Chemiluminescence Determination of Cysteine with Ru(phen)32+ -SDBS-KMnO4 System

doi:10.7517/j.issn.1674-0475.2005.04.267

Abstract

Abstract: In the presence of anionic surfactant, sodium dodecyl benzene sulfonate (SDBS), the chemiluminescence (CL) intensity of tris-(1,10-phenanthroline)ruthenium(Ⅱ)( Ru(phen)₃²⁺)-KMnO₄ system could be greatly enhanced by Cysteine, based on which, a novel CL method for the determination of Cysteine was developed. Under the optimum experimental conditions, the linear range and detection limit of the proposed method were 2. 5×10^-2-2.0μg·mL^-1 and 2.1×10^-2 μg·mL^-1, respectively. The relative standard deviation (R. S. D.) of determining 11 solutions containing 0.5 μg·mL^-1 Cysteine was 5.3%. This CL method has been successfully applied to the determination of Cysteine in the synthetic samples. The mechanism of CL reaction was also studied.

Key words: cysteine, chemiluminescence, tris-(1,10-phenanthroline)ruthenium(Ⅱ)

CLC Number:

O657

ZHANG Shao-hong, XI Juan, HE Zhi-ke. Chemiluminescence Determination of Cysteine with Ru(phen)₃²⁺ -SDBS-KMnO₄ System[J]. Imaging Science and Photochemistry, 2005, 23(4): 267-273.

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Chemiluminescence Determination of Cysteine with Ru(phen)₃²⁺ -SDBS-KMnO₄ System

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