含氟丙烯酸酯光致聚合物的全息特性研究

doi:10.7517/j.issn.1674-0475.2009.02.103

影像科学与光化学 ›› 2009, Vol. 27 ›› Issue (2): 103-110.DOI: 10.7517/j.issn.1674-0475.2009.02.103

含氟丙烯酸酯光致聚合物的全息特性研究

李芳, 朱宗文, 王跃川

四川大学, 高分子科学与工程学院, 四川, 成都610065

收稿日期:2008-07-07 修回日期:2008-09-09 出版日期:2009-03-23 发布日期:2009-03-23

Holographic Performance of Fluorinated Acrylate Photopolymer

LI Fang, ZHU Zong-wen, WANG Yue-chuan

College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, Sichuan, P. R. China

Received:2008-07-07 Revised:2008-09-09 Online:2009-03-23 Published:2009-03-23

摘要/Abstract

摘要： 提高记录单体在成膜物中的迁移速率,加大记录单体与成膜物的折射率差,可以实现光致聚合物的折射率空间调制最大化.本工作以高折射率的超支化聚酯(折射率1.586)为成膜树脂,利用超支化聚合物分子结构疏松、便于小分子在其间扩散的特性,同时以低折射率的单官能团含氟丙烯酸酯(折射率1.372)和高活性的双官能团丙烯酸酯(折射率1.457)为记录单体制备了光致聚合物全息膜,以衍射效率为指标优化单体构成和全息膜的厚度,研究了该全息膜的衍射效率、空间分辨率、折射率调制度等性能.该光致聚合物全息材料的折射率调制度为4.82×10^-3,衍射效率达到99.4%,在空间分辨率3750 lp/mm的衍射效率仍然达到85.6%,感光灵敏度56 mJ/cm².

关键词: 光致聚合物, 超支化聚酯, 全息材料

Abstract: By enhancing the diffusion of monomer,and by increasing the difference of refractive index between the recording monomer and the binder resin,modulation of refractive index of photopolymer for holographic recording will be greatly realized.Hyperbranched polyester (refractive index 1.586),with the loosely packing molecular structure that makes the monomer transport easily,and fluorine-containing acrylate (refractive index 1.372) combining with highly reactive diacrylate (refractive index 1.457) were used in this work as the binders and monomer,respectively,of photopolymer for holographic recording.The effects of composition and film thickness on diffraction efficiency of holographic recording were studied,as well as the characteristic space resolution and refractive-index modulation of the new holographic recording material.The photopolymer exhibited excellent performance of holographic recording with modulation of refractive index about 4.82×10^-3,photosensitivity 56 mJ/cm²,diffraction efficiency up to 99.4%,and 85.6% even at resolution as high as to 3754 lp/mm.

Key words: photopolymer, hyperbranched polyester, holographic material

中图分类号:

李芳, 朱宗文, 王跃川. 含氟丙烯酸酯光致聚合物的全息特性研究[J]. 影像科学与光化学, 2009, 27(2): 103-110.

LI Fang, ZHU Zong-wen, WANG Yue-chuan. Holographic Performance of Fluorinated Acrylate Photopolymer[J]. Imaging Science and Photochemistry, 2009, 27(2): 103-110.

参考文献

[1] 于美文.光全息学及其应用[M].北京:北京理工大学出版社,1996.147-197.Yu M W.Optical Holography and Its Applications[M].Beijing:Beijing University of Technology Press,1996.147-197.
[2] Trout T J,Schmieg J J,Gambogi W J,et al.Optical photopolymers:design and applications[J].Advanced Materials,1998,10(15):1219-1224.
[3] Solymar L,Cooke D J.Volume Holography and Volume Gratings[M].University of Oxford Press,1981.293-298.
[4] 徐敏,朱建华,陈力,等.红敏聚乙烯醇/丙烯酰胺体系光致聚合物全息记录材料的空间分辨力增强研究[J].光学学报,2007,27(4):616-620.Xu M,Zhu J H,Chen L,et al.Spatial resolution of polyvinyl alcohol/acrylamide based photopolymer holographic recording material[J].Acta Optica Sinica,2007,27(4):616-620.
[5] Martin S,Feely C A,Toal V.Holographic recording characteristics of an acrylamide-based photopolymer[J].Appl.Opt.,1997,36(23):5757-5768.
[6] Blaya S,Carretero L,Mallavia R,Fimia A,et al.Optimization of an acrylamide-based dry film used for holographic recording[J].Appl.Opt.,1998,37(32):7604-7610.
[7] Cho Y H,Shin W,Kim N,et al.High-performance transmission holographic gratings via different polymerization rates of dipentaerythritol acrylate and siloxane-containing epoxides[J].Chem.Mater.,2005,17:6263-6271.
[8] 徐成刚,朱建华,王跃川.含氟红敏光致聚合物全息材料的组分优化[J].光学学报,2007,27(1):26-30.Xu C G,Zhu J H,Wang Y C.Composition optimization of fluoro-containing red-sensitive photopolymer holographic materials[J].Acta Optica Sinica,2007,27(1):26-30.
[9] 谭惠民,罗运军,等.树枝形聚合物[M].北京:化学工业出版社,2002,151-159.Tan H M,Luo Y J,et al.Dendritic Polymer[M].Beijing:Chemical Industry Press,2002.151-159.
[10] Fouassier J P,Allona X,Burget D.Photopolymerization reactions under visible lights:principle,mechanisms and examples of applications[J].Progress in Organic Coating,2003,47:16-36.
[11] Herwing K.Coupled wave theory for thick hologram gratings[J].The Bell System Technical Journal,1969,48(9):2909-2947.

含氟丙烯酸酯光致聚合物的全息特性研究

Holographic Performance of Fluorinated Acrylate Photopolymer

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 9

编辑推荐

Metrics

本文评价

[1]	王笑天. UV固化超支化聚酯树脂的制备研究[J]. 影像科学与光化学, 2019, 37(4): 292-296.
[2]	王震, 张荻琴, 赵宇, 张云龙, 赵榆霞. 用于全息存储的新型感绿光敏剂的制备及其性能研究[J]. 影像科学与光化学, 2018, 36(3): 211-218.
[3]	魏明宾, 李泽仁, 谢棒, 王贵喜, 朱建华. 全色光致聚合物的全息记录特性及应用研究[J]. 影像科学与光化学, 2012, 30(1): 26-32.
[4]	冯宗财, 李琳, 邓凤娟, 韦丽, 刘晓苑. TA-EG-GMA合成超支化碱溶性感光聚合物[J]. 影像科学与光化学, 2010, 28(3): 193-201.
[5]	万晓君, 薛建强, 王焕勇, 刘鹏飞, 赵榆霞, 吴飞鹏, 陶世荃. 新型全息用光致聚合物的研究[J]. 影像科学与光化学, 2008, 26(5): 343-348.
[6]	施盟泉, 吴飞鹏, 赵榆霞, 王大勇, 陶世荃. 全息用光致聚合物中双单体组分对材料性能的影响[J]. 影像科学与光化学, 2008, 26(5): 410-416.
[7]	冯宗财, 李琳. 季戊四醇-偏苯三酸酐-环氧氯丙烷合成超支化聚合物[J]. 影像科学与光化学, 2006, 24(1): 36-43.
[8]	施盟泉, 吴飞鹏, 李妙贞, 王尔鉴, 刘国栋, 何庆声, 王建岗. 光致聚合物材料中各组分对光聚合速度的影响及其在全息存储中的应用实验[J]. 影像科学与光化学, 2002, 20(5): 370-376.
[9]	施文芳. 星形超支化聚酯的合成及其光固化[J]. 影像科学与光化学, 1997, 15(2): 165-168.