溴代酞菁铁配合物的光谱电化学性质研究

doi:10.7517/j.issn.1674-0475.1990.03.182

影像科学与光化学 ›› 1990, Vol. 8 ›› Issue (3): 182-185.DOI: 10.7517/j.issn.1674-0475.1990.03.182

溴代酞菁铁配合物的光谱电化学性质研究

吴星, 刘长庆, 严鹏权, 丁子庆

扬州师范学院化学系, 扬州 225002

收稿日期:1988-09-21 修回日期:1989-03-27 出版日期:1990-08-20 发布日期:1990-08-20
通讯作者: 吴星

SPECTRO-ELECTROCHEMICAL STUDY OF BROMOPHTHALOCYANINATO IRON

WU XING, LIU CHANG-QING, YAN PENG-QUAN, DING ZI-QING

Department of Chemistry, Yangzhou Teachers College, Yangzhou 225002, P. R. China

Received:1988-09-21 Revised:1989-03-27 Online:1990-08-20 Published:1990-08-20

摘要/Abstract

摘要： 本文对μ-氧-四溴酞菁铁配合物([TBPcFe]₂O)的电化学性质及光谱电化学性质进行了研究。结果表明,μ-氧-四溴酞菁铁在所研究的电压区问内经历了三个单电子氧化还原反应,其半波电势为0.06V,—0.75V及—1.33V(相对于甘汞电极),分别对应于Fe³⁺/Fe³⁼、Fe²⁺/Fe⁺及TBPc^2-/TBPc^3-电对的氧化还原反应。光谱电化学性质研究亦观察到相应酞菁配合物的特征光谱。

关键词: 四溴酞菁铁, 光谱电化学

Abstract: Electrochemical and spectro-electrochemical properties of n-oxo-tetrabromophthalocyaninato iron ([TBPcFe]₂O) were studied.The experimental results showed that u-oxo-tetrabromoph-thalocyaninato iron undergoes three one-electron redox reactions,the half-wave potentials (E_1/2) of which are 0.06V,-0.75V and -1.33V (Hg₂Cl₂/Hg reference),corresponding to Fe³⁺/ Fe²⁺,Fe²⁺/Fe⁺ and TBPc^2-/TBPc^3- respectively.The typical spectra of the corresponding; complexes were also observed in the spectro-electrochemical studies.

Key words: tetrabromophthalocyaninato iron, spectro-electrochemical method

吴星, 刘长庆, 严鹏权, 丁子庆. 溴代酞菁铁配合物的光谱电化学性质研究[J]. 影像科学与光化学, 1990, 8(3): 182-185.

WU XING, LIU CHANG-QING, YAN PENG-QUAN, DING ZI-QING. SPECTRO-ELECTROCHEMICAL STUDY OF BROMOPHTHALOCYANINATO IRON[J]. Imaging Science and Photochemistry, 1990, 8(3): 182-185.

溴代酞菁铁配合物的光谱电化学性质研究

SPECTRO-ELECTROCHEMICAL STUDY OF BROMOPHTHALOCYANINATO IRON

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