影像科学与光化学 ›› 1995, Vol. 13 ›› Issue (3): 248-250.DOI: 10.7517/j.issn.1674-0475.1995.03.248

• 研究快讯 • 上一篇    下一篇

SYNTHESES OF AZETIDINES VIA PHOTOCYCLOADDITION OF C=C TO C=N DOUBLE BONDS

FENG JUN, MING YANG-FU, FAN MEI-GONG   

  1. 中国科学院感光化学研究所, 北京 100101
  • 收稿日期:1995-02-26 修回日期:1995-04-21 出版日期:1995-08-20 发布日期:1995-08-20
  • 通讯作者: FAN MEI-GONG
  • 基金资助:
    国家自然科学基金

SYNTHESES OF AZETIDINES VIA PHOTOCYCLOADDITION OF C=C TO C=N DOUBLE BONDS

FENG JUN, MING YANG-FU, FAN MEI-GONG   

  1. Institute of Photographic Chemistry, the Chinese Academy of Sciemes, Beijing 100101, P. R. China
  • Received:1995-02-26 Revised:1995-04-21 Online:1995-08-20 Published:1995-08-20

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摘要： The photocycloaddition of 6-azauracil (AU) with olefins have been carried out. Four new compounds,1,2,4-triazabicyclo [4,2,0] octane and 1,2,4-triazatricyclo [4,2,01.6,07.12]dodecane derivatives,were obtained. Based on structure identificationof productsand photosensitization behavior of this syste,the regioselection and the multiplicity of thisreaction were discussed.

关键词: 6-azauracil, photocycloaddition, regioselectivity

Abstract: The photocycloaddition of 6-azauracil (AU) with olefins have been carried out. Four new compounds,1,2,4-triazabicyclo [4,2,0] octane and 1,2,4-triazatricyclo [4,2,01.6,07.12]dodecane derivatives,were obtained. Based on structure identificationof productsand photosensitization behavior of this syste,the regioselection and the multiplicity of thisreaction were discussed.

Key words: 6-azauracil, photocycloaddition, regioselectivity

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