影像科学与光化学 ›› 2017, Vol. 35 ›› Issue (5): 614-625.DOI: 10.7517/j.issn.1674-0475.2017.04.022

• 综述 • 上一篇    下一篇

可见光催化需氧氧化在有机合成中的应用

张庆宝, 刘强   

  1. 兰州大学 应用功能有机分化学国家重点实验室, 甘肃 兰州 730000
  • 收稿日期:2017-06-05 修回日期:2017-06-13 出版日期:2017-09-15 发布日期:2017-09-15
  • 通讯作者: 刘强
  • 基金资助:

    国家自然科学基金(21572090)和中央高校基本科研基金(lzujbky-2017-k05)资助

Applications of Visible-light-driven Aerobic Oxidation in Organic Synthesis

ZHANG Qingbao, LIU Qiang   

  1. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, Gansu, P. R. China
  • Received:2017-06-05 Revised:2017-06-13 Online:2017-09-15 Published:2017-09-15

摘要:

可见光催化作为一种新兴且强大的有机合成手段,具有洁净节能、优秀的官能团兼容性和良好的化学选择性等特征。氧气作为一种廉价、无污染的氧化剂,与可见光催化相结合,极大地促进了绿色化学的发展。本文主要对我们课题组近年来在可见光需氧氧化领域取得的成果做了简明的综述,并对其发展进行了展望。

关键词: 可见光催化, 需氧氧化, 绿色化学, 有机合成

Abstract:

Visible-light photoredox catalysis, which shows typical features of clean and energy-saving procedures, excellent functional group tolerance, and high chemical selectivities, is a novel and powerful organic synthesis method. As a cheap, ecologically benign oxidant, the combination of aerobic oxidation with visible-light photoredox catalysis greatly promotes the development of green chemistry. This review briefly summarizes recent achievements in the area of visible-light-driven aerobic oxidation by our laboratory and also give its outlook in the future.

Key words: visible-light photoredox catalysis, aerobic oxidation, green chemistry, organic synthesis