影像科学与光化学 ›› 1986, Vol. 4 ›› Issue (1): 1-7.DOI: 10.7517/j.issn.1674-0475.1986.01.1

• 研究论文 •    下一篇

金在硫加金敏化的乳剂中的作用——Ⅱ.硫加金敏化与金过敏化及金潜影加强的异同

陈次平, 王维钦, 刘敦   

  1. 中国科学院感光化学研究所
  • 收稿日期:1984-02-15 修回日期:1985-09-11 出版日期:1986-02-20 发布日期:1986-02-20

ROLE OF GOLD IN SULPHUR-PLUS-GOLD SENSITIZED EMULSION Ⅱ. SULPHUR-PLUS-GOLD SENSITIZATION COMPARED WITH GOLD HYPERSENSITIZATION AND GOLD INTENSIFICATION

CHEN CI-PING, WANG WEI-QIN, LIU TUN   

  1. Institute of Photographic Chemistry, Academia Sinica
  • Received:1984-02-15 Revised:1985-09-11 Online:1986-02-20 Published:1986-02-20

摘要: 本文采用硫氰酸金溶液对硫敏化的立方体溴化银乳剂分别进行潜影加强和过敏化处理,并与硫加金敏化的乳剂进行感光性能的比较。硫敏化的乳剂经过潜影加强处理,感光度有明显提高,表明金具有促进乳剂颗粒显影的作用。另一方面,硫敏化的乳剂经过潜影加强处理,感光度虽有提高,仍达不到硫加金敏化的效果,而硫敏化的乳剂经过过敏化处理能达到甚至超过硫加金敏化的效果。这暗示着金对于硫加金敏化乳剂颗粒在曝光过程中潜影的形成是有贡献的。 本文采用Dember效应测量了乳剂的离子电导率,并进行了信号衰减速率的动力学分析。结果表明,硫加金敏化的乳剂颗粒的离子电导率和一级衰减参数与硫敏化的乳剂颗粒的相比有减小的趋势。硫敏化的乳剂经过金盐溶液过敏化处理后,乳剂颗粒的离子电导率和一级衰减参数明显减小,从而验证了金盐法过敏化效应是由于增加了颗粒环境中的银离子浓度的机理。

Abstract: A comparison has been made between the sensitometric results obtained from sulphur-sensitized cubic silver bromide emulsions which are latensified and hypersensitized with a gold thiocyanate solution, respectively, and those obtained from sulphur-plus-gold sensitized emulsions. An increase in the speed of sulphur-sensitized emulsion by gold latensification demonstrates the enhancing action of gold on the development of emulsion grains. On the other hand, the effect of sulphur-sensitization plus gold latensification is less pronounced than that of sulphur-plus-gold sensitization, whereas, the effect of sulphur-sensitization plus gold hypersensitization is more pronounced than that of sulphur-plus-gold sensitization. This implies some functions of gold in enhancing latent image formation during exposure.The ionic conductivity of these emulsions are measured by the Dember effect. Kinetic analysis of the signal decay rates shows that there is a decreasing trend in the ionic conductivity of the sulphur-plus-gold sensitized emulsion grains and pseudo-first-order decay parameter as compared with those of the sulphur-sensitized emulsion grains. However, gold hypersensitization obviously decreases the ionic conductivity of the sulphur-sensitized emulsion grains and the pseudo-first-order decay parameter. This supports the view that the hypersensitizing effect arises from the increase in the concentration of silver ions in the grain environmen