三缩乙二醇双甲基丙烯酸酯超低温紫外光聚合

doi:10.7517/j.issn.1674-0475.2005.05.321

影像科学与光化学 ›› 2005, Vol. 23 ›› Issue (5): 321-326.DOI: 10.7517/j.issn.1674-0475.2005.05.321

• 研究快讯 • 下一篇

三缩乙二醇双甲基丙烯酸酯超低温紫外光聚合

吕波, 聂俊

武汉大学, 化学与分子科学学院, 湖北, 武汉, 430072

收稿日期:2005-04-25 修回日期:2005-05-12 出版日期:2005-09-23 发布日期:2005-09-23
通讯作者: 聂俊(1965-), 男, 教授, 博士生导师, 主要从事光聚合、高分子材料、生物材料的研究.
基金资助:
国家自然科学基金资助项目(50473024),SRF for ROCS,SEM支持项目.

Super-Low Temperature UV Polymerization of TEGDMA

LÜ Bo, NIE Jun

College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, Hubei, P.R. China

Received:2005-04-25 Revised:2005-05-12 Online:2005-09-23 Published:2005-09-23

摘要/Abstract

摘要： 利用近红外技术(NIR)研究三缩乙二醇双甲基丙烯酸酯在不同温度下紫外光聚合动力学过程.结果表明,聚合温度越低,转化率越低,但暗反应过程显著.同时,不同温度下光固化产物的DMTA测试表明,20、0、-20和-40℃时光固化高分子膜的DMTA变化曲线近乎一致,而温度下降到-60℃、-75℃,lgE′和T_g急剧下降;不同温度下固化高分子的α松弛峰均很宽,说明树脂内部交联程度不均匀.

关键词: 超低温, 光聚合, 暗反应, 近红外技术

Abstract: TEGDMA was polymerized by UV radiation at different temperatures; polymerization conversion and dark reaction process were investigated by NIR spectroscopy. Results indicated that, when the polymerization temperature is lower, the conversion is lower but the dark reaction process is more distinct. DMTA results showed that, DMTA curves of samples polymerized at 20, 0,(-20,) and -40 ℃ are similar, however, lgE′ and T_g decrease with the continuous descent of temperature. The results also indicated that all α relaxed peaks are wide, which illuminates that the degree of crosslink are uniform in all films polymerized at different temperatures.

Key words: super-low temperature, photopolymerization, dark reaction, NIR spectroscopy

中图分类号:

TQ57

吕波, 聂俊. 三缩乙二醇双甲基丙烯酸酯超低温紫外光聚合[J]. 影像科学与光化学, 2005, 23(5): 321-326.

LÜ Bo, NIE Jun. Super-Low Temperature UV Polymerization of TEGDMA[J]. Imaging Science and Photochemistry, 2005, 23(5): 321-326.

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三缩乙二醇双甲基丙烯酸酯超低温紫外光聚合

Super-Low Temperature UV Polymerization of TEGDMA

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