Imaging Science and Photochemistry ›› 2016, Vol. 34 ›› Issue (5): 475-481.DOI: 10.7517/j.issn.1674-0475.2016.05.475

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Metal-modified Coal-based Graphene Composites and the Photocatalytic Performance

ZHANG Yating1, LI Keke1, REN Shaozhao1, WANG Daiyu1, ZHOU Anning1, QIU Jieshan2   

  1. 1. College of Chemistry & Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, Shaanxi, P. R. China;
    2. Carbon Research Laboratory, State Key Lab of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, P. R. China
  • Received:2016-08-03 Revised:2016-08-10 Online:2016-09-15 Published:2016-09-15

Abstract:

In this paper, we report a facile hydrothermal method toward in situ growth of ultradispersed CuO/TiO2 nanoparticles on coal-based graphene composites (CTG). The structure and morphology of composite materials were characterized by XRD, SEM and TEM, respectively. Then, the photocatalytic performance of CTG was evaluated based on photocatalytic reduction of CO2 to methanol under visible light irradiation. The results showed that the yield of product methanol was highest when Cu contained in CuO/TiO2/coal-based graphene composite was 2%(mass fraction) which showed a 5 fold increase in methanol production activity (94.79 μmol/g.cat) in comparison with coal-based graphene(19.05 μmol/g.cat) under the same conditions.

Key words: coal-based graphene, composites, photocatalytic, carbon dioxide