负载型纳米CdS制备及催化分解水制氢的研究进展

doi:10.7517/j.issn.1674-0475.2009.03.225

影像科学与光化学 ›› 2009, Vol. 27 ›› Issue (3): 225-232.DOI: 10.7517/j.issn.1674-0475.2009.03.225

负载型纳米CdS制备及催化分解水制氢的研究进展

曹莹^1,2, 白雪峰¹

1. 黑龙江省科学院, 石油化学研究院, 黑龙江, 哈尔滨150040;
2. 黑龙江大学, 化学化工与材料学院, 黑龙江, 哈尔滨, 150080

收稿日期:2008-08-15 修回日期:2008-11-03 出版日期:2009-05-23 发布日期:2009-05-23
通讯作者: 白雪峰,男,博士,研究员,主要从事工业催化方面研究.
基金资助:
国家863计划项目(2007AA03z337);黑龙江省杰出青年基金项目(JC200615);黑龙江省国际合作项目(WC05A13);哈尔滨市对俄科技合作项目(2006AA4BE053).

Progress in Research of Preparation of Loaded Nano-CdS and H₂ Production by Photocatalytic Decomposition of Water

CAO Ying^1,2, BAI Xue-feng¹

1. Institute of Petrochemistry, Heilongjiang Academy of Sciences, Harbin 150040, Heilongjiang, P.R.China;
2. School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, Heilongjiang, P.R.China

Received:2008-08-15 Revised:2008-11-03 Online:2009-05-23 Published:2009-05-23

摘要/Abstract

摘要： 硫化镉(CdS)是一种研究广泛的光催化剂,禁带能为2.4 eV,可以吸收波长小于520 nm的紫外和可见光,吸收波长范围宽,作为光催化剂具有较大的优势.纯CdS的光催化效率较低,在水溶液中易发生光腐蚀,致使催化寿命缩短,限制了CdS的应用.利用载体比表面积大,易于离子交换且有利于电子传递等优点,将纳米CdS制备成负载型催化剂,可以有效地提高CdS的光催化效率与稳定性,成为CdS改性的一种有效手段.本文综述了以SiO₂、Al₂O₃、MgO、分子筛、高分子材料、层状化合物及钙钛矿型复合氧化物等为载体,制备负载型纳米CdS光催化剂的方法及其在光催化分解水制氢中的应用.

关键词: 硫化镉(CdS), 负载型光催化剂, 分解水, 制氢

Abstract: Cadmium sulfide(CdS),which is a kind of visiblelight-response semiconductor catalyst with the band gap energy of 2.4 eV,is paid extensive attention in the field of photocatalytic reaction.The pure CdS is of low photocatalytic efficiency and easily photocorroded to lead to decrease its photocatalytic activity,which limit its application in the aqueous solution.It has been improved media for catalytic activity & stability of CdS semiconductor catalyst to load nano-CdS on the carriers with large specific surface area & easy exchange which prevent charger recombination.In this paper,preparation of nano-CdS loaded on SiO₂,Al₂O₃,MgO,zeolite,macromolecular materials & layered oxides and their applications in H₂ production of photocatalytic decomposition of water are summarized.

Key words: sadmium sulfide(CdS), loaded photocatalyst, water decomposition, hydrogen production

中图分类号:

曹莹, 白雪峰. 负载型纳米CdS制备及催化分解水制氢的研究进展[J]. 影像科学与光化学, 2009, 27(3): 225-232.

CAO Ying, BAI Xue-feng. Progress in Research of Preparation of Loaded Nano-CdS and H₂ Production by Photocatalytic Decomposition of Water[J]. Imaging Science and Photochemistry, 2009, 27(3): 225-232.

参考文献

[1] Fujishi ma A,Honda K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238(5358):37-38.
[2] Serpone N,Borgarello E,Gratzel M.Visible light induced generation of hydrogen from H₂Sin mixed semiconductordispersion:i mproved efficiency through inter-particle electron transfer[J].J.Chem.Soc.Chem.Commun.,1984,(6):342-344.
[3] Borgarello E,Serpone N,Gratzel M,et al.Hydrogen productionthrough microhetero geneous photocatalysis of hy-drogen sulfide cleavage:the thiosulfate cycle[J].Int.J.Hydrogen Energy,1985,10(11):737-741.
[4] Rufus I B,Viswanthan B,Ramakrishnan V,et al.Cadmiumsulfide withiridiumsulfide and platinumsulfide depositsas a photocatalyst for the decomposition of aqueous sulfide[J].J.Photochem.Photobiol.A,1995,91(1):63-66.
[5] Rufus I B,Viswanthan B,Ramakrishnan V,et al.Rhodiumand rhodiumsulfide coated cadmiumsulfide as a photo-catalyst for photochemical decomposition of aqueous sulfide[J].Langmuir,1990,6(3):565-567.
[6] Xing CJ,Zhang YJ,Yan W,et al.Bandstructure-controlledsolidsolution of Cd_1-xZn_xS photocatalyst for hydrogenproduction by water splitting[J].Int.J.Hydrogen Energy,2006,31(14):2018-2024.
[7] De G C,Roy A M,Bhattacharya S S.Effect of n-Si on the photocatalytic production of hydrogen by Pt-loaded CdSand CdS/ZnS catalyst[J].Int.J.Hydrogen Energy,1996,21(1):19-23.
[8] Jang J S,Li W,Oh S H,et al.Fabrication of CdS/TiO₂ nano-bulkcomposite photocatalystsfor aqueous H₂S solutionunder visible light[J].Chem.Phys.Lett.,2006,425(4-6):278-282.
[9] 王学华,曹宏,吕飞,等.La³⁺掺杂CdS/TiO₂ 复合膜的制备及性能表征[J].化学与生物工程,2006,22(6):40-42.Wang X H,Cao H,Lü F,et al.Preparation and photocatalytic properties of La³⁺-doped CdS/TiO₂ coupled thinfil ms[J].Chemistry&Bioengineering,2006,22(6):40-42.
[10] 邱炜,陈爱平,刘威,等.二氧化钛光催化剂的光敏化研究进展[J].现代化工,2004,24(S1):43-46.Qiu W,Chen AP,Liu W,et al.Advancesin photosensitization of titania semiconductor photocatalysts[J].ModernChemical Industry,2004,24(S1):43-46.
[11] Sobczynski A.Preparation and photocatalytic properties of silica-supported fine CdS powders[J].Monatshefte fürChemie,1992,123(3):211-216.
[12] Kakuka N,Park K H,Finlayson MF,et al.Photoassisted hydrogen production using visiblelight and copreclpitat-ed ZnS-CdS without a noble metal[J].J.Phys.Chem.,1985,89(5):732-734.
[13] 王芳,张鸟飞,金梅,等.Al₂O₃负载TiO₂ 光催化氧化剂的制备与性能试验[J].工业用水与废水,2007,38(4):88-94.Wang F,Zhang N F,Jin M,et al.Preparation of TiO₂ /Al₂O₃photocatalyst and oxidant and performance thereof[J].Industrial Water&Wastewater,2007,38(4):88-94.
[14] Arora M K,Sahu N,Sinha AS K,et al.Activity of cadmiumsulfide photocatalysts for hydrogen productionfromwater role of support[J].Ind.Eng.Chem.Res.,1999,38(7):2659-2665.
[15] Arora M K,Sahu N,Sinha AS K,et al.Alumina-supported cadmiumsulfide photocatalysts for hydrogen produc-tion from water role of dissolved ammonia in the i mpregnating solution[J].Ind.Eng.Chem.Res.,1999,38(12):4694-4699.
[16] Arora M K,Sinha A S K,Padhyay S N U.Effect of dispersion and distribution on activity of alumina-supportedcadmiumsulfide photocatalysts for hydrogen productionfrom water[J].Ind.Eng.Chem.Res.,1998,37(4):1310-1316.
[17] Subrahmanyam M,Supriya V T,Reddy P R.Photocatalytic H₂ production with CdS-based catalysts froma sul-phide/sulphite substrate:an effort to develop MgO-supportedcatalysts[J].Int.J.Hydrogen Energy,1996,21(2):99-106.
[18] Sathisha M,Viswanath R P.Photocatalytic generation of hydrogen over mesoporous CdS nanoparticle:Effect ofparticle size,noble metal and support[J].Catal.Today,2007,129(3-4):421-427.
[19] Ki m YI,Mallouk T E.Dynamic electron-transfer quenching of the tris(2,2’-bipyridyl)ruthenium(II)MLCTex-cited state byintrazeolitic methylviologenions[J].J.Phys.Chem.,1992,96(7):2879-2885.
[20] Corma A,Garcia H.Photoinduced electron transfer within zeolite cavities:cis-stilbene isomerization photosensitizedby 2,4,6-triphenylpyryliumcationi mprisonedinside zeolite[J].J.Am.Chem.Soc.,1994,116(6):2276-2280.
[21] 张向华,李文钊,徐恒泳.分子筛在光催化中的应用[J].化学进展.2004,16(4):728-737.Zhang X H,Li WZ,Xu HY.Application of zeolitesin photocatalysis[J].Process in Chemistry,2004,16(4):728-737.
[22] Landin R O,Acosta MF,Bon R R,et al.Characterization of CdSclustersinzeolite-Agrownin alkaline solution[J].J.Phys.Chem.Solids,2003,64(11):2245-2251.
[23] Peng H,Liu S M,Ma L,et al.Growing process of CdS nanoclusters in zeolite Ystudied by positron annihilation[J].J.Crystal Growth,2001,224(3-4):274-279.
[24] Ryu S Y,Balcerski W,Lee T K,et al.Photocatalytic production of hydrogen from water with visible light usinghybrid catalysts of CdS attached to microporous and mesoporous silicas[J].J.Phys.Chem.C,2007,111(49):18195-18203.
[25] Hirai T,Okubo H,Komasawa I.Size-selective incorporation of CdS nanoparticles into mesoporous silica[J].J.Phys.Chem.B,1999,103(21):4228-4230.
[26] Hwang YJ,Ki mS J,Park S,et al.Photoactivity of CdS particles grownin Pt-loaded zeolite Y[J].Bull.KoreanChem.Soc.,2000,21(2):187-192.
[27] Guan G Q,Kida T,Kusakabe K,et al.Photocatalytic H₂ evolution under visible light irradiation on CdS/ETS-4composite[J].Chem.Phys.Lett.,2004,385(3-4):319-322.
[28] Guan G Q,Kida T,Kusakabe K,et al.Photocatalytic activity of CdS nanoparticlesincorporatedintitaniumsilicatemolecular sieves of ETS-4 and ETS-10[J].Appl.Catal.,A,2005,295(1):71-78.
[29] Shen S,Guo L.Growth of quantum-confined CdS nanoparticles inside Ti-MCM-41 as a visible light photocatalyst[J].Mater.Res.Bull.,2008,43(2):437-446.
[30] Mau A WH,Huang C B,Kakuta N,et al.H₂photoproduction by Nafion/CdS/Pt fil msin H₂O/S^2- solutions[J].J.Am.Chem.Soc.,1984,106(22):6537-6542.
[31] Kanadea K G,Baegc J O,Kale B B,et al.Nano-CdS by polymer-inorganic solid-state reaction:Visiblelight pristinephotocatalyst for hydrogen generation[J].Mater.Res.Bull.,2006,41(12):2219-2225.
[32] 桑丽霞,刘宇,李群伟,等.纳米钙钛矿型复合氧化物LaFeO₃光催化分解水制氢[J].中国稀土学报,2006,24(S1):42-45.Sang L X,Liu Y,Li Q W,et al.Photocatalytic hydrogen evolutionfrom water over nano perovskite oxides LaFeO₃[J].Journal ofthe Chinese Rare Earth Society,2006,24(S1):42-45.
[33] 桑丽霞,李群伟,胥利先,等.掺杂Cu²⁺对钙钛矿型LaFeO₃光分解水制氢性能的影响[J].西安交通大学学报,2008,42(5):626-629.Sang L X,Li Q W,Xu L X,et al.Effect of doping Cu²⁺on photocatalytic activity of perovskite oxides LaFeO₃forhydrogen evolution from water[J].Journal of Xi’an Jiao Tong University,2008,42(5):626-629.
[34] 张莉莉,陆路德.无机层状化合物及其应用评述[J].化工新型材料,2004,32(3):1-4.Zhang L L,Lu L D.Reviewoninorganiclayered compoundinorganiclayered compound andits application[J].NewChemical Materials,2004,32(3):1-4.
[35] 上管文峰.太阳能光解水制氢的研究进展[J].无机化学学报,2001,17(5):619-626.Shangguan WF.Progress in research of hydrogen production from water on photocatalysts with solar energy[J].Chinese Journal ofInorganic Chemistry,2001,17(5):619-626.
[36] Shangguan WF.Photocatalytic hydrogen evolutionfrom water on nanocompositesincorporatingcadmiumsulfideintothe interlayer[J].J.Phys.Chem.B,2002,106(47):12227-12230.
[37] Shangguang WF,Yoshida A.Synthesis and photocatalytic properties of CdS-intercalated metal oxides[J].Sol.Energy Mater.Sol.Cells,2001,69(1):189-194.
[38] Kida T,Guan G,Yoshida A.LaMnO₃/CdS nanocomposite:a newphotocatalyst for hydrogen productionfrom waterunder visible light irradiation[J].Chem.Phys.Lett.,2003,371(5-6):563-567.
[39] Gates B C.Supported metal clusters:synthesis,structure,and catalysis[J].Chem.Rev.,1995,95(3):511-522.

负载型纳米CdS制备及催化分解水制氢的研究进展

Progress in Research of Preparation of Loaded Nano-CdS and H₂ Production by Photocatalytic Decomposition of Water

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负载型纳米CdS制备及催化分解水制氢的研究进展

Progress in Research of Preparation of Loaded Nano-CdS and H2 Production by Photocatalytic Decomposition of Water

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Progress in Research of Preparation of Loaded Nano-CdS and H₂ Production by Photocatalytic Decomposition of Water