硬脂酸镍对以异位合成AgBr乳剂为光敏元的PTG材料感光性能的影响

doi:10.7517/j.issn.1674-0475.2012.02.134

影像科学与光化学 ›› 2012, Vol. 30 ›› Issue (2): 134-141.DOI: 10.7517/j.issn.1674-0475.2012.02.134

硬脂酸镍对以异位合成AgBr乳剂为光敏元的PTG材料感光性能的影响

梁海燕¹, 李姝静¹, 王心蕊¹, 李金培², 马望京², 琚伟³

1. 北京工商大学, 北京 100048;
2. 中国科学院理化技术研究所, 北京 100190;
3. 山东省科学院新材料研究所, 山东济南 250014

收稿日期:2011-11-18 修回日期:2011-12-31 出版日期:2012-03-15 发布日期:2012-03-15
通讯作者: 梁海燕(1978-),女,博士,从事光敏热成像材料的研究,E-mail:lianghy@th.btbu.edu.cn.

The Influence of Nickel Stearate on the Photographic Properties of PTG Material Based on AgBr Emulsions Obtained from an Ex-situ Preparation

LIANG Hai-yan¹, LI Shu-jing¹, WANG Xin-rui¹, LI Jin-pei², MA Wang-jing², JU Wei³

1. Beijing Technology and Business University, Beijing 100048, P.R. China;
2. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R.China;
3. Shandong Province Academy of Sciences, Ji’nan 250014, Shandong, P.R.China

Received:2011-11-18 Revised:2011-12-31 Online:2012-03-15 Published:2012-03-15

摘要/Abstract

摘要： 本文报道了硬脂酸镍(NiSt₂)对以异位合成AgBr乳剂为光敏元的光敏热显影(PTG)材料感光性能的影响.结果表明AgBr与AgTTA的摩尔比为0.25时,PTG材料感光度最大,并且硬脂酸镍可将感光度提高约1.1倍。本文通过对AgBr乳剂的光吸收和硬脂酸镍的DSC的研究,初步分析了硬脂酸镍对PTG材料感光性能的影响原因.

关键词: AgBr, 硬脂酸镍, 甲基苯并三氮唑银, 光敏热显影材料

Abstract: The influence of nickel stearate on the photographic properties of photothermographic (PTG) materials based on AgBr emulsions obtained from an ex-situ preparation was reported. The results showed that the maximal sensitivity of PTG materials could be obtained when the ratio of AgBr to AgTTA was 0.25, and the sensitivity of PTG materials with nickel stearate was 1.1 times higher than the origin one. The possible reason of the influence of nickel stearate on the photographic properties was studied primarily by UV-Vis of AgBr grains and DSC of nickel stearate.

Key words: silver bromide, nickel stearate, silver tolyltriazole, photothermographic material

中图分类号:

TQ57

梁海燕, 李姝静, 王心蕊, 李金培, 马望京, 琚伟. 硬脂酸镍对以异位合成AgBr乳剂为光敏元的PTG材料感光性能的影响[J]. 影像科学与光化学, 2012, 30(2): 134-141.

LIANG Hai-yan, LI Shu-jing, WANG Xin-rui, LI Jin-pei, MA Wang-jing, JU Wei. The Influence of Nickel Stearate on the Photographic Properties of PTG Material Based on AgBr Emulsions Obtained from an Ex-situ Preparation[J]. Imaging Science and Photochemistry, 2012, 30(2): 134-141.

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硬脂酸镍对以异位合成AgBr乳剂为光敏元的PTG材料感光性能的影响

The Influence of Nickel Stearate on the Photographic Properties of PTG Material Based on AgBr Emulsions Obtained from an Ex-situ Preparation

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