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    20 February 1985, Volume 3 Issue 1
    STUDIES ON THE METHOD OF DETERMINATION OF NOISE LEVEL OF BLACK-AND-WHITE PHOTOGRAPHIC MATERIALS
    ZHAO WEN-FANG, Lu JING-TI, LIU YU-CHEN, JIANG JIANG, EEN XIN-MIN
    1985, 3(1):  1-6.  DOI: 10.7517/j.issn.1674-0475.1985.01.1
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    According to the recent studies on the noise character of photographic materials, two kinds of noise can be defined: the macronoise, σD (mac), and the micronoise, σD (mic). The macronoise is equivalent to the KMS-granularity of the photographic material, which is defined as and is belived to include the effect of large-scale nonuniformity of the emulsion layer. On the other hand, the micronoise, which is defined as is thought to be determined by the ultimate limit of the statistical fluctuation in the process of photon recording on the emulsion layer. This was verified experimentally and also by computer simulation. The results show that σD (mac) is generally greater than σD (mic), and the standard correlation coefficientis r=1-σD2(mic)/σD2(mac) greater than zero. This is apparently not due to the overlaping of the successive sampling spots. When the sampling rate was reduced from 50s-1 to 11s-1, which is equivalent to increase the distance between the successive sampling spots from 4.4 microns to 190 microns, the micronoise became close or equal to the macronoise, whereas the latter remained unchanged. The computer simulation showed that the micronoise approaches the macronoise as the distance between the successive sampling spots increases. The authors suggested that the macronoise, i.e. the RMS-granularity, can be used as a figure of merit in the evaluation of photographic materrials, whereas the micronoise may be more meaningful when one ’s interest is on the influence of silver halide emulsion on the photographic image quality. The standard correlation coefficient may serve as a measure of the effect of large-scale nonuniformity of a photographic layer.
    INFLUENCE OF (NH4)3IrCl6 AND (NH4)2IrCl6 ON IONIC CONDUCTIVITY OF AgCl (Br,I) EMULSION MICROCRYSTALS
    PENG BI-XIAN, GAO XIU-LIN, PENG YAN-BIN
    1985, 3(1):  7-11.  DOI: 10.7517/j.issn.1674-0475.1985.01.7
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    In this paper the influence of (NH4)3IrCl6 and (NH4)2JrCl6 on the ionic conductivity of AgCl (Br. I) emulsion microcrystals during the chemical ripening is studied with the aid of dielectric loss measurement in the range of 10-3-10-3M/M AgX.As the amount of iridium salts increases, the dielectric loss peak fmax shifts to lower frequency. When the amount of iridium salts added is up to 10-3M/M AgX, the dielectric loss absorption peak becomes broader obviously. When the amounts of (NH4)3IrCl6 and (NH4)JrCl6 are the same, the similar drops of fmax are observed. A probable mechanism of the phenomena observed is discussed.The addition of iridium salts has a great modifying effect on the ionic conductivity of the emulsion microcrystals during the chemical ripening.
    COMPUTER SIMULATION OF GRANULARITY MEASUREMENT FOR PATTERNED SILVER HALIDE GRAIN LAYERS——THE EFFECT OF SQUARE SAMPLING APERTURE
    XIA PEI-JIE, LIU YU-CHEN
    1985, 3(1):  12-21.  DOI: 10.7517/j.issn.1674-0475.1985.01.12
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    Several patterns of silver halide grain array in emulsion layers are designed and a method of computer simulation of granularity measurement is used to analyse the image layers. These image layers are obtained from the photographic layers with various patterns of grain arrays after exposure and development. The variations of granularity with relative densities are analysed. In the simulating measurements of granularities for the patterned grain layers, it is found that a minor variation in sampling aperture size causes a considerable fluctuation of the granularity values measured. That differs from that of the conventional photographic layers in which grains are randomly distributed. It may be predicted that the shape of sampling aperture and its orientation over the samples will have an appreciable influence on the granularity measurement. A circular aperture, therefore, is supposed to be more appropriate.
    THE EXPERIMENTAL OBSERVATION OF IODINE CONTENT AND DISTRIBUTION IN SINGLE Ag(Br,I) CRYSTALLITE
    Xu YONG-EN, CHENG HU-MIN, WANG YU-PING
    1985, 3(1):  22-28.  DOI: 10.7517/j.issn.1674-0475.1985.01.22
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    Iodine content and distribution in single Ag (Br, I) crystal of several kinds of Ag (Br, I) emulsdons have been observed and analyzed by scanning transmissive electron microscopy (STEM) and energy dispersive X-ray spectrometer (EDS). The heterogeneous distribution of iodine in some Ag (Br, I) grains was proved directly. This method could provide useful informations for studying the relations between the structure and properties of Ag (Br, I) emulsion grains.
    INFLUENCE OF SOME STABILIZERS ON THE IONIC COND-UCTIVITY OF SILVER HALIDE MICROCRYSTALS OF PHOTOGRAPHIC EMULSION
    PENG BI-XIAN, PENG YAN-BIN, LI ZHEN-XING, WANG RONG-QIN
    1985, 3(1):  29-34.  DOI: 10.7517/j.issn.1674-0475.1985.01.29
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    The influences of sodium benzosulfinate (BSI), 1-phenyl-5-mercaptotetrazole (PMT) and 5-methyl-7-hydroxy-1, 3, 4-triazaindolizine (TAI) on the ionic conductivity of the microcrystals of silver halide emulsion are investigated by Maxwell-Wagner effect with the aid of dielectric loss measurement in the frequency range of 10 kHz-3 MHz.The addition of BSI (4.76-19.07 g/M AgBr) causes no drop of the ionic conductivity, whereas the addition of PMT and TAI (0.93 g/M AgBr) decreases the ionic conductivity greatly by about 2 log units and increases the conduction activation energy and surface potential by 0.12 eV. It is further shown that the iodide contained in emulsion microcrystals has a great restraining effect on the ionic conductivity decrease when TAI is adsorbed onto the microcrystals. This finding is of significance from the practical aspect.The possible explanation of the above-mentioned phenomena in ionic condutivity behaviour is presented and discussed.
    STUDIES ON THE CHARACTERISTICS OF THE ORGANIC PHOTOCONDUCTOR-LIQUID CRYSTAL LIGHT VALVE (TRANSMISSION MODE)
    LU SHENG-QING, CHANG YOU-MING, ZHANG JING-WEN, CAI ZHONG-FU, JIN XIANG-FENG, WANG DUN-SHI, QIAN EEN-TUAN, HONG XI-JUN, GE MING-JUAN, LIU CHUNG-YI, HANG ZHEN, TANG SHU-MIN, LIU ZHU-JIN
    1985, 3(1):  35-39.  DOI: 10.7517/j.issn.1674-0475.1985.01.35
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    In this paper the d.c. transmission mode liquid crystal light valves (LCLVs) made from thin films of polyvinylcarbazole (PVK) and trinitrofluorenone (TNF) charge transfer complex coupled with nematic liquid crystal or cholesteric-nematic liquid crystal are reported. Results of the studies on the LCLVs made from sandwich structure consisting of thin films of PVK-TNF and three different kinds of liquid crystals, including twisted nematic field effect, phase transition storage effect and dynamic storage effect liquid crystals, are described. Switching effects of these LCLVs have been observed. In addition, the threshold voltage, contrast ratio and rise time of the twisted nematic LCLVs as a function of input light intensities have been studied. Projected image from the twisted nematic LCLV (incoherent-to-coherent conversion) has been obtained. The resolution of the light valve determined by MTF method is approximately 34 lps/mm.
    A STUDY ON THE PHOTOOXIDATION OF α-PINENE
    ZHI LIN, ZHANG BAO-WEN, WU SHI-KANG, FENG XIN-DE
    1985, 3(1):  40-46.  DOI: 10.7517/j.issn.1674-0475.1985.01.40
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    The contact charge transfer (CCT) complex can be formed in the ground state between the α-pinene and oxygen. Under the irradiation of light with suitable wavelength which response to the absorption of CCT complex, it will be advantageous for the photooxidation of α-pinene. The effect of solvent polarity is presented evidently in the oxidation. The larger the polarity is, the faster rate of photooxidation the α-pinene has. All of these shows that charge transfer plays an important role in the reaction. In addition, the oxidation of α-pinene can also take place in complete dark conditions as a result of the CCT complex formation of α-pinene and oxygen. According to the analysis of products in photooxidation and dark oxidation, it is certain that the oxidation in our condition proceeds through a free radical mechanism.
    1985, 3(1):  46-46.  DOI: 10.7517/j.issn.1674-0475.1985.01.46
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    REFLECTION MODE ORGANIC PHOTOCONDUCTORLIQUID CRYSTAL LIGHT VALVE
    LU SHENG-QING, CHANG YOU-MING, ZHANG JING-WEN, CAI ZHONG-FU, QIAN REN-TUAN, YUAN LIANG, TONG SHOU-SHENG, ZAO JING-AN
    1985, 3(1):  47-50.  DOI: 10.7517/j.issn.1674-0475.1985.01.47
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    In this paper d.c. reflection mode liquid crystal light valves (LCLV) made from thin films of polyvinylcarbazole-2, 4, 7-trinitrofluorenone (PVK-TNF) charge transfer complex and chiral nematie-nematic phase transition liquid crystal coupled with a MgF2/ZnS dielectric reflecting interlayer and their light valve characteristics are described, including the dependence of the threshold voltage and the response time on input light intensity and the temperature.The above LCLVs show good light valve effect, which can be used to perform the real-time image conversion from noncoherent to coherent light and also for image storing. Clear projected large area image can be observed.
    SENSITIZED PHOTO-REDOX REACTION-TETRAPHENYLPO-RPHIN AND METAL TETRAPHENYLPORPHINS INDUCED PHOTOREDUCTION OF METHYL VIOLOGEN
    WANG XIU-ZHI, CHEN YU-YI, LIANG XIAO-GUANG
    1985, 3(1):  51-56.  DOI: 10.7517/j.issn.1674-0475.1985.01.51
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    In DMSO-H2O mixture, using TPP and metal TPP’s as sensitizers, EDTA as electron donor, methyl viologen was reduced to the blue methyl viologen cation radical upon irradiation with white light. Order of reactivity is as follows:ZnTPP > TPP > MgTPP≥≥CoTPP > CuTPPThe quantum yield of the ZnTPP sensitized reaction was determined to be 0.08, using potassium ferrioxalate as chemical actinometer. The effect of oxygen, the concentration dependency of sensitizer, methyl viologen and EDTA on the reaction rate, were also examined. The reduction of methyl viologen has been studied kinetically. With [EDTA]≥3×10-4 M and [MV2+] between 1.0-10×10-4 M, the reduction rate follows the following expression: where P is ZnTPP.
    DI-π METHANE PHOTOREARRANGEMENT OF 2,6-DIMETHYL-3,5-DICARBOETHOXY-l,4-DIHYDROPYRIDINE
    Hu QING-TU, HUANG Xm
    1985, 3(1):  57-62.  DOI: 10.7517/j.issn.1674-0475.1985.01.57
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    2, 6-Dimethyl-3, 5-carboethoxy-1, 4-Dihydropyridine was synthesized and its photochemical reaction under UV (366 nm) irradiation was studied. The results show that the main product is 2, 6-Dimethyl-3, 5-Dicarboethoxy-pyridine (95%) and a small amount of Di-π Methane photorearrangement product, 1, 3-Dimethyl-2-aza-4, 5-Dicarboe-thoxy-bicyclo-(3, 1, 0,)-hexene-3 (5%), is obtained.
    A STUDY ON THE QUANTUM YIELD OF HYDROGEN GENERATION FOR SEVERAL CATALYTIC SYSTEMS FOR THE PHOTOREDUCTION OF WATER(Ⅱ)
    ZHAO CHENG-WEN, SHI XIAO-BO
    1985, 3(1):  63-65.  DOI: 10.7517/j.issn.1674-0475.1985.01.63
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    The quantem yield of hydrogen generation was reported for the following catalytic systems: Acridine Vellow/MV2+/EDTA/K2PtCl4, Acridine Yellow/PPVn+/BDTA/ K2 PtCl4 Acridine Yellow/PBVn+/BDTA/K2 ptCl4 and Acridine Yellow/Eh (bpy)33+/TEOA /K2PtCl4. The quantum yield are 0.10,0.04,0.04 and 0.01 respectively.