Study on UV-curing Properties of Phenyl Glycidyl Ether Acrylate Modified by Nano-SiO2

doi:10.7517/issn.1674-0475.190410

Abstract

Abstract: A new photosensitive prepolymer phenyl glycidyl ether acrylate (PGEA) was synthesized from phenyl glycidyl ether (PGE) and acrylic acid (AA) as raw materials, triphenylphosphine as the catalyst and 4-methoxy phenol as the inhibitor. Then, nano-SiO₂ was treated with cetyltrimethylammonium bromide and surface-modified with silane coupling agent γ-meth-acryloxypropyltrimethoxysilane (KH-570), and added to the synthetic prepolymer PGEA, formulated as UV nanocomposite coating.By scanning electron microscopy (SEM) observation, it was found that the dispersion of modified nano-SiO₂ was better when its content of the coating was less than 5%. Scanning atomic force microscope (AFM) observation showed that the surface of curing film was smooth. And the modified nano-SiO₂ in a appropriate amount can improve the tensile strength, elongation and impact strength of the UV-curing materials.

Key words: UV-curing, phenyl glycidyl ether acrylate, nano-SiO₂, silane coupling agent

WU Baolin, HUANG Biwu, DU Zhipeng, YONG Tao, HAN Linlin. Study on UV-curing Properties of Phenyl Glycidyl Ether Acrylate Modified by Nano-SiO₂[J]. Imaging Science and Photochemistry, 2019, 37(4): 304-314.

References

[1] Decker C, Keller L, Zahouily K, Benfarhi S. Synthesis of nanocomposite polymers by UV-radiation curing[J]. Polymer, 2005,46(17):6640-6648.
[2] Roppolo I, Debasu M L, Ferreira R A S, Rocha J, Carlos L D, Sangermano M. Photoluminescent epoxy/Gd₂O₃:Eu³⁺ UV-cured nanocomposites[J]. Macromolecular Materials & Engineering, 2013,298(2):181-189.
[3] Otsuhata T, Toyota K, Hirabaru C, Fukuoka M, Goto S. Study about Recycling for UV cured prints[J]. Japan Tappi Journal, 2016,70(4):354-357.
[4] Lee M H, Choi H Y, Jeong K Y, Lee J W, Hwang T W, Kim B K. High performance UV cured polyurethane dispersion[J]. Polymer Degradation & Stability, 2007,92(9):1677-1681.
[5] Deng C, Xie W, Huang B, Wan S, Hu K. Study on the properties of oxetane/acrylate UV-cured hybrid system[J]. Imaging Science and Photochemistry, 2014,32(3):289-298.
[6] Zhao F S, Zeng J B, Md M P A, Sun P, Qi J, Motwani P, Gheewala M, Li C H, Paterson A, Strych U, Raja B, Willson R C, Wolfe J C, Lee T L, Shih W C. Monolithic NPG nanoparticles with large surface area, tunable plasmonics, and high-density internal hot-spots[J].The Royal Society of Chemistry, 2014,6:8199-8207.
[7] Ow H, Larson D R, Srivastava M, Baird B A, Webb W W, Wiesner U. Bright and stable core-shell fluorescent silica nanoparticles[J]. Nano Letters, 2005,5(1):113.
[8] Zamanian M, Mortezaei M, Salehnia B, Jam J E. Fracture toughness of epoxy polymer modified with nanosilica particles:particle size effect[J]. Engineering Fracture Mechanics, 2013,97(2):193-206.
[9] Guan B W, Liu K P, Zhang Y, Zhang X X. Advances in research on preparation and modification of nano-SiO₂[J]. Liaoning Chemical Industry, 2008,14(9):537-542.
[10] Yong T. Preparation of phenyl glycidyl ether acrylate and study on its UV curing properties[D]. Nanchang:Nanchang University, 2016.
[11] Tang H L, Xiong H G, Tang S W, Zou P. A starch-based biodegradable film modified by nano silicon dioxide[J]. Journal of Applied Polymer Science, 2009,19(4):34-40.
[12] Chen Y, Zhao M M, Yu X W, Wang B H, Zhang Q. Preparation and application of KH-570 modified nano-SiO₂[J]. Electroplating & Finishing, 2014,33(18):783-787.
[13] Xiong M N, Wu L M, Zhou S X, You B. Preparation and characterization of acrylic latex/nano SiO₂ composites[J]. Society of Chemical Industry, 2002,51:693-698
[14] Silva E K, Zabot G L, Bargas M A, Meireles M A A. Microencapsulation of lipophilic bioactive compounds using prebiotic carbohydrates:effect of the degree of inulin polymerization[J]. Carbohydrate Polymers, 2016,152:775-779.
[15] Ni S B, Nie W Y, Zhou Y F, Song L Y. Preparation and surface modification of nano-silica[J]. New Chemical Materials, 2012,5:119-121.
[16] Semenov A N, Gonzalez-Perez A, Krafft M P, Legrand J L. Theory of surface micelles of semifluorinated alkanes[J]. Langmuir the ACS Journal of Surfaces & Colloids, 2006,22(21):8703-8717.
[17] Bose S, Mahanwar P A. Effects of titanate coupling agent on the properties of mica-reinforced nylon-6 composites[J].Polymer Engineering & Science, 2005,45(11):1479-1486.

Study on UV-curing Properties of Phenyl Glycidyl Ether Acrylate Modified by Nano-SiO₂

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