影像科学与光化学 ›› 1983, Vol. 1 ›› Issue (1): 31-38.DOI: 10.7517/j.issn.1674-0475.1983.01.31

• 研究论文 • 上一篇    下一篇

染色尼龙丝中光物理过程的研究——聚己内酰胺与染料1-氨基-4-羟基蒽醌之间的能量转移

许大年, 吴世康, 冯新德   

  1. 中国科学院感光化学研究所
  • 收稿日期:1982-01-09 出版日期:1983-01-23 发布日期:1983-01-23

PHOTOPHYSICAL PROCESSES IN DYED NYLON-6 FIBERENERGY TRANSFER FROM POLYCAPROLACTAM TO1-AMINO-4-HYDROXY-ANTHRAQUINONE

XU DA-NIAN, WU SHI-KANG, PENG XIN-DE   

  1. Institute of Photographic Chemistry, Academia Sinica
  • Received:1982-01-09 Online:1983-01-23 Published:1983-01-23

摘要: 在研究用染料1-氨基-4-羟基蒽醌染色的尼龙-6单丝的燐光光谱时,观察到染料的延迟荧光。这表明在这一体系中发生了聚合物的杂质基团与染料间的能量转移。用测定尼龙丝的燐光寿命随染料浓度变化的方法对此过程作动力学研究,测得能量转移速度常数kt=2901·mol-1·s-1,能量转移的临界距离R0=52.0Å,并证明该过程是以三线态-单线态的远程共振机理进行的,染料淬灭了尼龙-6中有害的杂质基团激发三线态,从而起到了光稳定化的作用。

Abstract: The delayed fluorescence of 1-amino-4-hydroxy-anthraquinone is observed in the phosphorescence spectrum of dyed nylon-6 fiber. This indicates that energy transfer occurs between polymer (impurity groups) and the dye. Kinetic analysis shows that the critical distance of energy transfer equals 52.0Å, and the rate constant of this process is 290 1·mol-1·s-1. It is proved that energy is transferred by a mechanism of long range resonance. After being irradiated, the dyed nylon fiber shows less strength loss than the undyed ones, which means the dye functions as a kind of photostabilizer.