影像科学与光化学 ›› 1986, Vol. 4 ›› Issue (1): 47-51.DOI: 10.7517/j.issn.1674-0475.1986.01.47

• 研究论文 • 上一篇    下一篇

萘与2,6-萘二甲酸二甲酯形成激基复合物的光物理过程

陈尚贤, 牛二平   

  1. 中国科学院化学研究所
  • 收稿日期:1985-04-09 修回日期:1985-06-15 出版日期:1986-02-20 发布日期:1986-02-20

THE PHOTOPHYSICAL PROCESSES OF EXCIPLEX FORMATION BETWEEN NAPHTHALENE AND 2,6-DIMETHYL NAPHTHALENE DICARBOXYLATE

CHEN SHANG-XIAN, NIU ER-PING   

  1. Institute of Chemistry, Academia Sinica
  • Received:1985-04-09 Revised:1985-06-15 Online:1986-02-20 Published:1986-02-20

摘要: 本文用时间分辨荧光光谱证实了萘与2,6-萘二甲酸二甲酯形成激基复合物。并结合稳态荧光光谱算出光物理过程的基元过程常数,讨论了结构与基元常数之间的关系。

Abstract: In this paper, the formation of exciplex between 2,6-dimethyl naphthalene dicar-boxylate and naphthalene was demonstrated by time-resolved fluorescence spectra. The elementary rate constants of the photophysieal processes were calculated by fluorescence spectra measured at steady-state condition. The relationship between the structure and the rate constant has been discussed.