影像科学与光化学 ›› 1997, Vol. 15 ›› Issue (2): 155-160.DOI: 10.7517/j.issn.1674-0475.1997.02.155

• 研究简报 • 上一篇    下一篇

单分散扁平卤化银微晶成核过程的研究

胡勇军, 王荣琴, 彭必先   

  1. 中国科学院感光化学研究所, 北京100101
  • 收稿日期:1996-07-19 修回日期:1997-01-13 出版日期:1997-05-20 发布日期:1997-05-20
  • 通讯作者: 彭必先
  • 基金资助:
    国家自然科学基金资助项目(批准号:29473138)

STUDY OF NUCLEATION OF MONODISPERSE TABULAR GRAIN OF SILVER HALIDE

HU Yongjun, WANG Rongqin, PENG Bixian   

  1. Institute of Photographic Chemistry, The Chinese Academy of Sciences, Beijing 100101, P.R. China
  • Received:1996-07-19 Revised:1997-01-13 Online:1997-05-20 Published:1997-05-20

摘要: 多年来,卤化银乳剂微晶体制备的研究重点一直放在宏观相的结构与性能的关系上,已经发现卤化银照相乳剂的感光性能与晶体的结构和大小有很重要的关系[1,2]。随着研究工作的深入,人们逐渐认识到:晶体的成核过程决定着宏观相微晶体的结构和形状,因此成核过程的研究日益受到人们的关注。Tanaka[3,4]应用分光光度法从反应动力学角度入手研究AgX微晶的成核过程。

关键词: 卤化银乳剂, 成核过程, 扁平颗粒

Abstract: he formation of monodispersed hexagonal T grain of silver bromide has been observed and investigated by means of analytical electron microscopy. The morphological observation of the grains shows clearly that: the formation of tabular grain is a gradual evolution process. At the early nucleation stage the grains are spherical, after definite time the spherical grains become tabular. The size distribution indicates that at the nucleation stage two district populations (grain size distribution peaks) appear on the size distribution curve. Between these two peaks there is a critical size. Grains of size being larger than that critical size tend to grow and become tabular, while the others smaller than critical size is apt to desappears or become small. The values of n of silver halide cluster at the early nucleation stage has been estimated and discussed.

Key words: silver halide emulsion, nucleation, T-grain