影像科学与光化学 ›› 1998, Vol. 16 ›› Issue (2): 111-116.DOI: 10.7517/j.issn.1674-0475.1998.02.111

• 综述 • 上一篇    下一篇

沸石的包结作用提高分子内萘蒽的交叉光加成

佟振合, 苏宁, 吴骊珠, 苑振宇   

  1. 中国科学院感光化学研究所, 北京100101
  • 收稿日期:1997-12-23 修回日期:1997-12-31 出版日期:1998-05-20 发布日期:1998-05-20
  • 通讯作者: 佟振合
  • 基金资助:

    国家自然科学基金资助项目(批准号:29392205),中科院基础局项目(KJ951-A-1-503).

ENHANCEMENT OF PHOTOINDUCED INTRAMOLECULAR CROSSDIMERIZATION BETWEEN NAPHTHALENE AND ANTHRACENE MOIETIES VIA INCLUSION WITHIN ZEOLITE

TONG Zhenhe(Chen HoTung), SU Ning, WU Lizhu, YUAN Zhenyu   

  1. Institute of Photographic Chemistry, The Chinese Academy of Sciences, Beijing 100101, P. R. China
  • Received:1997-12-23 Revised:1997-12-31 Online:1998-05-20 Published:1998-05-20

摘要:

萘与萘、蒽与蒽的光二聚反应已经被广泛研究,但萘与蒽的交叉光二聚反应报道不多。我们合成了两末端分别以萘和蒽标记的聚醚化合物,利用NaY沸石的孔腔作为纳米反应器,将此化合物置于孔腔中,通过光反应得到分子内的萘和蒽交叉二聚体。

关键词: 沸石, 萘蒽交叉光加成, 双发色团分子

Abstract:

Although the photodimerizat ion of anthracene[1] and that of naphthalene[2,3] have beenext ensively studied,until recently relatively little has been reported on the cross-phot odimer-ization between an ant hracene and a naphthalene moiety[4].

Key words: zeolite, cross-photodimerization between naphthalene and anthrancene, bichromophoric molecule