Imaging Science and Photochemistry ›› 2007, Vol. 25 ›› Issue (1): 24-31.DOI: 10.7517/j.issn.1674-0475.2007.01.24

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Synthesis and Optical Properties of Novel Eu(Ⅲ) Complex Containing Naphthalimide Unit

ZHU Wei-hong1, LI Heng1, ZHU Shi-qin2   

  1. 1. Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai 200237, P.R.China;
    2. Institute of Science & Technology Information, East China University of Science & Technology, Shanghai 200237, P.R.China
  • Received:2006-07-20 Revised:2006-09-12 Online:2007-01-23 Published:2007-01-23

Abstract: A novel complex Eu(DBM)3(PNI-phen) was synthesized via incorporation of naphthalimide unit to the neutral ligand of 1,10-phenanthroline,which enables the europium complex to exhibiting the characteristic luminescence of naphthalimide unit and Eu3+ ion via selective excitation.The pathway of energy transfer and the luminescence mechanism were studied by the fluorescence and excitation spectra.

Key words: Eu complex, naphthalimide unit, energy transfer, luminescence

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