含有蒽酰亚胺的铜(I)配合物的合成、结构及光谱研究

doi:10.7517/j.issn.1674-0475.2008.01.60

影像科学与光化学 ›› 2008, Vol. 26 ›› Issue (1): 60-67.DOI: 10.7517/j.issn.1674-0475.2008.01.60

含有蒽酰亚胺的铜(I)配合物的合成、结构及光谱研究

赵希娟^1,2, 陈勇^1,2, 迟绍明¹, 傅文甫¹

1. 中国科学院, 理化技术研究所, 北京, 100080;
2. 中国科学院, 研究生院, 北京, 100039

收稿日期:2007-06-04 修回日期:2007-07-24 出版日期:2008-01-23 发布日期:2008-01-23
通讯作者: 傅文甫,E-mail:fuwf@mail.ipc.ac.cn.
基金资助:
国家自然科学基金资助项目(20671094);NSFC/RGC联合资助项目(50418010)

Synthesis,Structure and Spectroscopic Properties of a Novel Copper (I) Complex with N-(6-Aminopyridine-2-yl)-9-Anthracenecarbonamide

ZHAO Xi-juan^1,2, CHEN Yong^1,2, CHI Shao-ming¹, FU Wen-fu¹

1. Technical Institute of Physics and Chemistry, the Chinese Academy of Sciences, Beijing 100080, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100039, P. R. China

Received:2007-06-04 Revised:2007-07-24 Online:2008-01-23 Published:2008-01-23

摘要/Abstract

摘要： 合成了两个含蒽酰亚胺基团的新配体N-(2-(6-氨基吡啶))-9-蒽酰亚胺(L¹)和N,N′-(2,6-吡啶基)-二(9-蒽酰亚胺)(L²),以及L¹的铜(I)配合物[CuL¹(PPh₃)₂](BF₄)(1),并研究了它们的结构和光谱性质.理论计算表明配体L¹配位前为反式构象,配合物1的晶体结构显示L¹配位后发生结构扭曲呈顺式构象,羰基氧原子与铜(I)离子配位.光谱研究表明配体L¹和配合物1都表现出蒽的特征吸收和发射峰.

关键词: 铜(I)配合物, 氧配位, 晶体结构, 光谱性质

Abstract: Two new ligands,N-(6-aminopyridine-2-yl)-9-anthracenecarbonamide (L¹) and N,N’-(pyridine-2,6-yl)-bis (9-anthracenecarbonamide) (L²),and the novel copper (I) complex of L¹,[CuL¹ (PPh₃)₂] (BF₄) (1),have been synthesized and characterized.The crystal structures of L² and 1 were determined by single crystal Xray analysis,which show that the carbonyl (C=O) group in 1 is coordinated to the copper (I) ion through the oxygen atom.In addition,the spectroscopic properties of L¹ and 1 were studied at room temperature.

Key words: copper (I) complex, oxygen-bonding, crystal structure, spectroscopic properties

中图分类号:

赵希娟, 陈勇, 迟绍明, 傅文甫. 含有蒽酰亚胺的铜(I)配合物的合成、结构及光谱研究[J]. 影像科学与光化学, 2008, 26(1): 60-67.

ZHAO Xi-juan, CHEN Yong, CHI Shao-ming, FU Wen-fu. Synthesis,Structure and Spectroscopic Properties of a Novel Copper (I) Complex with N-(6-Aminopyridine-2-yl)-9-Anthracenecarbonamide[J]. Imaging Science and Photochemistry, 2008, 26(1): 60-67.

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含有蒽酰亚胺的铜(I)配合物的合成、结构及光谱研究

Synthesis,Structure and Spectroscopic Properties of a Novel Copper (I) Complex with N-(6-Aminopyridine-2-yl)-9-Anthracenecarbonamide

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