Imaging Science and Photochemistry ›› 2004, Vol. 22 ›› Issue (5): 350-356.DOI: 10.7517/j.issn.1674-0475.2004.05.350

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Cooperative Sensitization by Reduction and Chemical Sensitizations in AgBrⅠ Core-Shell Emulsions

ZHI Xin, SHI Yao, CAO Jing, XIA Pei-jie   

  1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, P. R. China
  • Received:2004-04-14 Revised:2004-05-19 Online:2004-09-23 Published:2004-09-23

Abstract: A series of cubic AgBrⅠ core-AgBr shell emulsions with different amounts of DMAB used for producing Ag2 (R center) in the core were prepared by using a double-jet apparatus controlled by a microcomputer.The results from sensitometric measurements of these emulsions show that the emulsions doped by Ag2 in the AgBrⅠ core exhibited a significant increase in sensitivities and the existence of I- in the core-shell grains did not influence the sensitization of the internal Ag2; and that these core-shell emulsions after surface sensitization by sulfur-plus-gold exhibited a remarkable cooperative sensitization,i.e.their sensitivities were much higher than that of the controlled one which was not doped with Ag2 in the core.These results reconfirmed two kinds of different sensitization mechanisms,i.e.via trapping holes by the internal Ag2 centers and concentration of electrons by sulfur-plus-gold sensitizing centers.Taking advantage to both mechanisms,a cooperative sensitization could be realized to improve the efficiency of latent image formation.

Key words: hole-electron converter, AgBrⅠ core-shell emulsion, doped by Ag dimmer, sulfur-plus-gold sensitization, cooperative sensitization

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