叔碳酸缩水甘油酯改性碱溶性酚醛环氧丙烯酸酯的研究

doi:10.7517/issn.1674-0475.190105

影像科学与光化学 ›› 2019, Vol. 37 ›› Issue (3): 185-194.DOI: 10.7517/issn.1674-0475.190105

叔碳酸缩水甘油酯改性碱溶性酚醛环氧丙烯酸酯的研究

王浩东^1,2, 孙冠卿^1,2, 安丰磊², 袁燕华², 刘仁^1,3

1. 江南大学化学与材料工程学院, 江苏无锡 214122;
2. 江苏广信感光新材料股份有限公司, 江苏无锡 214400;
3. 江南大学光响应功能分子材料国际联合研究中心, 江苏无锡 214122

收稿日期:2019-01-17 出版日期:2019-05-15 发布日期:2019-05-15
通讯作者: 刘仁
基金资助:
江苏省产学研合作项目（BY2018038）资助

Study on Alkali-soluble Epoxy Acrylates Resin Modified by Glycidyl Ester of Versatic Acid

WANG Haodong^1,2, SUN Guanqing^1,2, AN Fenglei², YUAN Yanhua², LIU Ren^1,3

1. School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu, P. R. China;
2. Jiangsu Guangxin Photosensitive New Materials Co. Ltd., Wuxi 214400, Jiangsu, P. R. China;
3. International Research Center for Photoresponsive Molecules and Materials, Jiangnan University, Wuxi 214122, Jiangsu, P. R. China

Received:2019-01-17 Online:2019-05-15 Published:2019-05-15

摘要/Abstract

摘要： 为了获得高分辨率和耐侧蚀性能优异的阻焊油墨，本文利用叔碳酸缩水甘油酯（E10p）对碱溶性酚醛环氧丙烯酸酯进行改性，并将其应用到阻焊油墨体系。实验结果表明，该改性树脂具有优异的感光性，同时涂层性能测试表明该树脂具有优异的耐热性及柔韧性。与未改性树脂相比，该树脂所制备的阻焊油墨分辨率由75 μm线距提高到50 μm，侧蚀由37.5 μm降低到24.5 μm，表现出了更高的分辨率及更优的耐侧蚀性。

关键词: 环氧丙烯酸酯, 叔碳酸缩水甘油酯, 阻焊油墨, 分辨率

Abstract: In this paper, the glycidyl ester of versatic acid (E10p) was used to modify the alkali-soluble epoxy acrylates resin,then the modified resin was applied to the solder resist ink to improve its resolution and resistance undercut. The results showed that the modified resin exhibits exceptional photosensitivity, good heat resistance and flexibility. Compared with unmodified resin, the solder resist ink prepared with the modified resin improved the resolution from 75 μm line spacing to 50 μm, and reduced the resistance undercut from 37.5 μm to 24.5 μm, showing higher resolution and better side erosion resistance.

Key words: epoxy acrylate, glycidyl ester of versatic acid, solder resist ink, resolution

王浩东, 孙冠卿, 安丰磊, 袁燕华, 刘仁. 叔碳酸缩水甘油酯改性碱溶性酚醛环氧丙烯酸酯的研究[J]. 影像科学与光化学, 2019, 37(3): 185-194.

WANG Haodong, SUN Guanqing, AN Fenglei, YUAN Yanhua, LIU Ren. Study on Alkali-soluble Epoxy Acrylates Resin Modified by Glycidyl Ester of Versatic Acid[J]. Imaging Science and Photochemistry, 2019, 37(3): 185-194.

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叔碳酸缩水甘油酯改性碱溶性酚醛环氧丙烯酸酯的研究

Study on Alkali-soluble Epoxy Acrylates Resin Modified by Glycidyl Ester of Versatic Acid

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