Synthesis and Characterization of a Supramolecular Side-chain Electro-optic Polymer Based on Hydrogen Bonding

doi:10.7517/j.issn.1674-0475.2016.02.166

Imaging Science and Photochemistry ›› 2016, Vol. 34 ›› Issue (2): 166-171.DOI: 10.7517/j.issn.1674-0475.2016.02.166

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Synthesis and Characterization of a Supramolecular Side-chain Electro-optic Polymer Based on Hydrogen Bonding

DENG Guowei^1,2, CHEN Zhuo¹, BO Shuhui¹, WU Jieyun¹, HUANG Heyan¹, QIU Ling¹, ZHEN Zhen¹, LIU Xinhou¹

1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. College of Chemistry and Life Science, Chengdu Normal University, Chengdu 611130, Sichuan, P. R. China

Received:2016-01-05 Revised:2016-02-02 Online:2016-03-15 Published:2016-03-15

Abstract

Abstract:

Supramolecular side-chain electro-optic(EO) polyvinyl pyridine based on hydrogen bond were designed and prepared, and the hydrogen-bond between nonlinear optical(NLO) chromophore and polymer backbone was characterized by IR spectra. The studies indicated that the noncovalent interaction can suppress the dye aggregation, avoiding the macroscopic phase separation and allowing high doping concentration. Moreover, such a strategy can suppress the dipolar-dipolar interaction, and the poled EO films revealed the maximum EO coefficient value (r33) of 17.6 pm/V.

Key words: organicelectro-optic materials, hydrogen-bond, supramolecular side-chain polymer, electro-optic coefficient

DENG Guowei, CHEN Zhuo, BO Shuhui, WU Jieyun, HUANG Heyan, QIU Ling, ZHEN Zhen, LIU Xinhou. Synthesis and Characterization of a Supramolecular Side-chain Electro-optic Polymer Based on Hydrogen Bonding[J]. Imaging Science and Photochemistry, 2016, 34(2): 166-171.

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Synthesis and Characterization of a Supramolecular Side-chain Electro-optic Polymer Based on Hydrogen Bonding

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