影像科学与光化学 ›› 1983, Vol. 1 ›› Issue (3): 6-15.DOI: 10.7517/j.issn.1674-0475.1983.03.6

• 研究论文 • 上一篇    下一篇

掺杂立方AgBr乳剂介电频谱的研究——Ⅰ.Cd++、Cu++离子的影响

程虎民, 刘军   

  1. 北京大学化学系
  • 收稿日期:1982-02-20 出版日期:1983-08-20 发布日期:1983-08-20

A STUDY ON THE DIELECTRIC SPECTRA OF DOPEDCUBIC SILVER BROMIDE EMULSIONSⅠ.EFFECT OF Cd++ AND Cu++ IONS

CHENG HU-MIN, Liu JUN   

  1. Department of Chemistry, Beijing University
  • Received:1982-02-20 Online:1983-08-20 Published:1983-08-20

摘要: 测定了立方AgBr乳剂经添加不同量Cd(NO3)2、CdCl2、CdBr2、Cu(NO3)2、CuCl2、CuBr2、KCl和KBr以后的介电频谱,发现Cd++离子只有在卤素离子存在的情况下才能进入AgBr微晶的表面层晶格,使AgBr微晶表面层内填隙银离子浓度降低,从而使AgBr乳剂的介电吸收峰明显向低频方向偏移.Cu++离子很难进入AgBr微晶的表面层晶格,因而对介电吸收峰的位置和形状没有明显影响.这种差别可能主要是由于Cd++和Cu++离子的离子半径、电子层构型及晶体中的配位情况不同所引起的.最后,对Sillars方程应用于照相乳剂体系的条件作了初步探讨.

Abstract: The dielectric spectra of doped cubic silver bromide emulsions are studied.1-8 mol% Cd(NO3)2, CdCl2, CdBr,, Cu(NO3)2, CuCl2, CuBr2, KCl and KBr are added into the cubic AgBr emulsions, respectively.It is observed that the peaks of dielectric loss curves are broadened and markedly shifted to lower frequencies in silver bromide emulsions with CdCl2, and CdBr2, while there is no change in dielectric spectra in the case of Cd(NFO3)2 and Cu(NO3)2 doping.For emulsion samples with CuCl2, CuBr2, KCl and KBr, the peaks of dielectric loss curves are shifted slightly to higher frequencies.On the basis of these experimental results, it is deduced that Cd++ ions can incorporate into the crystal lattice on the surface of silver bromide crystal only in the presence of excess halogen ions in the emulsion, and that it is difficult for Cu++ ions to incorporate into the crystal lattice even when excess halogen ions are present.The difference in the behaviour of Cd++ and Cu++ ions is attributed to the difference between the radii of both ions, the electron configuration of the ions and their coordination in the crystals.Finally, the condition under which the Sillars equation applies to a photographic emulsion system is considered.