Imaging Science and Photochemistry ›› 2006, Vol. 24 ›› Issue (4): 291-300.DOI: 10.7517/j.issn.1674-0475.2006.04.291

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Nitrogen Removal via Ammonia Oxidation and Nitrite Reduction Using Ag/TiO2 and Photocatalysis

LIU Li-fen1,2, LI Xiu-ting1, YANG Feng-lin1, Jimmy C Yu3   

  1. 1. Key Laboratory of Industrial Ecology and Environmental Engineering, MOE, School of Environmental and Biological Science, Dalian University of Technology, Dalian 116023, Liaoning, P.R. China;
    2. Center for Nanomaterial and Science, Dalian University of Technology, Dalian 116023, Liaoning, P.R. China;
    3. Department of Chemistry, The Chinese University of Hong Kong, Shatin, Hong Kong
  • Received:2006-04-03 Revised:2006-04-25 Online:2006-07-23 Published:2006-07-23

Abstract: Highly active Ag/TiO2 photocatalyst was prepared using a photocatalytic reduction method and was characterized with XRF,TEM and XRD,XPS and UV-Vis.Effects of conditional factors such as Ag doping,photo-reduction time,stirring gas and addition of Fe2+ on the activity of photocatalyst in nitrogen removal from water by coupled ammonia oxidation and nitrite reduction were investigated.Results showed that nitrite reduction rate and the nitrogen removal rate were highest with 1.0% Ag doping.Also,reduction was ineffective without sufficient irradiation during photocatalyst preparation,the photocatalyst activity was enhanced under protection of nitrogen and addition of Fe2+ increased photocatalytic reduction of nitrite.2 h photocatalytic reaction reduced the total nitrogen by 63.9% for water samples with both ammonia and nitrite.

Key words: Ag/TiO2, photocatalysis, ammonia, nitrite

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