NEW OBSERVATION OF CYCLIC VOLTAMMETRIC BEHAVIOR OF Ag+-ZEOLITE MODIFIED ELECTRODE

doi:10.7517/j.issn.1674-0475.2002.02.111

Abstract

Abstract: The cyclic voltammegrams(CV)of silver ions exchanged zeolite modified electrode(Ag⁺-zeolite)differed from the behavior of silver ions from an aqueous solution on solid sliver electrode.The formation of silver clusters in the pores of zeolite had a significant effect on the CV behavior of electrodes.In light of CV characteristics of Ag⁺-zeolite electrodes in the electrolyte solution containing anions forming insoluble salt with Ag⁺-,a selectivity of Ag⁺-zeolite for anions was proposed to explain CV characteristics of Ag⁺-zeolite Y.

Key words: zeolite modified electrodes, silver nanoparticle, cyclic voltammetry

CLC Number:

TQ57

LI Yong-jun, LIU Chun-yan . NEW OBSERVATION OF CYCLIC VOLTAMMETRIC BEHAVIOR OF Ag⁺-ZEOLITE MODIFIED ELECTRODE[J]. Imaging Science and Photochemistry, 2002, 20(2): 111-117.

References

[1] Parton R F,Vankelecom I F J,Casselman M J A,et al.An efficient mimic of cytochrome P-450 from a zeolite-encaged iron complex in a polymer membrane[J].Nature,1994,370:541.
[2] Konps-Gerrits P-P,Dirk De Vos,Thibault-Starzyk F,et al.Zeolite-encapsulated Mn(Ⅱ)complexes as catalysts for selective alkene oxidation[J].Nature,1994,369:543.
[3] Huang Y M,Meng X B,Dang Z Y,et al.Light olefin synthesis from carbon dioxide by hydrogenation over Fe₃(CO)₁₂[J].J.Chem.Soc.Chem.Commun.,1995,1025.
[4] 董绍俊,车广礼,谢远武,等.化学修饰电极[M].北京:科学出版社,1995.278.Dong S J,Che G L,Xie Y W,et al.Chemically Modified Electrodes[M].Beijing:Science Press,1995:278.
[5] Rolison D R.Zeolite-modified electrodes and electrode-modified zeolites[J].Chem.Rew.,1990,90:867.
[6] Li J W, Calzaferri G. Copper-zeolite-modified electrodes: An intrazeolite ion transport mechanism[J]. Electroanal.Chem.,1994,377:163.
[7] Li J W, Pfanner K, Calzaferri G. Silver-zeolite-modified electrodes: An intrazeolite electron transport mechanim[J].J.Phys.Chem.,1995,99:2119.
[8] Brown D R,Kevan L.Comparative electron spin resonance and optical absorption studies of silver-exchanged sodium Y zeolites:sliver centers formed on dehydration,oxidation,and subsequent γ-irradiation[J]. J.Phys.Chem.,1986,90:1129.
[9] Ozin G A,Hugues F.Silver atoms and small silver clusters stabilized in zeolite Y:optical spectroscopy[J].J Phys.Chem.,1983,87:94.
[10] Jelinek R,Stein A,Ozin G A.⁸¹Br and ³⁵Cl NMR investigation of sodium,silver,halo-sodalite semiconductor supralattices[J].J.Am.chem.Soc.,1993,115:2390.
[11] Stein A,Ozin G A,Stucky G D.From the molecule to an expanded Ⅰ-Ⅶ semiconductor quantum superlattice:silver,sodium halo-sodalites[J].J.Am.Chem.Soc.,1990,112:904.
[12] Senaratne C,Baker M D.Zeolite-modified electrodes:electrochemical response as a probe of intracrystalline cation-exchange dynamics in zeolites X and Y[J].J.Phys.Chem.,1994,98:13687.
[13] Pereira-Ramos J-P,Messina R,Perichon J.Electrochemical behaviour of a silver exchanged "mordenite"-type zeolite[J].J.Electroanal.Chem.,1983,146:157.
[14] Baker M D,Zhang J.Silverion exchanged zeolite modified electrodes:observation of electrochemically distinct silver ions[J].J.Phys.Chem.,1990,94:8703.
[15] Tauch-Treml R,Henglein A,Lilie J.Reactivity of silver atom in aqueous solution Ⅱ:A pluse radiolysis study[J].Ber.Bunsenges.Phys.Chem.,1978,82:1335.
[16] Henglein A,Tauch-Treml R.Optical absorption and catalytic activity of subcolloidal and colloidal silver in aqueous solution:A pluse radiolysis study[J].J.Coll.Interf.Sci.,1981,80:84.
[17] Baker M D,Senaratne C,Zhang J W.Silver zeolite-modified electrodes:importance of ion-exchange and cation site effects[J].J.Phys.Chem.,1994,98:1996.
[18] Bessel C A,Rolison D R.Topological redox isomers: surface chemistry of zeolite encapsulated Co (salen) and [Fe(bpy)₃]²⁺ complexes[J].J.Phys.Chem.B, 1997,101:1148.
[19] David R L,Frederikse H P R(Ed.)CRC Handbook of Chemistry and Physics[M].75^th ed.CRC Press,Inc.,1995.
[20] Fischer G.Neuere vorstellungen vom wirkmechanismus der stabilistoren und antischleiermittel für photographische emulsionen[J].J.Inf.Rec.Mater.,1988,16:91.
[21] 姚允斌,解涛,高英敏.物理化学手册[M]第一版.上海:上海科学出版社,1985.752.Yao Y B,Xie T,Gao Y M.Handbook of Physics and Chemistry[M].1st ed.Shanghai:Science Press,1985.752.

NEW OBSERVATION OF CYCLIC VOLTAMMETRIC BEHAVIOR OF Ag⁺-ZEOLITE MODIFIED ELECTRODE

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