核壳型纳米粒子合成方法及其性能的研究进展

doi:10.7517/j.issn.1674-0475.2010.01.65

摘要/Abstract

摘要： 核壳纳米粒子作为复合纳米粒子一个重要的分支,由于其光、磁和催化等方面的优异性能,近年来引起了人们广泛的关注.本文主要介绍了核壳纳米粒子的制备方法及诸多性能,并对核壳纳米粒子的发展进行了展望.

Abstract: As an important branch of composite nanoparticles,core-shell nanoparticles have received great concern due to their versatility of optics,catalysis,megnetism recently.In this paper,a comprehensive review was presented on the core-shell nanoparticles including the preparation,application, and then the development trends of core-shell nanoparticles were also proposed.

Key words: core-shell nanoparticels, optical property, catalytic property, magnetic property

中图分类号:

王莹, 王华, 李蓉, 杜玉扣. 核壳型纳米粒子合成方法及其性能的研究进展[J]. 影像科学与光化学, 2010, 28(1): 65-78.

WANG Ying, WANG Hua, LI Rong, DU Yu-kou. Recent Progress in Synthesis and Properties of the Core-Shell Nanoparticles[J]. Imaging Science and Photochemistry, 2010, 28(1): 65-78.

参考文献

[1]张小塔,宋武林,胡木林,谢长生,郭连贵.核壳结构纳米复合材料的研究进展[J].材料导报,2006,20(7),209-211. Zhang X T,Song W L,Hu M L,Xie C S,Guo L G.Research and development of core-shell nanocomposites[J]. Materials Review,2006,20(7),209-211.
[2]Mayer A B R,Grebner W,Wannemacher R.Preparation of silver-latex composites[J].J.Phys.Chem.B,2000, 104(31):7278-7285.
[3]Ung T,Liz-Marzan L M,Mulvaney P.Redox catalysis using Ag@SiO₂ colloids[J].J.Phys.Chem.B,1999,103 (32):6770-6773.
[4]Saunders A E,Popov I,Banin U.Synthesis of hybrid CdS-Au colloidal nanostructures[J].J.Phys.Chem.B, 2006,110(50):25421-25429.
[5]Du Y K,Qiao Y,Zou C E,et al.The preparation and characterization of Au-core/Pt-shell nanoparticles[J].Colloid. Polym.Sci.,2007,285:553-556.
[6]Hines M A,Guyot-Sionnest P.Synthesis and characterization of strongly luminescing ZnS-capped CdSe nanocrystals [J].J.Phys.Chem.,1996,100(2):468-471.
[7]Dingenouts N,Kim Y S,Ballauff M.Radial density distribution in core-shell latexes as revealed by small-angle X-ray scattering[J].MacromolecularRapid Communications,1994,15(7):613-617.
[8]田娜,陈卫,孙世刚.核-壳结构Au-Pt纳米粒子的光谱表征和电催化性能[J].物理化学学报,2005,21(1): 74-78. Tina N,Chen W,Sun S G.Spectroscopic characterization and electrocatalytic properties of core-shell Au-Pt nanoparticles [J].Acta Phys.Chim.Sin.,2005,21(1):74-78.
[9]Radtchenko I L,Sukhorukov G B,Gaponik N,et al.Core-shell structures formed by the solvent-controlled precipitation of luminescent CdTe nanocrystals on latex sphere[J].Adv.Mater.,2001,13(22):1684-1687.
[10]周建安,李冬梅,桑文斌.ZnS-CdS核壳纳米微晶的制备与光学特性[J].人工晶体学报,2004,33(1):43-47. Zhou J A,Li D M,Sang W B.Preparation of core-shell structure ZnS-CdS nanocrystals and their optical properties [J].Journal of Synthetic Crystals,2004,33(1):43-47.
[11]范晓敏,邹文君,顾仁敖等.Au@SiO₂核壳纳米粒子的制备及其表面增强拉曼光谱[J].高等学校化学学报, 2008,29(1):130-134. Fan X M,Zou W J,Gu R A,et al.Preparation of Au@SiO₂ core-shell nanoparticles and their surface-enhanced roman spectra[J].Chemical Journal of Chinese Universities,2008,29(1):130-134.
[12]端木云,张宇,马明等.Fe/Au核壳复合纳米粒子的制备及表征[J].东南大学学报,2004,34(3):340-343. Duan M Y,Zhang Y,Ma Ming,et al.Preparation and characterization of Fe/Au core-shell composite nanoparticles [J].Journal of Southeast University,2004,34(3):340-343.
[13]Hirai T,Bando Y,Komasawa I.Immobilization of CdS nanoparticles formed in reverse micelles onto alumina particles and their photocatalytic properties[J].J.Phys.Chem.B.,2002,106(35):8967-8970.
[14]Loukanov A R,Dushkin C D,Papazova K I,et al.Photoluminescence depending on the ZnS shell thickness of CdS/ZnS core-shell semiconductor nanoparticles[J].Colloids and Surfaces A:Physicochem.Eng.Aspects,2004, 245:9-14.
[15]Sarkar P,Springborg M,Seifert G.A theoretical study of the structural and electronic properties of CdSe/CdS and CdS/CdSe core/shell nanoparticles[J].Chemical Physics Letters,2005,405(1-3):103-107.
[16]Wang Y,Naoto Nishida,Yang P,et al.Synthesis,separation,and characterization of Au@CdS nanoparticles[J]. Journal of Dispersion Science and Technology,2009,30(8):1175-1181.
[17]刘冰,王德平,姚爱华,等.溶胶-凝胶法制备核壳SiO₂/Fe₃O₄复合纳米粒子的研究[J].无机材料学报,2008, 23(1):33-38. Liu B,Wang D P,Yao A H,et al.Preparation of core-shell SiO₂/Fe₃O₄ nanocomposite particles via sol-gel approach [J].Journal of inorganic materials,2008,23(1):33-38.
[18]Sakai H,Kanda T,Shibata H,et al.Preparation of highly dispersed core/shell-type titania nanocapsules containing a single Ag nanoparticle[J].J.Am.Chem.Soc.,2006,128(15):4944-4945.
[19]李志会,杨修春,杜天伦.核壳结构纳米颗粒的研究进展[J].材料导报,2007,21(8):189-192. Li Z H,Yang X C,Du T L.Research progress in core-shell structure nanoparticles[J].Materials Review,2007, 21(8):189-192.
[20]Du Y K,Zhang W,Wang X M,et al.Prepartion of platinum core-polyaryl ether aminediacetic acid dendrimer shell nanocomposition for catalytic hydrogenation of phenyl aldehydes[J].Catalysis Letters,2006,107(3-4):177-183.
[21]Yang X L,Liu H F,Zhong H.Hydrogenation of o-chloronitrobenzene over polymer-stabilized palladium-platinum bimetallic colloidal clusters[J].Journal of Molecular Catalysis A:Chemical,1999,147(1-2):55-62.
[22]胡永红,容建华,刘应亮,满石清.SiO₂/Ag核壳结构纳米粒子的制备及表征[J].化学学报,2005,63(24): 2189-2193. Hu Y H,Rong J H,Liu Y L,Man S Q.Preparation and characterization of SiO₂/Ag core-shell nanoparaticles[J]. Acta Chimica Sinica,2005,63(24):2189-2193.
[23]纪小会,王连英,袁航,马岚,白玉白,李铁津.Au/Ag核-壳结构复合纳米粒子形成机制的研究[J].化学学报,2003,61(10):1556-1560. Ji X H,Wang L Y,Yuan H,Ma L,Bai Y B,Li T J.Formation mechanism of core-shell Au/Ag nanoparticles[J]. Acta Chimica Sinica,2003,61(10):1556-1560.
[24]杨晓峰,董相廷,黄磊.CeO₂@Au核壳结构粒子的合成与性质研究[J].中国稀土学报,2008,26(6):683-688. Yang X F,Dong X T,Huang L.Synthesis and properties of CeO₂@Au core-shell structure nanoparticles[J].Journal of Chinese Rare Earth,2008,26(6):683-688.
[25]戴兢陶,杜玉扣,狄国庆,华南平,杨平.核-壳型Pt₃Co@Pt纳米粒子的制备及磁性[J].无机化学学报,2006, 22(10):1908-1910. Dai J T,Du Y K,Di G Q,Hua N P,Yang P.Synthesisi and magnetic property of Pt₃Co@Pt core-Pt shell nanoparticles[J].Chinese Journal of Inorganic Chemistry,2006,22(10):1908-1910.
[26]Dai J T,Du Y K,Yang P.Preparation and characterization of Pt/Co-Core Au-Shell magnetic nanoparticles[J].Z. Anorg.Allg.Chem.,2006,632(6):1108-1111.
[27]尤晓刚,贺蓉,高峰,等.核/壳型CdTe@SiO₂荧光纳米复合粒子的制备与表征[J].化学学报,2007,65 (6):561-565. You X G,He Rong,Gao F,et al.Preparation and characterization of CdTe@SiO₂ core/shell luminescent composite nanoparatices[J].Acta Chimica Sinica,2007,65(6):561-565.
[28]Lin H Y,Chen Y F.Carrier transfer induced photoluminescence change in metal-semiconductor core-shell nanostructures [J].Applied Physics Letters,2006,88(161911):1-3.
[29]Qi Y L,Chen M,Liang S,et al.Micro-patterns of Au@SiO₂ core-shell nanoparticles formed by electrostatic interactions [J].Applied Surface Science,2008,254:1684-1690.
[30]Oldenburg S J,Averitt R D,Westcott S L,et al.Nanoengineering of optical resonances[J].Chemical Physics Letters, 1998,288(2-4):243-247.
[31]Yu K,Wu Z C,Zhao Q R,et al.High-temperature-stable Au@SnO₂ core/shell supported catalyst for CO oxidation [J].J.Phys.Chem.C.,2008,112(7):2244-2247.
[32]鲍芳,姚建林,顾仁敖.Au_(core)Pt_(shell)纳米粒子对甲醇氧化的电催化性能研究[J].电化学,2006,12(2):218-222. Bao F,Yao J L,Gu R A.Electrochemical studies on electrocatalytic activity of Au_(core)Pt_(shell) nanopartciles to methanol oxidation[J].Electrochemistry,2006,12(2):218-222.
[33]唐学红,吴莹,张玉,等.光催化还原制备Au/Ag核壳结构纳米粒子及其修饰电极的电催化性能[J].应用化学,2009,26(4):471-474. Tang X H,Wu Y,Zhang Y,et al.Preparation of Au core/Ag shell nanoparticles by photocatalysis reduction method and electrocatalysis of its modified electrode[J].Chinese Journal of Applied Chemistry,2009,26(4):471-474.
[34]Fu Q,Deng W,Saltsburg H,et al.Activity and stability of low-content gold-cerium oxide catalysts for the watergas shift reaction[J].Applied Catalysis B:Environmental,2005,56(1-2):57-68.
[35]Zhao W R,Gu J L,Zhang L X,et al.Fabrication of uniform magnetic nanocomposite spheres with a magnetic core/mesoporous silica shell structure[J].J.Am.Chem.Soc.,2005,127(25):8916-8917.
[36]Chen D,Liao M.Preparation and characterization of YADH-bound magnetic nanoparticles[J].J Molecular Catalysis, 2002,16(5/6):283-291.
[37]鲍芳,姚建林,顾仁敖.铁氧化物/金磁性核壳纳米粒子的制备及其富集与SERS研究[J].高等学校化学学报,2008,29(8):1552-1554. Bao F,Yao J L,Gu R A.Preparation of magnetic Fe oxide core/Au shell nanoparticles and their surface-enhanced raman spectroscopy[J].Chemical Journal of Chinese Universities,2008,29(8):1552-1554.
[38]王维娜,黄昊,张雪峰,等.SiO₂/Ni核-壳结构纳米粒子的制备及其磁性能[J].复合材料学报,2007,24(3): 131-135. Wang W N,Huang H,Zhang X F,et al.Preparation of SiO₂/Ni core-shell structured nanoparticles and their magnetic properties[J].Acta Material Composite Sinica,2007,24(3):131-135.
[39]Deng J G,Peng Y X,Wang J H.Magnetic and conductive Fe₃O₄-polyaniline nanoparticles with core-shell structure [J].Synthetic Metals,2003,139:295-301.
[40]Sun Y K,Duan L,Guo Z R,et al.An improved way to prepare superparamagnetic magnetite-silica core-shell nanoparticles for possible biological application[J].J.Mag.Mag.Mater.,2005,285(1-2):65-70.
[41]Liu X Q,Xing J M,Guan Y P,et al.Synthesis of aminosilane modified superparamagnetic silica supports and their use for protein immobilization[J].Collioid Surface A:Phys.Eng.Aspects,2004,238:127.