影像科学与光化学 ›› 1988, Vol. 6 ›› Issue (3): 32-35.DOI: 10.7517/j.issn.1674-0475.1988.03.32

• 研究论文 • 上一篇    下一篇

照相染料还原电位的研究

姚祖光, 徐小良, 强詠岭, 朱正华   

  1. 华东化工学院精细化工研究所 上海
  • 收稿日期:1987-05-09 修回日期:1988-02-12 出版日期:1988-08-20 发布日期:1988-08-20

STUDY ON THE REDUCTION POTENTIAL OF PHOTOGRAPHIC DYES

YAO ZU-CUANG, XU XIAO-LIANG, QIANG YONG-LING, ZHU ZHEN-HUA   

  1. Research Institute of Fine Chemicals, Bast China Institute of Chemical Technology, Shanghai
  • Received:1987-05-09 Revised:1988-02-12 Online:1988-08-20 Published:1988-08-20

摘要: 本文测定了八个照相染料在不同pH条件下的还原电位。发现其中一些增感染料的还原电位与其溶液的pH值无关,而一些减感染料依赖于pH值的变化。本文用染料质子化机理分析了这些结果。

关键词: 照相染料, 还原电位, 共轭链, 质子化

Abstract: In this paper the reduction potentials of eight photographic dyes were measured. It was found that reduction potential of some cyanine dyes are independent of pH, whereas that of desensitizing dyes are pH-dependent. These results were discussed in terms of the protonation mechanism of dyes.

Key words: photographic dye, reduction potential, conjugated chain, protonation