Imaging Science and Photochemistry ›› 1998, Vol. 16 ›› Issue (4): 348-352.DOI: 10.7517/j.issn.1674-0475.1998.04.348

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KINETICS OF PHOTO-AND THERMO-DECOMPOSITIONS OF DIPHENYLAMINE DIAZONIUM SALTS IN ETHANOL

ZHAO Chao, CHEN Jinyu, CAO Weixiao   

  1. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
  • Received:1997-12-26 Revised:1998-04-07 Online:1998-11-20 Published:1998-11-20

Abstract: The kinetics of photo-and thermo-decomposition of various diphenylamine diazonium salts in ethanol were investigated. It was found that the diphenylamine-4-diazonium salts studied in this work possess better properties both in photosensitive behavior and in thermostabilities than that of diphenylamine-2-diazonium salt. 3-Methoxy-and 2-sulfonic-diphenylamine-4-diazonium salts exhibit excellent thermostabilities. The carbazole-3-diazonium salt has similar properties towards photo-and thermo-decomposition as compared with that of dephenylamine-2-diazonium salt.

Key words: diphenylamine diazonium salt, the kinetics of photo-and thermo-decomposition, negative presensitized plate