Imaging Science and Photochemistry ›› 2017, Vol. 35 ›› Issue (5): 658-666.DOI: 10.7517/j.issn.1674-0475.2017.04.026

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Advances in Catalytic Isomerization of Olefins and Theirs Derivatives

QIN Fangli1, AI Guanya1,2, MA Wangjing2, XIE Jinpeng2,3, LI Zhi2, YANG Xinmin2   

  1. 1. College of Science, China University of Petroleum, Beijing 102249, P. R. China;
    2. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
    3. Shanxi Agricultural University, Taigu 030801, Shanxi, P. R. China
  • Received:2017-06-05 Revised:2017-06-13 Online:2017-09-15 Published:2017-09-15

Abstract:

C=C double bond isomerization (DBI) is a method for synthesizing new organic compounds from olefins and theirs derivatives, which was based on C=C migration along carbon chain and cis/trans transform, and it plays an important role in the fields of organic synthesis, synthesis of daily chemicals, raw oil's development and synthesis of natural products and so on. In this paper, advances of five types of catalytic methods for DBI of olefins and its derivatives since 1960s were discussed in detail; Based on his recent work, the author mainly introduces application and development of photo catalysis in DBI of olefins and theirs derivatives.

Key words: olefins, double bond, isomerization, photocatalyst