叶绿素光敏氧化香叶烯合成齿小蠹二烯醇

doi:10.7517/j.issn.1674-0475.1991.02.107

影像科学与光化学 ›› 1991, Vol. 9 ›› Issue (2): 107-111.DOI: 10.7517/j.issn.1674-0475.1991.02.107

叶绿素光敏氧化香叶烯合成齿小蠹二烯醇

何慧珠, 魏淑霞, 谢洁, 王夺元

中国科学院感光化学研究所北京 100101

收稿日期:1989-08-21 修回日期:1990-03-19 出版日期:1991-05-20 发布日期:1991-05-20
通讯作者: 何慧珠

SYNTHESIS OF IPSDIENOL FROM MYRCENE WITH CHLORO-PHYLL SENSITIZED PHOTOOXIDATION

HE HUI-ZHUO, WEI SHU-XIA, XIE JIE, WANG DUO-YUAN

Institute of Photographic Chemistry, Academia Sinica Beijing 100101, P. R. China

Received:1989-08-21 Revised:1990-03-19 Online:1991-05-20 Published:1991-05-20

摘要/Abstract

摘要： 报道了以叶绿素(Chl)为敏化剂、香叶烯光敏氧化的同时用四丁基硼氢化铵(TBABH₄)还原得到相应的二级和三级烯丙基醇。讨论了玫瑰红(RB)、甲素(HA)和叶绿素三种敏化剂对产物分布的影响。实验结果表明:以叶绿素为敏化剂由香叶烯合成的齿小蠹二烯醇(Ipsdienol,2-甲基-6-甲叉基-2,7-辛二烯-4-醇),副产物少,收率较高。还讨论了还原剂的用量及光照时间对产物的影响。

关键词: 叶绿素, 香叶烯, 齿小蠹二烯醇, 四丁基硼氢化铵

Abstract: This paper reports chlorophyll sensitized photooxidation of myrcene with simultaneous reduction of hydroperoxides with TBABH₄ to the corresponding mixture of secondary and tertiary allylic alcohols. Effect of sensitizers, RB. HA and Chl., irradiation time and the amount of reductant on product distribution were discussed. The experimental results show that the synthesis of ipsdienol from myrcene with chlorophyll as a sensitizer can obtain ipsdienol in good yield.

Key words: chlorophyll, myrcene, ipsdienol, tetrabutylammonium borohydride

何慧珠, 魏淑霞, 谢洁, 王夺元. 叶绿素光敏氧化香叶烯合成齿小蠹二烯醇[J]. 影像科学与光化学, 1991, 9(2): 107-111.

HE HUI-ZHUO, WEI SHU-XIA, XIE JIE, WANG DUO-YUAN. SYNTHESIS OF IPSDIENOL FROM MYRCENE WITH CHLORO-PHYLL SENSITIZED PHOTOOXIDATION[J]. Imaging Science and Photochemistry, 1991, 9(2): 107-111.

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叶绿素光敏氧化香叶烯合成齿小蠹二烯醇

SYNTHESIS OF IPSDIENOL FROM MYRCENE WITH CHLORO-PHYLL SENSITIZED PHOTOOXIDATION

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