光固化阻燃单体、树脂合成及其阻燃机理研究

doi:10.7517/issn.1674-0475.190503

影像科学与光化学 ›› 2019, Vol. 37 ›› Issue (4): 281-291.DOI: 10.7517/issn.1674-0475.190503

光固化阻燃单体、树脂合成及其阻燃机理研究

王庆丰, 闫瑞强

台州学院医药化工与材料工程学院, 浙江台州 318000

收稿日期:2019-05-05 出版日期:2019-07-15 发布日期:2019-07-15
通讯作者: 王庆丰
基金资助:
浙江省教育厅高校境外培训教师专业发展项目（JW2016003）和台州市科技计划项目（1702gy08）资助

Syntheses and Flame Retardancy Mechanism of UV Curable Flame-retardant Monomers and Resins

WANG Qingfeng, YAN Ruiqiang

School of Pharmaceutical and Materials Engineering, Taizhou University, Taizhou 318000, Zhejiang, P. R. China

Received:2019-05-05 Online:2019-07-15 Published:2019-07-15

摘要/Abstract

摘要： 本文综述了过去十余年间中国科技大学施文芳教授研究组在光固化阻燃技术领域的工作成果，主要包括活性单体、稀释剂、光固化树脂配方等体系，品类有磷酸酯类单体、含磷丙烯酸酯、超支化丙烯酸酯树脂、膦酸酯类单体和树脂、丙烯酸化环状磷腈、甲基丙烯酸化三聚氰胺、含磷环氧单体等十余种。同时介绍了这些配方体系的合成、性能和应用方法，以及对其热降解、阻燃性能评价和阻燃机理的研究。

关键词: 光固化, 阻燃, 磷酸酯单体, 含磷丙烯酸酯, 膦酸酯单体, 超支化

Abstract: Research of UV curing flame retardant technologies in Professor Wenfang Shi's group in the past decade was reviewed in this article. Reactive momomers, diluents and formulations of UV-curable resins were applied in these works. All of them were categorized as phosphate, phosphorus-containing acrylate, hyperbranched acrylate, phosphonate, acrylated cyclophosphazene, methacrylated phenolic melamine and phosphorus-containing epoxy monomer. Syntheses, properties and applications of these formulations were described. Thermal degradation, evaluation and mechanism of flame retardancy were also introduced.

Key words: UV-curing, flame retardance, phosphate, phosphorus-containing acrylate, phosphonate, hyperbranched

王庆丰, 闫瑞强. 光固化阻燃单体、树脂合成及其阻燃机理研究[J]. 影像科学与光化学, 2019, 37(4): 281-291.

WANG Qingfeng, YAN Ruiqiang. Syntheses and Flame Retardancy Mechanism of UV Curable Flame-retardant Monomers and Resins[J]. Imaging Science and Photochemistry, 2019, 37(4): 281-291.

参考文献

[1] World Fire Statistics:Information Bulletin of the World Fire Statistics Centre. Geneva:The Geneva Association, 2012.
[2] Zhu S W, Shi W F. Synthesis, characterization and flame retardancy of methacrylated phosphate/diphosphate[J]. Polymer International, 2004, 53(3):266-271.
[3] Zhu S W, Shi W F. Combustion behaviour and thermal properties of UV cured methacrylated phosphate/epoxy acrylate blends[J]. Polymer Degradation & Stability, 2003, 81(2):233-237.
[4] Liang H B, Shi W F. Thermal behaviour and degradation mechanism of phosphate di/triacrylate used for UV curable flame-retardant coatings[J]. Polymer Degradation and Stability, 2004, 84(3):525-532.
[5] Liang H B, Asif A, Shi W F. Photopolymerization and thermal behavior of phosphate diacrylate and triacrylate used as reactive-type flame-retardant monomers in ultraviolet-curable resins[J]. Journal of Applied Polymer Science, 2005, 97(1):185-194.
[6] Liang H B, Huang Z G, Shi W F. Different effects of tri(acryloyloxyethyl) phosphate on the thermal degradation of photopolymerized epoxy acrylate and polyurethane acrylate films[J]. Journal of Applied Polymer Science, 2006, 99(6):3130-3137.
[7] Liang H B, Ding J, Shi W F. Kinetics and mechanism of thermal oxidative degradation of UV cured epoxy acrylate/phosphate triacrylate blends[J]. Polymer Degradation & Stability, 2004, 86(2):217-223.
[8] Huang Z G, Shi W F. Synthesis and properties of poly(bisphenol A acryloxyethyl phosphate) as a UV curable flame retardant oligomer[J]. European Polymer Journal, 2006, 42(7):1506-1515.
[9] Huang Z G, Shi W F. Thermal behavior and degradation mechanism of poly(bisphenyl acryloxyethyl phosphate) as a UV curable flame-retardant oligomer[J]. Polymer Degradation and Stability, 2006, 91(8):1674-1684.
[10] Huang Z G, Shi W F. Effect of poly(bisphenol A acryloxyethyl phosphate) on the activation energy in thermal degradation of urethane acrylate[J]. Journal of Thermal Ana-lysis & Calorimetry, 2007, 88(3):833-841.
[11] Zhu S W, Shi W F. Synthesis and photopolymerization of hyperbranched polyurethane acrylates applied to uv curable flame retardant coatings[J]. Polymer International, 2002, 51(3):223-227.
[12] Zhu S W, Shi W F. Flame retardant mechanism of hyperbranched polyurethane acrylates used for UV curable flame retardant coatings[J]. Polymer Degradation & Stability, 2002, 75(3):543-547.
[13] Huang Z G, Shi W F. Synthesis and properties of a novel hyperbranched polyphosphate acrylate applied to UV curable flame retardant coatings[J]. European Polymer Journal, 2007, 43(4):1302-1312.
[14] Wang Q F, Shi W F. Photopolymerization and thermal behaviors of acrylated benzenephosphonates/epoxy acrylate as flame retardant resins[J]. European Polymer Journal, 2006, 42(10):2261-2269.
[15] Wang H L, Wang Q F, Huang Z G, Shi W F. Synthesis and thermal degradation behaviors of hyperbranched polyphosphate[J]. Polymer Degradation and Stability, 2007, 92(10):1788-1794.
[16] Ding J, Shi W F. Thermal degradation and flame retardancy of hexaacrylated/hexaethoxyl cyclophosphazene and their blends with epoxy acrylate[J]. Polymer Degradation & Stability, 2004, 84(1):159-165.
[17] Ding J, Liang H B, Shi W F, Shen X F. Photopolymerization and properties of UV-curable flame-retardant resins with hexaacrylated cyclophosphazene compared with its cured powder[J]. Journal of Applied Polymer Science, 2005, 97(5):1776-1782.
[18] Liang H B, Asif A, Shi W F. Thermal degradation and flame retardancy of a novel methacrylated phenolic melamine used for UV curable flame retardant coatings[J]. Polymer Degradation & Stability, 2005, 87(3):495-501.
[19] Wang H L, Liu J H, Xu S P, Shi W F. Preparation and film properties of tri(3,4-epoxycyclohexylmethyl) phosphate based cationically UV curing coatings[J]. Progress in Organic Coatings, 2009, 65(2):263-268.

光固化阻燃单体、树脂合成及其阻燃机理研究

Syntheses and Flame Retardancy Mechanism of UV Curable Flame-retardant Monomers and Resins

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