基于蒽酰亚胺基团的新型Fe3+和Hg2+化学敏感器

doi:10.7517/j.issn.1674-0475.2009.01.23

影像科学与光化学 ›› 2009, Vol. 27 ›› Issue (1): 23-31.DOI: 10.7517/j.issn.1674-0475.2009.01.23

基于蒽酰亚胺基团的新型Fe³⁺和Hg²⁺化学敏感器

徐全清^1,2, 王俊^1,2, 张辉淼^1,2, 傅文甫¹

1. 中国科学院, 理化技术研究所, 北京100190;
2. 中国科学院, 研究生院, 北京100049

收稿日期:2008-05-20 修回日期:2008-06-10 出版日期:2009-01-23 发布日期:2009-01-23
通讯作者: 傅文甫,E-mail:fuwf@mail.ipc.ac.cn
基金资助:
国家自然科学基金资助项目(20671094,90610034)

New Selective Fe³⁺ and Hg²⁺ Ions Chemosensors Based on Anthracenecarbonamide Derivatives

XU Quan-qing^1,2, WANG Jun^1,2, ZHANG Hui-miao^1,2, FU Wen-fu¹

1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received:2008-05-20 Revised:2008-06-10 Online:2009-01-23 Published:2009-01-23

摘要/Abstract

摘要： 含蒽酰亚胺基团的化合物N-(2-(6-氨基吡啶))-9-蒽酰亚胺(L¹)对Fe³⁺表现出灵敏的荧光增强响应.L¹的衍生物N,N-’(2,6-吡啶基)-二(9-蒽酰亚胺)(L²)对Hg²⁺在紫外-可见吸收光谱和荧光光谱上显示了良好的识别性.即使在其它金属阳离子存在下,L¹和L²分别对于Fe³⁺和Hg²⁺仍然表现出较好的选择性.

关键词: 蒽酰亚胺, 化学敏感器, Fe³⁺, Hg²⁺, 光谱

Abstract: Two synthesized compounds,N-(6-aminopyridine2-yl)-9-anthracenecarbonamide(L¹) and N,N’-(pyridine-2,6-yl)-bis(9-anthracenecarbonamide)(L²) are found to show good sensitivity and selectivity to Fe³⁺ and Hg²⁺ ions,respectively.L¹ shows highly sensitive response to Fe³⁺ on fluorescence spectrum.The recognition of L² to Hg²⁺ could be achieved by using absorption and fluorescence spectra.The effect of the presence of other metal ions on sensing for the aim ions were studied too.In addition,the coordination models of these two compounds with metal ions were suggested.

Key words: anthracenecarbonamide, chemosensor, Fe³⁺, Hg²⁺, spectroscopy

中图分类号:

徐全清, 王俊, 张辉淼, 傅文甫. 基于蒽酰亚胺基团的新型Fe³⁺和Hg²⁺化学敏感器[J]. 影像科学与光化学, 2009, 27(1): 23-31.

XU Quan-qing, WANG Jun, ZHANG Hui-miao, FU Wen-fu. New Selective Fe³⁺ and Hg²⁺ Ions Chemosensors Based on Anthracenecarbonamide Derivatives[J]. Imaging Science and Photochemistry, 2009, 27(1): 23-31.

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基于蒽酰亚胺基团的新型Fe³⁺和Hg²⁺化学敏感器

New Selective Fe³⁺ and Hg²⁺ Ions Chemosensors Based on Anthracenecarbonamide Derivatives

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