基于主-客体相互作用的插层水滑石光敏特性研究

doi:10.7517/j.issn.1674-0475.2017.03.307

影像科学与光化学 ›› 2017, Vol. 35 ›› Issue (3): 307-315.DOI: 10.7517/j.issn.1674-0475.2017.03.307

基于主-客体相互作用的插层水滑石光敏特性研究

王心蕊¹, 唐丽萍¹, 李勇¹, 程慧敏¹, 于婷婷¹, 闫东鹏²

1. 北京工商大学北京市植物资源研究开发重点实验室, 北京 100048;
2. 北京师范大学化学学院, 北京 100875

收稿日期:2017-01-12 修回日期:2017-01-31 出版日期:2017-05-15 发布日期:2017-05-15
通讯作者: 王心蕊,闫东鹏
基金资助:
国家自然科学基金项目（21301012和21473013）和北京工商大学北京市植物资源研究开发重点实验室开放课题基金资助课题（PRRD-2016-YB5）

The Photosensitization Based on Host-guest Interactions in a Layered Double Hydroxide

WANG Xinrui¹, TANG Liping¹, LI Yong¹, CHENG Huimin¹, YU Tingting¹, YAN Dongpeng²

1. Beijing Key Lab of Plant Resource Research and Development, Beijing Technology and Business University, Beijing 100048, P.R. China;
2. Department of Chemistry, Beijing Normal University, Beijing 100875, P.R. China

Received:2017-01-12 Revised:2017-01-31 Online:2017-05-15 Published:2017-05-15

摘要/Abstract

摘要：

本文基于水滑石类插层材料（LDHs）特有的超分子结构及其功能可调控性，采用离子交换法成功合成了邻、间、对硝基苯甲酸阴离子（o-、m-、p-NBA-）插层的锌铝水滑石，并研究了插层产物的光敏性能。插层后这3种异构体化合物都在紫外光照射下表现出不同的光响应程度，即光敏作用：m-NBA-LDH>>o-NBA-LDH≈p-NBA-LDH。用PXRD、FTIR、UV/Vis和理论计算研究了光敏性能，并提出了可能的光敏机理，为其应用于新型感光材料提供了一定的理论基础。

关键词: 水滑石, 光敏现象, 超分子结构, 插层

Abstract:

The paper describes a systematic study on the synthesis of Zn-Al layered double hydroxides (LDHs). Different guest species intercalated LDHs have been synthesized by the methods of coprecipitation and ion exchange, respectively, such as o-, m-, p-nitrobenzoic acid. PXRD, FTIR, UV/Vis and theoretical calculation were used to study the photosensitivity, and the possible mechanism was proposed, which provides a theoretical basis and a prerequisite for the application of the new photosensitive materials.

Key words: layered double hydroxides, photochromism, supramolecular structure, intercalation

王心蕊, 唐丽萍, 李勇, 程慧敏, 于婷婷, 闫东鹏. 基于主-客体相互作用的插层水滑石光敏特性研究[J]. 影像科学与光化学, 2017, 35(3): 307-315.

WANG Xinrui, TANG Liping, LI Yong, CHENG Huimin, YU Tingting, YAN Dongpeng. The Photosensitization Based on Host-guest Interactions in a Layered Double Hydroxide[J]. Imaging Science and Photochemistry, 2017, 35(3): 307-315.

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基于主-客体相互作用的插层水滑石光敏特性研究

The Photosensitization Based on Host-guest Interactions in a Layered Double Hydroxide

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