9-乙烯基蒽和对-N,N-二甲氨基苯乙烯激基络合物的生成和光二聚反应

doi:10.7517/j.issn.1674-0475.1988.02.1

影像科学与光化学 ›› 1988, Vol. 6 ›› Issue (2): 1-6.DOI: 10.7517/j.issn.1674-0475.1988.02.1

• 研究论文 • 下一篇

9-乙烯基蒽和对-N,N-二甲氨基苯乙烯激基络合物的生成和光二聚反应

郭荣昆, 袁惠良, 杨礼娴, 吴飞鹏

中国科学院感光化学研究所, 北京

收稿日期:1986-10-06 修回日期:1987-07-24 出版日期:1988-05-20 发布日期:1988-05-20

THE EXCIPLEX FORMATION AND PHOTODIMERIZATION OF 9-VINYL ANTHRACENE AND P-N, N-DIMETHYLAMINO STYRENE

GUO RONG-KUN, YUAN HUI-LIANG, YANG LI-XIAN, WU FEI-PENG

Institute of Photographic Chemistry, Academia Sinica Beijing

Received:1986-10-06 Revised:1987-07-24 Online:1988-05-20 Published:1988-05-20

摘要/Abstract

摘要： 测定了9-乙烯基蒽和对-N,N-二甲氨基苯乙烯体系在不同极性的溶剂中的荧光光谱和荧光量子产率。发现随着溶剂极性的增加,激基络合物的荧光发生红移,荧光量子产率降低。同时9-乙烯基蒽和对-N,N-二甲氨基苯乙烯之间的光二聚产物的相对产率也降低。并讨论了经过激基络合物中间体的光二聚反应机理。

关键词: 激基络合物, 9-乙烯基蒽, 对-N,N-二甲氨基苯乙烯

Abstract: It was found that exciplex can be formed between singlet excited state of 9-vinyl anthracene and p-N, N-dimethylamino styrene in various solvents. Exciplex emission Wavelength red shifts and fluorescence quantum yield Φ_e of exciplex decrease with the increase of the polarity of solvents. The relative yield of photodimerization reduces with Φ_e. Exciplex intermediate mechanism was suggested for the photodimerization between 9-vinyl anthracene and p-N, N-dimethylamino styrene.

Key words: exciplex, 9-vinyl anthracene, p-N,N-dimethylamino styrene

郭荣昆, 袁惠良, 杨礼娴, 吴飞鹏. 9-乙烯基蒽和对-N,N-二甲氨基苯乙烯激基络合物的生成和光二聚反应[J]. 影像科学与光化学, 1988, 6(2): 1-6.

GUO RONG-KUN, YUAN HUI-LIANG, YANG LI-XIAN, WU FEI-PENG. THE EXCIPLEX FORMATION AND PHOTODIMERIZATION OF 9-VINYL ANTHRACENE AND P-N, N-DIMETHYLAMINO STYRENE[J]. Imaging Science and Photochemistry, 1988, 6(2): 1-6.

9-乙烯基蒽和对-N,N-二甲氨基苯乙烯激基络合物的生成和光二聚反应

THE EXCIPLEX FORMATION AND PHOTODIMERIZATION OF 9-VINYL ANTHRACENE AND P-N, N-DIMETHYLAMINO STYRENE

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