Novel Inherently Conducting Polymer Acting as Antistatics

doi:10.7517/j.issn.1674-0475.2005.03.232

Imaging Science and Photochemistry ›› 2005, Vol. 23 ›› Issue (3): 232-238.DOI: 10.7517/j.issn.1674-0475.2005.03.232

Novel Inherently Conducting Polymer Acting as Antistatics

XU Jing-kun^1,2, HU Xiu-jie², PU Shou-zhi¹, SHEN Liang¹, CHEN Ping²

1. Key Laboratory of Organic Functional Molecules, Jiangxi Normal University of Science and Technology, Nanchang 330013, Jiangxi, P.R. China;
2. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, P.R. China

Received:2004-11-19 Revised:2004-12-31 Online:2005-05-23 Published:2005-05-23

Abstract

Abstract: Among the antistatic coatings, inherently conducting polymer films were found to be one of the most useful. In this paper, the application of inherently conducting polymers in antistatic coating, such as polythiophenes and polyaniline, have been briefly reviewed, including their conducting mechanism, their characteristics and their development. The special notice was focused on poly (3,4-ethylenedioxythiophene)/polystyrene sulfonic acid, which succeeded in photographic materials as antistatic coating in the past decade.

Key words: conducting polymers, antistatic coating, polythiophenes, polyaniline

CLC Number:

TQ57

XU Jing-kun, HU Xiu-jie, PU Shou-zhi, SHEN Liang, CHEN Ping. Novel Inherently Conducting Polymer Acting as Antistatics[J]. Imaging Science and Photochemistry, 2005, 23(3): 232-238.

References

[1] 张淑琴. 抗静电剂.见:中国化工大全(9)[M].第一版.北京:化工出版社,1995.667-690.Zhang S Q, Antistatic agents In:Encyclopedia of Chemical Engineering[M].1st ed.Beijing:Press of Chemical Industry, 1995.667-690.
[2] Groenendaal L B, Jonas F, et al. Poly(3,4-ethylenedioxythiophene) and its derivatives: past, present and future[J]. Adv. Mater., 2000, 12(7): 481-494.
[3] 李永舫.导电聚合物[J].化学进展, 2002, 14: 207-211.Li Y F. Conducting polymers[J].Progress in Chemistry, 2002, 14: 207-211.
[4] Stenger-Smith J D. Intrinsically electronically conducting polymers. Synthesis, characterization and their applications[J].Prog. Polym. Sci., 1998,23: 57-79.
[5] Kanatzldls M G. Conducting polymers[J]. Chem. & Engin., 1990, (12): 36-54.
[6] 石高全, 李春, 梁映秋. 高性能导电高分子材料[J]. 大学化学,1998, (1): 1-5.Shi G Q, Li C, Liang Y Q. High quality conducting polymers[J].University Chemistry, 1998, (1): 1-5.
[7] 朱道本, 王佛松. 有机固体[M]. 上海:上海科学技术出版社,1999. 89-136, 274-296.Zhu D B,Wang F S.Organic Solids[M].Shanghai:Shanghai Press of Science and Technology.1999.89-136,274-296.
[8] 江明, 府寿宽.高分子科学中的近代论题[M]. 上海: 复旦大学出版社, 1998. 212-230.Jiang M, Fu S K. Recent Interest of Polymer Science[M]. Shanghai: Press of Fudan University, 1998. 212-230.
[9] 陈湘宁, 王天文. 用于最佳静电防护的本征导电聚合物的最新进展[J].化工新型材料, 2002, 30(11): 47-50.Chen X N, Wang T W. Recent progress of inherently conducting polymers in antistatic coatings[J]. New Chemical Materials, 2002, 30(11): 47-50.
[10] Heywang G, Jonas F. Poly(alkylenedioxythiophene)s-new, very stable conducting polymers[J].Adv. Mater.,1992, 4(2): 116-118.
[11] Pei Q, Zuccarello G, Ahlskog M, Inganas O. Electrochromic and highly stable poly(3,4-ethylenedioxythiophene) swithes between opaque blue-black and transparent sky blue[J]. Polymer, 1994, 35(7): 1347-1351.
[12] Jonas F, Heywang G, Schmidtberg W, et al. Polythiophenes, process for their preparation and their use[P]. US Patent, 4 959 430,1989.
[13] Groenendaal L B, Zotti G, Aubert P H, et al. Electrochemistry of poly(3,4-alkylenedioxythiophene) derivatives[J].Adv. Mater., 2003, 15(11): 855-879.
[14] Kiebooms R, Aleshin A, Hutchison K, Wudl F. Thermal and electromagnetic behavior of doped poly(3,4-ethylenedioxythiophene) films[J]. J.Phys. Chem. B, 1998, 101: 11037-11039.
[15] Louwet F, Samijn R. Redisperable latex comprising a polythiophene[P].US Patent, 0 016 440, 2002.
[16] Roncali J. Conjugated poly(thiophenes): synthesis, functionalization and appplicaiton[J].Chem. Rev., 1992, 92: 711-738.
[17] Heuer H W, Wehrmann R, Kirchmeyer S. Electrochromic window based on conducting poly(3,4-ethylenedioxythiophene) poly(styrene sulfonate)[J].Adv. Funct. Mater., 2002,12(2): 89-94.
[18] 王铁军,齐英群,陈萍,等.聚乙二醇对PEDOT/PSS导电性能的影响[J].科学通报,2003,48(19): 2036-2037.Wang T J,Qi Y Q,Chen P,et al. Effect of addition of poly (ethylene glycol) on electrical conductivity of poly (3,4-ethylenedioxythiophene)-poly (styrene sulfonate) hybrid[J].Chinese Science Bulletin, 2003, 48(22): 2444-2445.
[19] Frank L. 3,4-alkylenedioxy-thiophene copolymer[P].EP, 1 323 763, 2003.
[20] Frank L. PEDOT/PSS, synthesis, characterization, properties and applications[J].Synthesis Metal,2003:115-117,125-136.
[21] Kirchmeyer S, Jonas F, Transparent polythiophene layers of high conductivity[P]. US Patent,0 161 941,2003.
[22] Tom C, Johan L, Frank L, Ronn A. A method for preparing a conductive polythiophene layer at low temperature[P]. EP,1 003 179, 2000.
[23] dan Bogaert R V. Aqueous composition containing a polymer or copolymer of a 3,4-dialkoxythiophene and a non-newtonian binder[P].US Patent,0 062 510, 2003.
[24] Louwet F, Groenendaal B. Process for preparing an aqueous or non-aqueous solution or dispersion of a polythiophene copolymer[P]. WO 03/048227, 2003.
[25] Alben G V A, Somers M J M. Light transmissive substrate carrying a light transmissive low ohmic coating[P]. US Patent, 6 404 120, 2002.
[26] Wang S S. High contrast, moisture resistant antistatic/antireflective coating fro CRT display screen[P]. US Patent,0 029 357,2003.

Novel Inherently Conducting Polymer Acting as Antistatics

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 1

Recommended Articles

Metrics

Comments