掺P25水热法制备纳晶多孔TiO2薄膜电极

doi:10.7517/j.issn.1674-0475.2008.06.499

影像科学与光化学 ›› 2008, Vol. 26 ›› Issue (6): 499-506.DOI: 10.7517/j.issn.1674-0475.2008.06.499

掺P25水热法制备纳晶多孔TiO₂薄膜电极

张秀坤, 吴季怀, 李树全, 徐波, 李彪, 李品将, 兰章, 黄妙良, 林建明, 范乐庆

华侨大学, 材料物理化学研究所, 福建, 泉州, 362021

收稿日期:2008-03-24 修回日期:2008-05-12 出版日期:2008-11-23 发布日期:2008-11-23
通讯作者: 吴季怀,E-mail:jhwu@hqu.edu.cn.
基金资助:
国家自然科学基金资助项目(50572022,50372030);教育部科学技术研究重点项目(206074);福建省自然科学基金资助项目(E0640003,E0210023,E0110026)

Preparation of Nano-crystalline TiO₂ Porous Film Electrode Using a Mixing P25 Hydrothermal Method

ZHANG Xiu-kun, WU Ji-huai, LI Shu-quan, XU Bo, LI Biao, LI Pin-jiang, LAN Zhang, HUANG Miao-liang, LIN Jian-ming, FAN Le-qing

College of Materials Science and Engineering, Huaqiao University, Quanzhou 362021, Fujian, P. R. China

Received:2008-03-24 Revised:2008-05-12 Online:2008-11-23 Published:2008-11-23

摘要/Abstract

摘要： 以水热法为基础,向其溶胶中掺入适量的P25(二氧化钛粉体),来制备纳晶TiO₂胶体,以纳晶TiO₂为电子传输体组装染料敏化太阳能电池.通过XRD、SEM、UV-vis和电池的光电性能测试,来分析掺入P25对染料敏化太阳能电池性能的影响.结果表明,加入适量P25([P25]/[Ti]=0.2)后,染料敏化太阳能电池性能达到最佳值,在100 mW/cm²光照条件下,光电转换效率达到5.4%.

关键词: 水热法, 纳晶TiO₂, 染料敏化太阳能电池

Abstract: Nano-crystalline titanium dioxide (TiO₂) colloid was prepared from mixing TiO₂ nano-crystalline P25 to sol by hydrothermal method.Using the nano-crystalline TiO₂ as the electron transmission medium,a dye-sensitized solar cell (DSSC) was assembled.The influence of amount of mixing P25 on the photoelectronic properties of the DSSC was confirmed by XRD pattern,SEM ob-servation,UV-vis spectra,and I-V curve of the solar cells.The results show that when mixing proper P25 ([P25]/[Ti]=0.2) to sol,the photoelectric performance of the DSSC is the best.The photoelectric conversion efficiency with the film electrode could be 5.4% irradiated by a solar simu-lator with 100 mW/cm².

Key words: hydrothermal method, nano-crystallne TiO₂, dye-sensitized solar cell

中图分类号:

张秀坤, 吴季怀, 李树全, 徐波, 李彪, 李品将, 兰章, 黄妙良, 林建明, 范乐庆. 掺P25水热法制备纳晶多孔TiO₂薄膜电极[J]. 影像科学与光化学, 2008, 26(6): 499-506.

ZHANG Xiu-kun, WU Ji-huai, LI Shu-quan, XU Bo, LI Biao, LI Pin-jiang, LAN Zhang, HUANG Miao-liang, LIN Jian-ming, FAN Le-qing. Preparation of Nano-crystalline TiO₂ Porous Film Electrode Using a Mixing P25 Hydrothermal Method[J]. Imaging Science and Photochemistry, 2008, 26(6): 499-506.

参考文献

[1] O'Regan B,Gratzel M.Low-cost high-efficiency solar cell based on dye-sensitized colloidal TiO₂ films[J].Nature.,1991,353:737-740.
[2] Barbe C J,Arendse F,Gratzel M,et al.Nanocrystslline titaniumoxide elecrodes for photovoltaic applications[J].J.Am.Ceram.Soc.,1997,80:3157-3171.
[3] 孔海霞,孙彦平,武爱莲.TiO₂薄膜光电极能带结构和催化活性的初探[J].感光科学与光化学(影像科学与光化学),2004,22(5):327-332.KONG HX,SUN YP,WU A L.Preliminary study on band structure of TiO₂ thin photoelectrode and catslytic activity[J].Photographic Science and Photochemistry(Imaging Sicnce and Photochemistry),2004,22(5):327-323.
[4] 李斌,邱勇.染料敏化纳米太阳能电池[J].感光科学与光化学(影像科学与光化学),2000,18:336-347.LI B,QIU Y.Dye-sensitized nano-crystalline solar cell[J].Photographic Science and Photochemistry(Imaging Science and Photochemistry),2000,18:336-347.
[5] 兰鼎,罗欣莲,万发荣,等.TiO₂薄膜的制备方法及其对染料敏化太阳能电池性能的影响[J].感光科学与光化学(影像科学与光化学),2003,21:262-272.LAND,LUO X L,WAN FR,et al.The method to prepare TiO₂ film.and its effect on the behaviour of dye-sensitized solar cell[J].Photographic Science and Photochemistry(Imaging Science and Photochemistry),2003,21:262-272.
[6] Nakade S,Kubo W,Saito Y,et al.Electron density and dye adsorption dependence of electron transport in dye-sensitized TiO₂ solar Cell[J].Proc.of SPIE,2004,5215:24-31.
[7] Nazeruddin M K,Kay A,et al.Conversion of light to electricity by cis-X2 bis(2,2'-bipyridyl-4,4'-dicarboxylate) ruthenium(Ⅱ) charge-transfer sensitizers (X=Cl^-,Br^-,I^-,CN^-,and SCN^-) on nanacrystalline TiO₂ electrodes[J].J.Am.Ceram.Soc.,1993,115:6382.
[8] 范乐庆,吴季怀,黄昀昉,等.染料敏化太阳能电池的二氧化钛膜性能研究[J].感光科学与光化学(影像科学与光化学),2003,21:231-237.FAN L Q,WU J H,HUANGYF,et al.Study on properties of dye-sensitized TiO₂ films[J].Photographic Science and Photochemisry(Imaging Science and Photochemistry),2003,21:231-237.
[9] 王东波,吴季怀,郝三存,等.纳米二氧化钛的水热法制备及在染料敏化太阳能电池中的应用[J].感光科学与光化学(影像科学与光化学),2006,24:173-179.WANG D P,WU J H,HAO S C,et al.Preparation nano-TiO₂ by hydrothermal method arid its application in dye-sensitized solar cell[J].Photographic Science and Photochemistry(Imaging Science and Photochemistry),2006,24:173-179.
[10] 郝三存,吴季怀,林建明,等.铂修饰光阴极及其在纳晶太阳能电池中的应用[J].感光科学与光化学(影像科学与光化学),2004,22:175-181.HAO S C,WU J H,LIN J M,et al.Modification of photocathode with platinum and its application in dye-semitized solar cell[J].Photographic Science and Photochemistry(Imaging Science and Photochemistry),2004,22:175-181.
[11] Gratzel M.Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells[J].J.Photoch.Photobio.A,2004,164:3-14.
[12] 黄春辉,李富友,黄岩谊.光电功能超薄膜[M].北京:北京大学出版社,2001.383-384.HUANG C H,LI F Y,HUANG Y Y.Ultrathin Film for Optics and Electronics[M].Beijing:Peking University Press,2001.383-384.
[13] Hore S,Nitz P,Vetter C,et al.Scattering Spherical Voids in nancrystailine TiO₂-enchancement of efficienc-y in dye-sensitized solar cells[J].Chem.Commun.,2005,20011-2013.
[14] 范乐庆,吴季怀,黄昀昉,等.染料敏化太阳能电池中电子的传输性能[J].太阳能学报,2005,26:35-38.FAN L Q,WU J H,HUANG Y F,et al.Study on the nature of electron migration in dye-sensitized solar cells[J].Solar Energy Journal,2005,26:35-38.

掺P25水热法制备纳晶多孔TiO₂薄膜电极

Preparation of Nano-crystalline TiO₂ Porous Film Electrode Using a Mixing P25 Hydrothermal Method

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 13

编辑推荐

Metrics

本文评价

[1]	赵雪, 裴娟, 李英品. 不同受体结构染料共敏化对染料敏化太阳电池性能的影响[J]. 影像科学与光化学, 2019, 37(6): 525-535.
[2]	徐红霞, 王在伟, 张传健, 崔光磊. CoSe/TiN同轴纳米管阵列在染料敏化太阳能电池对电极中的应用研究[J]. 影像科学与光化学, 2017, 35(5): 758-764.
[3]	张美林, 金峰, 郑美玲, 刘洁, 段宣明. 水热法生长方式对ZnO纳米棒阵列结构和性能的影响[J]. 影像科学与光化学, 2015, 33(2): 136-143.
[4]	李海洋, 张敬波, 魏刚, 孙丽娜, 林原, 付国柱. 电沉积法制备固态染料敏化太阳能电池[J]. 影像科学与光化学, 2014, 32(6): 514-522.
[5]	李波, 黄忠兵, 孟宪伟, 唐芳琼. L-半胱氨酸改性Fe₃O₄纳米粒子的水热合成及其应用[J]. 影像科学与光化学, 2014, 32(2): 163-170.
[6]	李海燕, 钱俊杰, 刘金凤, 李秋叶, 张敏, 杨建军. 氮铋共掺杂TiO₂的合成及其可见光催化性能研究[J]. 影像科学与光化学, 2013, 31(6): 411-420.
[7]	方艳艳, 林原. 离子液体基聚合物的结构对染料敏化太阳能电池性能的影响研究[J]. 影像科学与光化学, 2013, 31(6): 430-439.
[8]	吴世康, 汪鹏飞. 功能染料在有机太阳能电池中的应用[J]. 影像科学与光化学, 2010, 28(3): 217-229.
[9]	何立, 刘博, 陈宇, 朱为宏. 新型含有多氰基受体单元的近红外敏化染料的合成及其光伏性能研究[J]. 影像科学与光化学, 2010, 28(2): 137-146.
[10]	张阳, 曾庆慧, 只金芳. 过氧化钛配合物(PTC)体系在柔性染料敏化太阳能电池中的应用[J]. 影像科学与光化学, 2009, 27(6): 418-426.
[11]	张凤, 陶杰, 陶海军, 董祥. 柔性TiO₂纳米管薄膜电极的制备及其光电性能[J]. 影像科学与光化学, 2008, 26(3): 224-232.
[12]	李胜军, 林原, 杨世伟, 陈今茂, 肖绪瑞. 染料敏化太阳能电池TiO₂电极的制备及电解质的影响[J]. 影像科学与光化学, 2008, 26(1): 54-59.
[13]	王东波, 吴季怀, 郝三存, 兰章, 杨宏训. 纳米二氧化钛的水热法制备及在染料敏化太阳能电池中的应用[J]. 影像科学与光化学, 2006, 24(3): 173-179.