DAR成色剂结构与性能的关系

doi:10.7517/j.issn.1674-0475.2004.04.306

影像科学与光化学 ›› 2004, Vol. 22 ›› Issue (4): 306-317.DOI: 10.7517/j.issn.1674-0475.2004.04.306

• 综述 • 上一篇

DAR成色剂结构与性能的关系

刘玉婷^1,2, 吕峰¹, 邹竞³, 张大德¹, 姚祖光¹

1. 华东理工大学, 精细化工研究所, 上海, 200237;
2. 陕西科技大学化学与化工学院, 陕西, 咸阳, 712081;
3. 中国乐凯胶片集团公司, 河北, 保定, 071054

收稿日期:2004-03-01 修回日期:2004-04-08 出版日期:2004-07-23 发布日期:2004-07-23
通讯作者: 刘玉婷(1971-), 女, 讲师, 博士研究生, 研究方向:有机合成.
基金资助:
中国乐凯胶片公司资助课题.

Relation Between DAR Coupler’s Structure and Property

LIU Yu-ting^1,2, ¹, LÜ Feng³, ZOU Jing¹, ZHANG Da-de¹

1. Institute Research of Fine Chemicals, East China University of Science and Technology, Shanghai 200237, P.R. China;
2. College of Chemistry and Chemical Engineering, Shanxi University of Science and Technology, Xianyang 712081, Shanxi, P.R. China;
3. China L ucky Fil m Company, Baod ing 071054, H ebei, P.R. China

Received:2004-03-01 Revised:2004-04-08 Online:2004-07-23 Published:2004-07-23

摘要/Abstract

摘要： 通过分析DAR成色剂的结构和作用机理,讨论了其结构与照相性能之间的关系.DAR成色剂的结构可表示为:Cp—L—A,其中Cp代表成色剂母体,A代表促进显影的功能基团即增强基团,L代表连接基团同时也有吸附功能即吸附基团.本文指出:当吸附基团和增强基团相同时,母体对照相性能影响不大;当母体及增强基团相同时,吸附基团的吸附性越强,照相性能越好;当母体及吸附基团相同时,增强基团的感染显影作用越强,照相性能越好.

关键词: DAR成色剂, 结构, 作用机理, 性能

Abstract: The relation of the structure of DAR coupler and it’s photographic property was reported by analysizing the structure of DAR coupler.The structure of DAR coupler can be represented by Cp-L-A.Cp is the coupler residue;L is the divalent linking group also is the adsorbing group;A is the development accelerating functional group.In this paper,conclusion were made:the Cp can make no effect apparently on photographic property when L and A are the same.The stronger of the development accelerating functional group,the better of the DAR coupler’s photographic property when Cp and L are the same.The stronger of the adsorbability of adsorbing group,the better of the DAR coupler’s photographic property when Cp and A are the same.

Key words: DAR coupler, structure, mechanism, property

中图分类号:

O644

刘玉婷, 吕峰, 邹竞, 张大德, 姚祖光. DAR成色剂结构与性能的关系[J]. 影像科学与光化学, 2004, 22(4): 306-317.

LIU Yu-ting, , LÜ Feng, ZOU Jing, ZHANG Da-de, YAO Zu-guang. Relation Between DAR Coupler’s Structure and Property[J]. Imaging Science and Photochemistry, 2004, 22(4): 306-317.

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DAR成色剂结构与性能的关系

Relation Between DAR Coupler’s Structure and Property

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