用复相光催化剂WO3/α-Fe2O3/W深度处理造纸废水的研究

doi:10.7517/j.issn.1674-0475.2001.02.131

影像科学与光化学 ›› 2001, Vol. 19 ›› Issue (2): 131-138.DOI: 10.7517/j.issn.1674-0475.2001.02.131

用复相光催化剂WO₃/α-Fe₂O₃/W深度处理造纸废水的研究

崔玉民¹, 朱亦仁¹, 何东宝²

1. 阜阳师范学院化学系, 阜阳236032;
2. 武汉大学环境科学院, 武汉430072

收稿日期:2000-09-29 修回日期:2001-01-02 出版日期:2001-05-20 发布日期:2001-05-20
通讯作者: 崔玉民(1964-), 男, 硕士, 副教授, 主要从事光催化、有机合成方面的研究及其教学工作.
基金资助:
安徽省教委自然科学基金资助项目(99JL0162)

A STUDY ON TREATMENT OF PAPERMAKING WASTEWATER BY WO₃/α-Fe₂O₃/W AS HETEROGENEOUS PHOTOCATALYST

CUI Yu-min¹, ZHU Yi-ren¹, HE Dong-bao²

1. Department of Chemistry, Fuyang Teacher’s College, Fuyang 236032, P.R. China;
2. Institute of Environmental Science, Wuhan University, Wuhan 430072, P.R. China

Received:2000-09-29 Revised:2001-01-02 Online:2001-05-20 Published:2001-05-20

摘要/Abstract

摘要： 采用光催化法对造纸废水的处理进行了研究.探讨了光催化反应机理,比较了光催化剂的活性顺序,讨论了复相光催化剂的组成、用量、试液pH值、光照时间与COD、色度去除率的关系.实验结果表明:采用WO₃/α-Fe₂O₃/W为复相光催化剂,其组成为WO₃:α-Fe₂O₃:W＝75:24:1,当其用量为0.500g、pH＝6.5、光照22h,造纸废水的COD和色度去除率分别达到68.3%和71.2%.

关键词: 复相光催化剂, 造纸废水, 去除率, 三氧化钨

Abstract: Papermaking wastewater was treated by a photocatalytic oxidation process. Reaction mechanism of photocatalysis was probed. The active order of photocatalyst was compared. The effects of primary factors on the removal efficiencies of COD and colority were discussed. The experimental results indicate that the removal efficiencies of COD and colority in papermaking wastewater can reach 68.3% and 71.2% respectively by using WO₃/α-Fe₂O₃/W as heterogeneous photocatalyst, with the composition of heterogeneous photocatalyst=75:24:1, quantity=0.500 g, pH= 6.5, illumination=22 h.

Key words: heterogeneous photocatalyst, papermaking wastewater, removal efficiency, tungsten trioxide

中图分类号:

O644

崔玉民, 朱亦仁, 何东宝. 用复相光催化剂WO₃/α-Fe₂O₃/W深度处理造纸废水的研究[J]. 影像科学与光化学, 2001, 19(2): 131-138.

CUI Yu-min, ZHU Yi-ren, HE Dong-bao. A STUDY ON TREATMENT OF PAPERMAKING WASTEWATER BY WO₃/α-Fe₂O₃/W AS HETEROGENEOUS PHOTOCATALYST[J]. Imaging Science and Photochemistry, 2001, 19(2): 131-138.

参考文献

[1] 杜仰民.造纸工业废水治理进展与评述[J].工业水处理,1997,17(3):1-5. Du Yang-min. Reviews and progress of waste water treatment in paper manufacturing[J]. Industrial Water Treatment. 1997,17(3):1-5.
[2] 杨润昌,周书天.硫酸对草浆造纸黑液催化作用的研究[J].环境科学,1994,15(5):46-48. Yang Run-chang, Zhou Shu-tian. Study on the role of sulfuric acid in the catalytical hydrolysis of black liquor from straw fiber pulping process[J]. Environmental Science, 1994,15(5):46-48.
[3] 朱亦仁,潘碌亭.乳状液膜法处理草浆纸厂黑液[J].华东理工大学学报,1998,24(3):368-371. Zhu Yi-ren, Pan Lu-ting. Treatment of straw pulp and paper mill black liquor by emulsion liquid membrane technique[J]. Journal of East China University of Science and Technology, 1998,24(3):368-371.
[4] Kambe S, Fuji M, Kawai T. The removal of substituted phenols by a photocatalytic oxidation process with CdS[J]. Chemical Physics Letters, 1984,109:105.
[5] 贺北平,王占生,张锡挥.半导体光催化氧化有机物的研究现状及发展趋势[J].环境科学,1994,15(3):80. He Bei-ping, Wang Zhan-sheng, Zhang Xi-hui. Advance in research on the photocatalytic oxidation of organic compounds over semiconductor materials[J]. Environmental Science, 1994,15(3):80.
[6] 文学洙.用半导体光催化剂WO₃处理印染废水的研究[J].太阳能学报,1985,6(2):201. Wen Xue-zhu. Studies on the treatment of printing and dyeing wastewater by photocatalyst WO₃[J]. Journal of Solar Energy, 1985,6(2):201.
[7] 崔玉民,孙文中.亚硫酸盐的光催化氧化[J].阜阳师范学院学报(自然),1998,(2):23-26. Cui Yu-min, Sun Wen-zhong. Photocatalytic oxidation of SO₃^2-[J]. Journal of Fuyang Teacher's College(Nature), 1998,(2):23-26.
[8] 崔玉民,朱亦仁.光催化氧化脱除硫化物[J].燃料化学学报,2000,28(5):468-472. Cui Yu-min, Zhu Yi-ren. Removal of sulphide by photocatalytic oxidation process[J]. Journal of Fuel Chemistry and Technology, 2000,28(5):468-472.
[9] 陈德智,文学洙.复相光催化剂WO₃/α-Fe₂O₃/W氧化水溶液中SO₃^2-的研究[J].化学通报,1988,(5):32-33. Chen, De-zhi, Wen Xue-zhu. Oxidation of SO₃^2- with heterogeneous photocatalyst WO₃/α-Fe₂O₃/W in aqueous solution[J]. Chemistry (Chemistry Bulletin), 1988,(5):32-33.
[10] 潭小萍,王国生,汤克敏.光催化氧化法用于垃圾渗滤液深度处理主要影响因素的试验研究[J].环境科学动态,1999,(1):28-30. Tan Xiao-ping, Wang Guo-sheng, Tang Ke-min. A study on the influences of chief factors on the depth treatment of percolation filtrate from rubbish[J]. Environmental Science Trends, 1999,(1):28-30.
[11] Wei T Y, Wan C C. Heterogeneous photocatalytic oxidation of phenol with titanium dioxide particles[J]. Ind. Eng. Chem., 1991,30:1293.
[12] Matthews R W. Photooxidation of organic impurities in water using thin films of titanium dioxide[J]. J. Phys. Chem., 1987,91:3328-3333.

用复相光催化剂WO₃/α-Fe₂O₃/W深度处理造纸废水的研究

A STUDY ON TREATMENT OF PAPERMAKING WASTEWATER BY WO₃/α-Fe₂O₃/W AS HETEROGENEOUS PHOTOCATALYST

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 2

编辑推荐

Metrics

本文评价

[1]	解恒参, 朱亦仁, 李爱梅, 鲁玲. 二氧化钛粉体在纸厂废水处理中的应用[J]. 影像科学与光化学, 2006, 24(4): 312-317.
[2]	陈次平, 任新民, 陆道惠, 张永康. 乙酸钠、草酸钠、酒石酸钾在三氧化钨-水体系中光生自由基的研究[J]. 影像科学与光化学, 1991, 9(4): 299-303.