Effect of Monomer Structure on Oxygen Inhibition of UV-Curing

doi:10.7517/j.issn.1674-0475.2013.04.004

Abstract

Abstract:

UV-curing of TMPTA and different ethoxylated TMPTA was studied respectively in air or nitrogen by UV-DSC.The oxygen inhibition in initial stage of curing was evaluated by the difference of the time when the curing rate growing fastest in different condition. The influence of the number of α-H in monomer and the monomer flow characteristics on oxygen inhibition was studied. The result shows that oxygen inhibition can be remitted by increasing the number of the ethyoxyls in monomer. Oxygen inhibition is related to the number of α-H and monomer viscosity.

Key words: UV-curing, UV-DSC, oxygen inhibition, α-H, viscosity

CLC Number:

QIAN Xia-qing, WANG De-hai, LI Heng. Effect of Monomer Structure on Oxygen Inhibition of UV-Curing[J]. Imaging Science and Photochemistry, 2013, 31(4): 276-285.

References

[1] 王德海, 江棂. 紫外光固化材料——理论与应用[M]. 北京: 科学出版社, 2001. 74-75. Wang D H,Jiang L. Theory and Application of UV-Curing Material[M]. Beijing: Science Press,2001. 74-75.

[2] Studer K, Decker C, Beck E, et al. Overcoming oxygen inhibition in UV-curing of acrylate coatings by carbon dioxide inerting: Part II[J]. Progress in Organic Coatings, 2003, 48(1): 101-111.

[3] 袁慧雅,黄曾,杨陈. 烯丙基醚改性光固化聚氨酯丙烯酸酯[J]. 应用化学, 2003, (8): 744-748. Yuan H Y,Huang Z,Yang C. Allyl ether modified UV curable polyurethane-acrylate resins[J]. Applied Chemistry, 2003,(8):744-748.

[4] 王永祯,王爱玲,许并社. 光固化成型材料中光引发剂对固化性能的影响研究[J]. 材料热处理学报, 2007: 314-318. Wang Y Z,Wang A L,Xu B S. Study on the influence of photoinitiator on the solidify performance of molding materials by UV[J].Transactions of Materials and Heat Treatment, 2007: 314-318.

[5] Biswal D, Hilt J Z. Analysis of oxygen inhibition in photopolymerizations of hydrogel micropatterns using FTIR imaging[J]. Macromolecules, 2009, 42(4): 973-979.

[6] Okadam, Iwasa M, Miyake H, et al. Evaluation of oxygen inhibition for UV-curable resins by adhesion force measurement using scanning probe microscope[J]. Journal of Vacuum Science and Technology B: Microelectronics and Nanometer Structures, 2010, 28(6): C6M17-C16M22.

[7] Bentivoglio Ruiz C S, Machado L D B, Volponi J E, et al. Oxygen inhibition and coating thickness effects on UV radiation curing of weatherfast clearcoats studied by photo-DSC[J]. Journal of Thermal Analysis and Calorimetry, 2004, 75(2): 507-512.

[8] Wight F R. Oxygen Inhibition of acrylic photopolymerization[J]. Journal of Polymer Science: Polymer Letters Edition, 1978, 16(3): 121-127.

[9] Loo-teck N, Sonny J N. Effects of light intensity and temperature on degree of conversion in free radical induced polymerisation[J]. RadTech Asia 2001-Proceedings of the 8th International Conference on Radiation Curing, 2001: 233-239.

[10] Rudolf R.热固性树脂[M]. 陆立明译.上海:东华大学出版社, 2009.108. Rudolf R.Thermosets[M]. translated by Lu L M. Shanghai:Donghua University Press,2009.108.

[11] Maffezzoli A, Terzi R. Effect of irradiation intensity on the isothermal photopolymerization kinetics of acrylic resins for stereolithography[J]. Thermochimica Acta, 1998, 321(1-2): 111-121.

[12] 潘祖仁. 高分子化学[M]. 第4版.北京:化学工业出版社, 2008.84-85. Pan Z R. Polymer Chemistry[M]. 4th ed.Beijing:Chemical Industry Press, 2008.84-85.

[13] Lee T Y, Guymon C A, Jonsson E S, et al. The effect of monomer structure on oxygen inhibition of (meth)acrylates photopolymerization[J]. Polymer, 2004, 45(18): 6155-6162.

[14] 高鸿宾. 有机化学[M]. 第4版.北京:高等教育出版社, 2005. Gao H B. Organic Chemistry[M]. 4th ed. Beijing:Higher Education Press,2005.

[15] Audouin L, Gueguen V, Tcharkhtchi A, et al. Close loop mechanistic schemes for hydrocarbon polymer oxidation[J]. Journal of Polymer Science Part A-Polymer Chemistry, 1995, 33(6): 921-927.

[16] 张南哲. 叔胺对UV固化胶表面氧阻聚抑制作用的研究[J]. 精细石油化工, 2005,(1): 23-25. Zhang N Z.Research on the function of tertiary amine to depress the polymerization due to surface oxygen in UV-curing adhesive[J].Speciality Petrochemical,2005,(1):23-25.

[17] O'brien A K, Cramer N B, Bowman C N.Oxygen inhibition in thiol-acrylate photopolymerizations[J]. Journal of Polymer Science, Part A: Polymer Chemistry, 2006, 44(6): 2007-2014.

[18] Barbot E, Seyssiecq I, Roche N, et al. Inhibition of activated sludge respiration by sodium azide addition: Effect on rheology and oxygen transfer[J]. Chemical Engineering Journal, 2010, 163(3): 230-235.

[19] 何曼君,张红东,陈维孝,等. 高分子物理[M].第3版.上海:复旦大学出版社, 2007.128-129. He M J,Zhang H D,Chen W X, et al. Polymer Physics[M]. 3rd ed. Shanghai:Fudan University Press,2007.128-129.