影像科学与光化学 ›› 2004, Vol. 22 ›› Issue (5): 321-326.DOI: 10.7517/j.issn.1674-0475.2004.05.321

• 研究快讯 •    下一篇

聚苯乙烯负载多吡啶铂(Ⅱ)炔基络合物的合成

彭明丽, 吴骊珠, 张丽萍, 佟振合   

  1. 中国科学院理化技术研究所, 北京, 100101
  • 收稿日期:2004-06-14 修回日期:2004-07-02 出版日期:2004-09-23 发布日期:2004-09-23
  • 通讯作者: 佟振合,吴骊珠.

Synthesis of Polystyrene-Supported Polypyridyl Platinum Acetylide Complex

PENG Ming-li, WU Li-zhu, ZHANG Li-ping, TONG Zhen-he   

  1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, P. R. China
  • Received:2004-06-14 Revised:2004-07-02 Online:2004-09-23 Published:2004-09-23

摘要: 通过自由基共聚成功地将具有高磷光发光效率的-苯基-2,2’-二联吡啶(C^N^N)Pt(Ⅱ)苯乙炔络合物共价键合在聚苯乙烯高分子骨架上,得到了发射磷光的聚合物.实验表明,发光聚合物基本保持了多吡啶铂络合物单体的光谱性质.具有与小分子相当的光致发光效率.

关键词: 6-苯基2,2’-二联吡啶(C^N^N)Pt(Ⅱ)苯乙炔, 聚苯乙烯, 发光聚合物

Abstract: 6-phenyl-2,2’-bipyridyl platinum (Ⅱ) acetylide complex with high luminescent quantum yield was covalently bonded to polystyrene by radical copolymerization.It was noted that the lumeniscent polymer displayed the similar spectroscopic properties compared with those of 6-phenyl-2,2’-bipyridyl platinum (Ⅱ) acetylide complex.

Key words: 6-phenyl-2,2’-bipyridyl platinum (Ⅱ) acetylide complex, polystyrene, luminescent polymer

中图分类号: