃兰州 730070

收稿日期:2015-12-04 修回日期:2016-02-29 出版日期:2016-07-15 发布日期:2016-07-15
通讯作者: 李莉
基金资助:
国家自然科学基金(20873101)和教育部教育管理信息中心2015年岗位模型课题研究项目(JYB-EMIC-15021)资助

Preparation of Self-assembled Films of Silver Nanoparticles and Silver Nanorods for SERS Research

LI Li¹, LU Feng¹, YANG Wu²

1. Gansu Vocational & Technical College of Nonferrous Metallurgy, Jinchang 737100, Gansu,P.R.China;
2. Key Lab of Eco-Environmental Related Polymer Materials of MOE, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, Gansu, P.R.China

Received:2015-12-04 Revised:2016-02-29 Online:2016-07-15 Published:2016-07-15

摘要/Abstract

摘要：

采用硼氢化钠还原硝酸银,用振荡器在不同转速下振荡得到单分散的银纳米微球和银纳米棒,再将银纳米微球及银纳米棒自组装于被3-氨丙基-三甲氧基硅烷(APTMS)修饰的玻璃基片上,制得了具有表面增强拉曼(SERS)活性的基底,分别以罗丹明6G(R6G)和罗丹明B(RB)为探针分子对这两种基底进行SERS活性检测,结果发现这两种基底均为较理想的SERS衬底。

关键词: 银纳米微球, 银纳米棒, 自组装, SERS

Abstract:

With different rotational speed of agitator, the silver nanoparticles and silver nanorods were obtained by the reduction of sodium borohydride. Then the silver nanoparticles and nanorods were self-assembed on a glass plate modified by the silane reagent 3-aminopropyltrimethoxysilane (APTMS). The glass plate was prepared as surface-enhanced Raman scattering (SERS) active basement, with Rhodamine 6G (R6G) and Rhodamine B (RB) molecular probes for the detection of the two substrates' SERS activities. The results showed that the two substrates are ideal SERS substrates.

Key words: silver nanoparticles, silver nanorods, self-assembled, SERS

李莉, 鲁峰, 杨武. 银纳米微球和银纳米棒自组装膜的制备及SERS研究[J]. 影像科学与光化学, 2016, 34(4): 329-335.

LI Li, LU Feng, YANG Wu. Preparation of Self-assembled Films of Silver Nanoparticles and Silver Nanorods for SERS Research[J]. Imaging Science and Photochemistry, 2016, 34(4): 329-335.

参考文献

[1] 沈剑沧.银纳米颗粒的合成与表面增强拉曼光谱[J]. 兰州大学学报(自然科学版), 2007, 43(5): 139-141. Shen J C. Silver nanocrystals: synthesis and surfae-enhand Raman spectroscopy[J]. Journal of Lanzhou University, 2007,43(5): 139-141.
[2] Olson L G, LO Y S, Beebe T P, Jr and Harris J M. Characterization of silane-modified immobilized gold colloids as a substrate for surface-enhanced Raman spectroscopy[J]. Analytical Chemistry, 2001, 73(17): 4268-4276.
[3] 凌丽,徐敏敏,顾仁敖,姚建林. Ag_核Au_壳双金属复合纳米线的制备及其表面增强拉曼光谱研究[J].化学学报, 2007, 65(9): 779-784. Ling L, Xu M M, Gu R A, Yao J L. Preparation of Ag_coreAu_shell nanowires and their surface enhanced raman spectroscopic studies[J]. Acta Chimica Sinica, 2007, 65(9): 779-784.
[4] Nie S and Emory S R. Probing single molecules and single nanoparticles by surface-enhanced Raman scattering[J]. Science, 1997, 275(21): 1102-1106.
[5] 聂宜文, 张兴业, 宋延林.单分散性银纳米粒子的可控制备[J].影像科学与光化学, 2014, 32(4): 402-409. Nie Y W, Zhang X Y, Song Y L. Controllable synthesis of monodispersed silver nanoparticles[J]. Imaging Science and Photochemistry, 2014, 32(4): 402-409.
[6] Kelly K L, Coronado E, Zhao L L and Schatz G C. The optical properties of metal nanoparticles: the influence of size, shape, and dielectric environment[J]. The Journal of Physical Chemistry B, 2003, 107(3): 668-677.
[7] Sun L L, Zhao D X, Ding M, Zhao H F, Zhang Z Z, Li B H, Shen D Z. One-step synthesis of hape-controllable gold nanoparticles and their application in surface-enhanced Raman scattering[J]. Journal of Materials Science & Technology, 2013, 29(7): 613-618.
[8] Gao C Y, Chen Y C, Chen K L, Huang C J. Surface plasmon enhanced organic light emitting diodes by goldnanoparticles with different sizes[J]. Applied Surface Science, 2015, 356: 791-794.
[9] Mohammad R, Karine M, Mickael D, Ludovic J, Valeriy L, Joumana T, Kamal H, Tayssir H, Rynno L, Hamidou H. Controlling shape and spatial organization of silver crystals bysite-selective chemical growth method for improving surfaceenhanced Raman scattering activity[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2015, 484: 508-517.
[10] Westcott S L, Oldenburg S J, Lee T R and Halas N J. Formation and adsorption of clusters of gold nanoparticles onto functionalized silica nanoparticle surfaces[J]. Langmuir, 1998, 14(19): 5396-5401.
[11] Jiang Z J, Liu C Y. Seed-mediated growth technique for the preparation of a silver nanoshell on a silica sphere[J]. The Journal of Physical Chemistry B, 2003, 107(45): 12411-12415.

[1]	李冰, 李海波, Mark Neisser, Caleb L. Breaux, Clifford L. Henderson. 用于大分子定向自组装的新型嵌段共聚物的合成与表征[J]. 影像科学与光化学, 2018, 36(4): 306-314.
[2]	柏宇豪, 谭剑波, 张力. 水相光引发聚合诱导自组装制备嵌段共聚物纳米材料[J]. 影像科学与光化学, 2017, 35(6): 816-823.
[3]	张雪超, 谭剑波, 张力. 水相光引发聚合诱导自组装制备CO₂响应性聚合物囊泡[J]. 影像科学与光化学, 2017, 35(6): 833-842.
[4]	万堂庆, 黎占亭. 从超分子聚合物到超分子有机框架:组装溶液相超分子结构的周期性[J]. 影像科学与光化学, 2015, 33(1): 3-14.
[5]	王安东, 阎云, 黄建滨. 光化学在自组装结构调控与探测中的应用[J]. 影像科学与光化学, 2015, 33(1): 15-27.
[6]	王秀凤, 杨东, 刘鸣华. 超分子凝胶中的光化学反应[J]. 影像科学与光化学, 2015, 33(1): 49-66.
[7]	马莹, 鱼春萌, 刘科, 蔡秀琴, 张少飞, 房喻. 杯[4]芳烃的表面化学组装及其在气态四氢呋喃荧光传感薄膜创制中的应用[J]. 影像科学与光化学, 2015, 33(1): 67-76.
[8]	刘占芳, 宋恺, 佟振合. 胶体光子晶体的平面介电常数缺陷[J]. 影像科学与光化学, 2013, 31(6): 401-410.
[9]	李海霞, 高云燕, 欧植泽, 金和林, 曹璐, 陈晨. PMADQUAT/PSt-PAA聚离子复合物聚集体增强卟啉和富勒烯类衍生物单重态氧产率[J]. 影像科学与光化学, 2013, 31(3): 197-207.
[10]	王飞, 丁可伟, 吴飞鹏. 水体系中含卟啉基团的两亲高分子的自组装行为和性质的研究[J]. 影像科学与光化学, 2011, 29(5): 389-397.
[11]	王维康, 郑美玲, 赵震声, 段宣明. 酸碱度对金纳米结构形貌的调控及其机理研究[J]. 影像科学与光化学, 2011, 29(3): 203-211.
[12]	陈学成, 王航, 张珅, 何溥, 贺军辉. 柔软的球状和长方体状氧化硅中空结构的制备研究[J]. 影像科学与光化学, 2010, 28(1): 59-64.
[13]	周林, 胡金梅, 郭祀远. B-藻红蛋白多层复合薄膜的静电组装及其光谱特性[J]. 影像科学与光化学, 2009, 27(1): 57-62.
[14]	杨朝晖, 张茂峰, 曹维孝. 聚-4-偶氮磺酸基苯乙烯与四-(三甲氨基苯基)-卟啉的自组装膜及其光电转换性能[J]. 影像科学与光化学, 2007, 25(2): 136-141.
[15]	陈东, 刘建树, 高继宁, 唐芳琼. 垂直排列法组装胶体晶体的最新进展[J]. 影像科学与光化学, 2005, 23(4): 281-288.

银纳米微球和银纳米棒自组装膜的制备及SERS研究

Preparation of Self-assembled Films of Silver Nanoparticles and Silver Nanorods for SERS Research

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价