Dissolving and Electro-Chemical Deposition of Copper Phthalocyanine

doi:10.7517/j.issn.1674-0475.2011.02.114

Imaging Science and Photochemistry ›› 2011, Vol. 29 ›› Issue (2): 114-122.DOI: 10.7517/j.issn.1674-0475.2011.02.114

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Dissolving and Electro-Chemical Deposition of Copper Phthalocyanine

QIAN Ling-feng, ZHANG Jia, XUE Min-zhao, ZHU Yuan-yuan, ZHANG Qing, LIU Yan-gang

School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai 200240, P.R.China

Received:2010-11-29 Revised:2011-01-14 Online:2011-03-23 Published:2011-03-23

Abstract

Abstract: In order to obtain the ideal Copper Phthalocyanine(CuPc) film from organic solution,first,we studied the solubility of CuPc in different solvents,and the effect of various amounts of trifluoroacetic acid(TFAA) to CuPc;Second,we fabricated CuPc films with different electro-chemical deposition conditions,and discussed the changes of the surface morphology.Then using the UV-Vis to measure the spectrum of copper phthalocyanine(CuPc) in four different organic solvents;using the scanning electron microscopy(SEM) to observe the surface morphology of CuPc films.The results showed that: after adding TFAA,CuPc is easily dissolved in both nitro-methane and chloroform,but in chloroform,it is more easily protonated;the amount of TFAA and CuPc has great influence to the surface morphology.

Key words: copper phthalocyanine, trifluoroacetic acid, electro-chemical deposition

CLC Number:

QIAN Ling-feng, ZHANG Jia, XUE Min-zhao, ZHU Yuan-yuan, ZHANG Qing, LIU Yan-gang. Dissolving and Electro-Chemical Deposition of Copper Phthalocyanine[J]. Imaging Science and Photochemistry, 2011, 29(2): 114-122.

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Dissolving and Electro-Chemical Deposition of Copper Phthalocyanine

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