影像科学与光化学 ›› 1994, Vol. 12 ›› Issue (2): 115-119.DOI: 10.7517/j.issn.1674-0475.1994.02.115

• 研究论文 • 上一篇    下一篇

ClInPc-(TPD-PVK)光电导体性能的研究

胡庆美, 黄德本   

  1. 浙江大学化学系 杭州 310027
  • 收稿日期:1993-04-20 出版日期:1994-05-20 发布日期:1994-05-20
  • 通讯作者: 胡庆美

ELECTROPHOTOGRAPHIC CHARACTERISTICS OF THE PHOTORECEPTOR DEViCE CONSISTING OF ClInPc/(PVK-TPD)

HU QING-MEI, HUANGC DE-BEN   

  1. Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R.China
  • Received:1993-04-20 Online:1994-05-20 Published:1994-05-20

摘要: 本文以氯化酞菁铟(ClInPc)为载流子发生层(CGL),四苯基联苯胺(TPD)与聚乙烯咔唑(PVK)复合为载流子传输层(CTL),形成双层结构的功能分离型有机光电导体(P/R),研究了它的静电感光性能。结果表明,ClInPc/PMMA(30%)与TPD/PVK(1:1)两者匹配时的P/R具有良好的光电导性能,其电荷接受能力Vmax≈800V,光电导率△Vt(ls)>70%,暗衰小(<50V/s),残余电位低(30V/s).由真空蒸镀成膜(CGL)所研制的P/R的光电导性能更为优异。

关键词: 氯化酞菁铟, 四苯基联苯胺, 有机光电导体, 光电导性能

Abstract: The photoelectroconductivity of a double-layered photoreceptor (P/R) was studiedin the paper,in which the chloroinduim phthalocyanine(ClInPc)was a carrier gen-eration layer and polyvinyl carbazole (PVK) incoporating tetraphenyl benzidine (TPD) as,a carrier transportation layer. Results of the P/R consisting of ClInPc/PMMA (30%) matched with TPD/PVK (1:1) shows excellent protoelectronic properties:acceptance po-tential,Vmax (800V);residual potential,Vmin (30V/s);dark decay,RD (<50V/s);light dis-charge,△Vt (ls) >70%;half decay,t1/2(ls)=0.30~0.53. Simultaneously the photoelectronicproperties of the P/R device in which the CGL is made by means of evaporating at vacuumare better than that of other method.

Key words: chloroindium phthalocyanine, tetraphenylbenzidine, organic electro photoreceptor, electrophotography electro photoconductivity