L(-)-α-苯乙胺拆分2-萘甲酸类立方烷光二聚体

doi:10.7517/j.issn.1674-0475.2006.06.404

影像科学与光化学 ›› 2006, Vol. 24 ›› Issue (6): 404-407.DOI: 10.7517/j.issn.1674-0475.2006.06.404

L(-)-α-苯乙胺拆分2-萘甲酸类立方烷光二聚体

雷蕾, 吴骊珠, 佟振合, 张丽萍

中国科学院, 理化技术研究所, 超分子光化学实验室, 北京, 100080

收稿日期:2006-06-20 修回日期:2006-07-05 出版日期:2006-11-23 发布日期:2006-11-23
通讯作者: 吴骊珠;佟振合
基金资助:
科技部国家重点基础研究发展规划项目(2003CB716802,2004CB719903);国家自然科学基金资助项目(20125207,20333080,20332040,20472091);中科院基础局资助项目(KJCX2-SW-H15).

Resolution of Cubane-like Photodimer of Carboxylic 2-Naphthoate by L-(-)-α-Phenyl Ethylamine

LEI Lei, WU Li-zhu, TONG Zhen-he(TUNG Chen-ho), ZHANG Li-ping

Laboratory of Supramolecular Photochemistry, Technical Institute of Physics and Chemistry, the Chinese Academy of Sciences, Beijing 100080, P.R. China

Received:2006-06-20 Revised:2006-07-05 Online:2006-11-23 Published:2006-11-23

摘要/Abstract

摘要： 使用L(-)-α-苯乙胺作为手性衍生化试剂,拆分了外消旋的类立方烷2-萘甲酸光二聚体,并通过圆二色谱进行了证明.

关键词: 类立方烷2-萘甲酸光二聚体, L(-)-α-苯乙胺, 拆分, 手性衍生化试剂

Abstract: The racemic photodimer of carboxylic 2-naphthoate was successfully resolved by using L(-)-α -methylbenzylamine as chiral derivative agentia (CDA).The circular dichroism spectra of the resolved racemic mixture were obtained.

Key words: resolution, cubane-like photodimer of carboxylic 2-naphthoate, L-(-)-α-phenyl ethylamine, chiral derivative agentia (CDA)

中图分类号:

雷蕾, 吴骊珠, 佟振合, 张丽萍. L(-)-α-苯乙胺拆分2-萘甲酸类立方烷光二聚体[J]. 影像科学与光化学, 2006, 24(6): 404-407.

LEI Lei, WU Li-zhu, TONG Zhen-he(TUNG Chen-ho), ZHANG Li-ping. Resolution of Cubane-like Photodimer of Carboxylic 2-Naphthoate by L-(-)-α-Phenyl Ethylamine[J]. Imaging Science and Photochemistry, 2006, 24(6): 404-407.

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L(-)-α-苯乙胺拆分2-萘甲酸类立方烷光二聚体

Resolution of Cubane-like Photodimer of Carboxylic 2-Naphthoate by L-(-)-α-Phenyl Ethylamine

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