THE RELATION OF PHOTOCATALYTIC ACTIVITY OF PEROVSKTIE (ABO3) TYPE OXIDE AND D-ELECTRON STRUCTURE OF ION B

doi:10.7517/j.issn.1674-0475.2001.02.109

Abstract

Abstract: The d-electron structure of ion B in perovskite(ABO₃) type oxide has the key role on the binding energy of B-O and the charge-transfer energy(ΔCT) between O_2p and B_3d, so it has an important influence on the photocatalytic activity of ABO₃. In this paper, the species LaBO₃(B=Ti-Co) were prepared by the mixed oxide method and the citrate complex method. By analyzing the photocatalytic degradation experiment and their photo acoustic spectra, the results show that photocatalytic activity of LaBO₃ increases with the increasing of d-electron number of ion B.

Key words: perovskite type oxide, photocatalytic activity, d-electron structure, charge-transfer energy(ΔCT)

CLC Number:

O644

SANG Li-xia, FU Xi-xian, BAI Shu-lin, YANG Qiu-hua, WANG Jun-zhen, ZENG Shu-lan. THE RELATION OF PHOTOCATALYTIC ACTIVITY OF PEROVSKTIE (ABO₃) TYPE OXIDE AND D-ELECTRON STRUCTURE OF ION B[J]. Imaging Science and Photochemistry, 2001, 19(2): 109-115.

References

[1] Sarma D D, Shanthi N, Barman S R, et al. Band theory for ground-state properties and excitation spectra of perovskite LaMo3(M＝Mn, Fe, Co, Ni)[J]. Physical Review Letters, 1995, 175(6):1126-1129.
[2] Taka-hisa Arima, Yoshinori Torura. Optical study of electronic structure in perovskite-type[J]. Journal of the Physical Society of Japan, 1995,54(7):2488-2501.
[3] Wolfram T, Kralt E A, Morin F J. d-band surface states on transition-metal perovskite crystals Ⅰ. qualitative features and application to SrTiO3[J]. Physical Review B, 1973,7(4):1677-1694.
[4] 秦永宁,田辉平,张鎏,等.钙钛矿型化合物催化氧化性能与d电子构型关系的研究[J].化学学报,1993,51:319-324. Qin Yongning,Tian Huiping,Zhang Liu,et al. Study on the correlation of d-electron catalytic oxidation activity of LaMnO₃[J].ACTA CHIMICA SINICA,1993,51:319-324.
[5] Pari G, Mathbi S, Jaya, et al. Density-functional description of the electronic structure of LaMO₃(M＝Sc, Ti, Cr, Mn, Fe, Co, Ni)[J]. Physical Review B, 1995,51(23):16575-16581.
[6] Arima T, Tokura Y, Tottance J B. Variation of optical gaps in perovskite-type 3d transition-metal oxides[J]. Physical Review B, 1993,48(23):17006-17009.
[7] Sarma D D, Santra A K, Rao C N R. Electronic structures of pervoskite oxides of transition metals of the type LaMO₃(M=Ti-Ni) as revealed by MSX α investigations[J]. Journal of Solid State Chemistry, 1994,110:393-396.
[8] Takashi Shimizu. Effect of electronic structure and tolerance factor on Co oxidation activity of pervoskite oxides[J]. Chemistry Letters, 1980,1-4.
[9] Heinz Gerischer, Adam Heller. The roke of oxygen in photooxidation of organic molecules on semiconductor particles[J]. J.Phys. Chem., 1991,95:5261-5267.
[10] 杨频,高孝恢.性能-结构-化学键[M].北京:高等教育出版社,1987.408. Yang Pin,Gao Xiahui.Chemical Bonding and Structure-Property Relations[M].Beijing:Advanced Education Press, 1987.408.
[11] 林西平泽.新型催化材料[M].北京:石油工业出版社,1984.12. Burton J J, Garten R L. New Type Catalysis Material[M]. Ling Xiping(transl.). Beijing: Petroleum Industry Press, 1984.12.
[12] Thornton G, Orchard A F, Rao C N R. A study of LaCoO3 and related materials by X-ray photoelectron spectroscopy[J]. J. Phys. C: Solid State Phys., 1976,9:1991-1999.
[13] Goodenough J B. Progress in Solid State Chemistry[M]. Vol. 5. Oxford: Pergamon Press, 1991.145.
[14] Voorhoeve R J H, Burton J J, Garton R L, et al. Advanced Materials in Catalysts[M]. New York: Academic Press, 1977.129.

THE RELATION OF PHOTOCATALYTIC ACTIVITY OF PEROVSKTIE (ABO₃) TYPE OXIDE AND D-ELECTRON STRUCTURE OF ION B

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 10

Recommended Articles

Metrics

Comments

[1]	LI Hai-yan, QIAN Jun-jie, LIU Jin-feng, LI Qiu-ye, ZHANG Min, YANG Jian-jun. Study on the Synthesis of N, Bi-codoped TiO₂ Nanoparticles and Their Visible Light Photocatalytic Performance [J]. Imaging Science and Photochemistry, 2013, 31(6): 411-420.
[2]	FEI Xue-ning, LIU Xing-xing, LI Jin-rui, JIANG Yuan-guang. Preparation and Characteristics of Magnetic TiO₂ Photocatalysts [J]. Imaging Science and Photochemistry, 2013, 31(3): 229-237.
[3]	JING Ming-jun, WANG Yan, ZHANG Min, YANG Jian-jun. Preparation of Gold-Modified Nitrogen-Doped TiO₂ and Its Visible Light Photocatalytic Activity [J]. Imaging Science and Photochemistry, 2011, 29(5): 353-363.
[4]	WANG Ying-ling, XIE You-hai, YUAN Jian-mei, ZHOU Qing-xiang, LIU Guo-guang. Preparation of B-Doped TiO₂ Nanoparticles and Their Photocatalytic Activities [J]. Imaging Science and Photochemistry, 2010, 28(4): 287-295.
[5]	CAO Jing, LIN Hai-li, JIA Li, CHEN Shi-fu. AgBr/TiO₂ Composite Catalyst:Preparation by Double-Jet Method and Visible Light Photocatalytic Property [J]. Imaging Science and Photochemistry, 2009, 27(6): 462-468.
[6]	WANG Ying-ling, XIE You-hai, LIU Guo-guang, ZHOU Jian-guo, ZHOU Qing-xiang. Gel-Network Controlled Synthesis of ZnO Nanoparticles and Their Photocatalytic Activities [J]. Imaging Science and Photochemistry, 2009, 27(3): 207-214.
[7]	JIANG Hong-quan, WANG Peng, CHEN Hong-yan, YU Kai. Surface Properties and Photocatalytic Activity of Pr³⁺-Doped TiO₂ Nano-Powders [J]. Imaging Science and Photochemistry, 2006, 24(4): 276-285.
[8]	TIAN Bao-zhu, TONG Tian-zhong, CHEN Feng, ZHANG Jin-long. Effects of Gelatin on Phase Transformation and Photocatalytic Activity of Nano-size Titanium Dioxide [J]. Imaging Science and Photochemistry, 2006, 24(2): 93-101.
[9]	CAO Ya-an, CHEN Yong-mei, GUAN Zi-sheng, MA Ying, WU Zhi-yun, BAI Yu-bai, LI Tie-jin, YAO Jian-nian. RELATIONSHIP OF PHOTOCATALYTIC ACTIVITY AND SURFACE STATES OF TiO₂ NANOPARTICLE FILM [J]. Imaging Science and Photochemistry, 1999, 17(2): 100-103.
[10]	CHEN Shifu, LIANG Xin, ZHAO Mengyue. THE EFFECT OF THE DIFFERENT PREPARATION CONDITIONS ON THE PHOTOCATALYTIC ACTIVITY OF TiO₂/beads [J]. Imaging Science and Photochemistry, 1999, 17(1): 25-31.