Third-Order Nonlinear Optical Properties of Croconium Dye for a Kind of Near Infrared Dye Used as Optical Record and Storage Material

doi:10.7517/j.issn.1674-0475.2007.04.241

Imaging Science and Photochemistry ›› 2007, Vol. 25 ›› Issue (4): 241-248.DOI: 10.7517/j.issn.1674-0475.2007.04.241

Third-Order Nonlinear Optical Properties of Croconium Dye for a Kind of Near Infrared Dye Used as Optical Record and Storage Material

LI Zhong-Yu^1,2, XU Song³, HUANG Xin¹, ZHANG Fu-shi¹, Kazuo Kasatani⁴

1. The Key Lab.of Organic Photoelectrons & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P.R. China;
2. Department of Chemical Engineering, Jilin Institute of Chemical Technology, Jilin 132022, P.R.China;
3. Department of Application Technology, Northeast China University of Electric Power Engineering, Jilin 132021, Jilin, P.R.China;
4. Department of Advanced Materials Science and Engineering, Faculty of Engineering, Yamaguchi University, Tokiwadai, Ube 755-8611, Japan

Received:2006-10-13 Revised:2006-12-22 Online:2007-07-23 Published:2007-07-23

Abstract

Abstract: As a new type of near infrared dye,croconium dyes have drawn much attention for their potential applications in the fields of optical record and storage,and nonlinear optical materials because of their thermal and optical stability as well as intense fluorescence.The third-order optical nonlinearities and responses of a croconium dye(1,3-bis[(3,3-dimethylindolin-2-ylidene)methyl] croconine) in tetrahydrofuran(THF) solution and in poly(methyl methacrylate)(PMMA) coating films were measured using a femtosecond degenerate four-wave mixing(DFWM) technique with a laser pulse of 130 fs system under resonant conditions.The molecular hyperpolarizability,γ of the croconium dye in THF solution was determined to be about 5.3×10^-29 esu,and the third-order nonlinear optical susceptibilities,χ⁽³⁾ of the present PMMA coating films containing the croconium dye was measured to be of the order of 10^-8 esu.Furthermore,the dynamic of DFWM optical response for croconium dye was also studied and analysed.

Key words: nonlinear optics, optical record and storage, croconium dye, near infrared absorption

CLC Number:

TQ57

LI Zhong-Yu, XU Song, HUANG Xin, ZHANG Fu-shi, Kazuo Kasatani. Third-Order Nonlinear Optical Properties of Croconium Dye for a Kind of Near Infrared Dye Used as Optical Record and Storage Material[J]. Imaging Science and Photochemistry, 2007, 25(4): 241-248.

References

[1] Yasui S,Matsuoka M,Kitao T.Syntheses and some properties of infrared-absorbing croconiumand related dyes[J].Dyes and Pigments,1988,10:13-22. [2] Li Z,Jin Z,Kasatani K,Okamoto H,Takenaka S.Large third-order optical nonlinearities of a croconiumdyeinte-trahydrofuran solution andin poly(methyl methacrylate)coating fil ms measured using resonant femtosecond degener-ate four-wave mixing technique[J].Jpn.J.Appl.Phys.,2005,44:4956-4961.
[3] Keil D,Hartmann H,Reichardt C.Synthesis and spectroscopic characterization of new NIR absorbing(2-thienyl)-and(4-dialkylaminoaryl)-substituted crconic acid dyes[J].Liebigs.Ann.Chem.,1993,935-939.
[4] Li Z,Jin Z,Kasatani K,Okamoto H,Takenaka S.Resonant enhancement of third-order nonlinear optical propertyinJ-like aggregates of a cyanine dye[J].Phys.Stat.Sol.B,2005,242:2107-2112.
[5] Pang Y,Prasad P N.Photoinduced processes andresonant third-order nonlinearityin poly(3-dodecylthiophene)stud-ied by femtosecond ti me resolved degenerate four wave mixing[J].J.Chem.Phys.,1990,93:2201-2204.
[6] Wong KS,Han S G,Vardeny Z V.Femtosecond degenerate four wave mixing studies of third order electronic non-linearities in conjugated polymers[J].Synth.Met.,1991,43:3209-3212.
[7] Wong KS,Han S G,Vardeny Z V.Femtosecond dynamics of the nonlinear optical response in polydiethynylsilane[J].Appl.Phys.Lett.,1991,58:1695-1697.
[8] Ji W,Tang S H,Xu G Q,H.Chan S O,Ng S C,Ng W W.Resonant optical nonlinearity of fullerenesinfree-stand-ing polymethyl methacrylate fil ms[J].J.Appl.Phys.,1993,74:3669-3672.
[9] Samoc M,Prasad P N.Dynamics of resonant third-order optical nonlinearity in perylene tetracarboxylic dianhydridestudied by monitoringfirst-andsecond-order diffractioninsubpicosecond degenerate four-wave mixing[J].J.Chem.Phys.,1989,91:6643-6649.
[10] Grund A,Kaltbeitzel A,Mathy A,Schwarz R,Bubeck C.Resonant nonlinear optical properties of spin-cast fil ms ofsoluble Oligomeric Bridged Phthalocyaninatoruthenium(II)complexes[J].J.Phys.Chem.,1992,96:7450-7454.
[11] Li Z,Jin Z,Kasatani K,Okamoto H.Large third-order optical nonlinearity and fast response of a squaryliumdye[J].Chin.Phys.Lett.,2005,22:2282-2285.
[12] Fu G,Yoda K,Kasatani K,Okamoto H,Takenaka S.Third-order optical nonlinearities of naphthalocyanine-deriva-tive-doped polymer fil ms measured by resonant femtosecond degenerate four-wave mixing[J].Jpn.Appl.Phys.,2005,44:3945-3950.

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Third-Order Nonlinear Optical Properties of Croconium Dye for a Kind of Near Infrared Dye Used as Optical Record and Storage Material

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