Photoinduced Hydrogen Evolution from a Novel [NiFe]-Hydrogenase Mimic

doi:10.7517/j.issn.1674-0475.2015.05.411

Abstract

Abstract:

We had successfully fabricated a photoinduced hydrogen evolution system from a novel [NiFe]-Hydrogenase Mimic with a NiRu center in the mixture of acetonitrile and water. Under the optimal conditions, the TON value for hydrogen evolution based on the catalyst was as high as 1893, and the TOF value was 2.6 s^-1 in the first ten minutes. Furthermore, the hydride intermidiate had been successfully observed by using electrochemical technique.

Key words: [NiFe]-Hydrogenase Mimics, photoinduced hydrogen evolution, metal hydride

LI Xubing, WANG Xuzhe, SONG Ziqi, ZHANG Liping, TONG Zhenhe, WU Lizhu. Photoinduced Hydrogen Evolution from a Novel [NiFe]-Hydrogenase Mimic[J]. Imaging Science and Photochemistry, 2015, 33(5): 411-416.

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